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公开(公告)号：US07737241B2
公开(公告)日：2010-06-15
申请号：US11544502
申请日：2006-10-06
IPC分类号： C08F4/52 , C08F265/06
CPC分类号： C08F220/18 , C07F5/02 , C08F4/52 , C09J4/00 , C09J4/06 , Y10T428/31504 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31928
摘要： The invention is a system for initiating free radical polymerization comprising: a) in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms and optionally containing one or more heteroatoms or heteroatom containing functional moieties, and one or more cationic counter ions and b) in a second part, a liberating compound which reacts with the nitrogen atom(s) bound to the boron atom(s) upon contact with the amido-borate to form an organoborane radical.
摘要翻译： 本发明是用于引发自由基聚合的体系，其包括：a）一种或多种含有一种或多种含有机硼酸盐的阴离子酰氨基硼酸盐部分的酰氨基硼酸盐化合物，其中硼原子与氨的氮原子键合 含有一个或多个氮原子的有机化合物，例如烃基胺，烃基多胺或含有一个或多个氮原子并且任选地含有一个或多个含杂原子或杂原子的官能部分的芳族杂环，以及一种或多种阳离子抗衡离子 和b）在第二部分中，与氨基硼酸盐接触时与硼原子结合的氮原子反应形成有机硼烷基团的释放化合物。
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公开(公告)号：US07816562B2
公开(公告)日：2010-10-19
申请号：US11544521
申请日：2006-10-06
IPC分类号： C08F4/52 , C08F265/06
CPC分类号： C08F220/18 , C07F5/02 , C08F4/52 , C09J4/00 , C09J4/06 , Y10T428/31504 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31928
摘要： The invention is amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate anion wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms, and a cationic counter ion.
摘要翻译： 本发明是含有一种或多种包含有机硼酸根阴离子的阴离子酰氨基硼酸盐部分的酰氨基硼酸盐化合物，其中硼原子与氨的氮原子或含有一个或多个氮原子的有机化合物例如烃基胺， 烃基多胺或含有一个或多个氮原子的芳族杂环，和阳离子抗衡离子。
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3.发明申请INITIATORS FOR POLYMERIZATION OF VINYL MONOMERS BASED ON THE REACTION OF PHENOXYALUMINUM COMPLEXES WITH OXYGEN 审中-公开基于苯氧基铝复合物与氧的反应聚合乙烯基单体的方法公开(公告)号：US20120016080A1
公开(公告)日：2012-01-19
申请号：US13179633
申请日：2011-07-11
CPC分类号： C08F220/14 , C08F4/28 , C08F4/52 , C09D7/70
摘要： One exemplary embodiment includes a method comprising polymerizing vinyl monomers with an initiator comprising a phenoxyaluminum alkyl compound in the presence of oxygen.
摘要翻译： 一个示例性实施方案包括在氧气存在下使乙烯基单体与包含苯氧基烷基铝化合物的引发剂聚合的方法。
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公开(公告)号：US20100105910A1
公开(公告)日：2010-04-29
申请号：US12603381
申请日：2009-10-21
IPC分类号： C07F5/02
摘要： An organoborane complex is disclosed. The complex includes a blocking agent comprising a bifunctional Lewis base. The blocking agents include an amine group and a second functional group that has a lower Lewis basicity than the first functional group. The blocking is based on amino alkyl pyridines.
摘要翻译： 公开了有机硼烷络合物。 络合物包括包含双功能路易斯碱的封闭剂。 封端剂包括具有比第一官能团低的路易斯碱度的胺基和第二官能团。 封闭基于氨基烷基吡啶。
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公开(公告)号：US20080295961A1
公开(公告)日：2008-12-04
申请号：US12182170
申请日：2008-07-30
摘要： The invention is a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species and in the second part one or more compounds capable of free radical polymerization and from about 20 to about 30 parts by weight based on the weight of the second part of i) a halogenated polyolefin having halosulfonyl groups or ii) a mixture of a halogenated polyolefin and an organic sulfonyl halide. The second part may further contain a compound capable of causing the organoboron compound to form free radical generating species upon contacting the two parts. The first part may further comprise one or more compounds capable of free radical polymerization.
摘要翻译： 本发明是一种两部分可聚合组合物，其一部分包含能够形成自由基产生物质的有机硼化合物，在第二部分中包含一种或多种能够进行自由基聚合的化合物和约20至约30重量份，基于重量 的第二部分i）具有卤磺酰基的卤代聚烯烃，或ii）卤化聚烯烃和有机磺酰卤的混合物。 第二部分可以进一步包含能够使有机硼化合物在接触两部分时形成自由基产生物质的化合物。 第一部分还可以包含一种或多种能够进行自由基聚合的化合物。
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公开(公告)号：US20080090981A1
公开(公告)日：2008-04-17
申请号：US11546794
申请日：2006-10-12
IPC分类号： C08F118/02
摘要： The invention is a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species and in the second part one or more compounds capable of free radical polymerization and from about 20 to about 30 parts by weight based on the weight of the second part of i) a halogenated polyolefin having halosulfonyl groups or ii) a mixture of a halogenated polyolefin and an organic sulfonyl halide. The second part may further contain a compound capable of causing the organoboron compound to form free radical generating species upon contacting the two parts. The first part may further comprise one or more compounds capable of free radical polymerization.
摘要翻译： 本发明是一种两部分可聚合组合物，其一部分包含能够形成自由基产生物质的有机硼化合物，在第二部分中包含一种或多种能够进行自由基聚合的化合物和约20至约30重量份，基于重量 的第二部分i）具有卤磺酰基的卤代聚烯烃，或ii）卤化聚烯烃和有机磺酰卤的混合物。 第二部分可以进一步包含能够使有机硼化合物在接触两部分时形成自由基产生物质的化合物。 第一部分还可以包含一种或多种能够进行自由基聚合的化合物。
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公开(公告)号：US08729168B2
公开(公告)日：2014-05-20
申请号：US13093013
申请日：2011-04-25
申请人： Gary L. Jialanella , Christopher P. Christenson , Valeriy V. Ginzburg , Toni Ristoski , Eric E. Cole , Sean C. Tobin , Lirong Zhou
发明人： Gary L. Jialanella , Christopher P. Christenson , Valeriy V. Ginzburg , Toni Ristoski , Eric E. Cole , Sean C. Tobin , Lirong Zhou
IPC分类号： C08K5/00
CPC分类号： C09J175/08 , C08G18/12 , C08G18/289
摘要： The invention is an adhesive composition comprising: a) an isocyanate functional polyether base prepolymers having a z molecular weight average (Mz) of about 10,000 to about 80,000 g/mole; a carbon black having an average oil absorption number of at least about 80 to at most about 400 cubic centimeters of dibutyl phthalate per 100 grams of the carbon black; (c) reactive silicon in an amount from about 0.001% to about 10% by weight of the adhesive composition; and (d) one or more catalysts for the reaction of isocyanate with hydroxyl groups. The adhesive compositions of the invention surprisingly may have improved sag performance (i.e., decreased sag) when heated, while also making them more easily pumped.
摘要翻译： 本发明是一种粘合剂组合物，其包含：a）具有约10,000至约80,000g /摩尔的z分子量平均值（Mz）的异氰酸酯官能聚醚基预聚物; 平均吸油量为每100克炭黑至少约80至至多约400立方厘米邻苯二甲酸二丁酯的炭黑; （c）反应性硅，其量为粘合剂组合物重量的约0.001％至约10％; 和（d）用于使异氰酸酯与羟基反应的一种或多种催化剂。 当加热时，本发明的粘合剂组合物令人惊奇地具有改善的下垂性能（即，减小的下垂），同时也使它们更容易地泵送。
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8.发明授权Stabilized organoborane polymerization initiators and polymerizable compositions 有权稳定的有机硼烷聚合引发剂和可聚合组合物公开(公告)号：US07247596B2
公开(公告)日：2007-07-24
申请号：US10864719
申请日：2004-06-09
申请人： Gary L. Jialanella , Toni Ristoski
发明人： Gary L. Jialanella , Toni Ristoski
CPC分类号： C09J4/00 , C08F10/00 , C08L33/06 , C09D133/06 , C09J5/06 , C09J133/06
摘要： The invention is polymerizable compositions comprising in one part an organoboron compound capable of forming a free radical generating species and a stabilizing amount of one or more compounds comprising a dihydrocarbyl hydroxyl amine, an alicyclic hydroxyl amine, or a nitrile oxide of a dihydrocarbyl hydroxyl amine or an alicyclic hydroxyl amine, and in the second part one or more compounds capable of free radical polymerization.
摘要翻译： 本发明是一种可聚合组合物，其一部分包含能够形成自由基产生物质的有机硼化合物和稳定量的一种或多种包含二烃基羟胺的二烃基羟胺，脂环族羟基胺或腈氧化物的化合物或 脂环族羟基胺，第二部分是一种或多种能够进行自由基聚合的化合物。
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9.发明申请Curable Compositions Containing Isocyanate Functional Components Having Improved Durability 有权含有具有改善的耐久性的异氰酸酯官能组分的可固化组合物公开(公告)号：US20130233488A1
公开(公告)日：2013-09-12
申请号：US13885279
申请日：2011-11-23
IPC分类号： C08K5/3435 , C09J5/00
CPC分类号： C08G18/778 , B29C65/00 , B29C65/48 , B29C65/485 , B29C65/4865 , B29C65/487 , B29C65/4875 , B32B17/00 , B32B17/061 , B32B17/10 , B32B27/00 , B32B27/40 , B32B37/00 , B32B37/12 , B60J1/00 , C08G18/10 , C08G18/12 , C08G18/2081 , C08K3/04 , C08K5/005 , C08K5/32 , C08K5/3435 , C08K13/02 , C08L75/04 , C09J5/00 , C09J175/02 , C09J175/04 , C09J175/12 , E06B3/56 , E06B3/64 , C08G18/307
摘要： A composition comprising: a) one or more isocyanate functional prepolymers; b) one or more catalysts for the reaction of isocyanate moieties with hydroxyl groups; c) one or more reinforcing fillers; and d) a stabilizing amount of one or more compounds comprising a dihydrocarbyl hydroxylamine, an alicyclic hydroxylamine, a nitrile oxide of a dihydrocarbyl hydroxylamine or a nitrile oxide of an alicyclic hydroxylamine. In another embodiment the invention is a method of bonding two or more substrates together which comprises contacting the two or more substrates together with a composition according to this invention disposed along at least a portion of the area wherein the substrates are in contact. The compositions of the invention are useful as an adhesive to bond substrates together.
摘要翻译： 一种组合物，其包含：a）一种或多种异氰酸酯官能预聚物; b）用于使异氰酸酯部分与羟基反应的一种或多种催化剂; c）一种或多种增强填料; 和d）稳定量的一种或多种包含二烃基羟胺，脂环羟胺，二烃基羟胺的腈氧化物或脂环羟胺的腈氧化物的化合物。 在另一个实施方案中，本发明是一种将两个或更多个基底结合在一起的方法，其包括使两个或更多个基底与沿着其中基底接触的区域的至少一部分布置的根据本发明的组合物接触。 本发明的组合物可用作将基底粘合在一起的粘合剂。
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公开(公告)号：US20110265932A1
公开(公告)日：2011-11-03
申请号：US13093013
申请日：2011-04-25
申请人： Gary L. Jialanella , Christopher P. Christenson , Valeriy V. Ginzburg , Toni Ristoski , Eric E. Cole , Sean C. Tobin , Lirong Zhou
发明人： Gary L. Jialanella , Christopher P. Christenson , Valeriy V. Ginzburg , Toni Ristoski , Eric E. Cole , Sean C. Tobin , Lirong Zhou
IPC分类号： B32B37/12 , B32B37/02 , C09J11/04 , C09J175/08 , C09J11/06
CPC分类号： C09J175/08 , C08G18/12 , C08G18/289
摘要： The invention is an adhesive composition comprising: a) an isocyanate functional polyether base prepolymers having a z molecular weight average (Mz) of about 10,000 to about 80,000 g/mole; a carbon black having an average oil absorption number of at least about 80 to at most about 400 cubic centimeters of dibutyl phthalate per 100 grams of the carbon black; (c) reactive silicon in an amount from about 0.001% to about 10% by weight of the adhesive composition; and (d) one or more catalysts for the reaction of isocyanate with hydroxyl groups. The adhesive compositions of the invention surprisingly may have improved sag performance (i.e., decreased sag) when heated, while also making them more easily pumped.
摘要翻译： 本发明是一种粘合剂组合物，其包含：a）具有约10,000至约80,000g /摩尔的z分子量平均值（Mz）的异氰酸酯官能聚醚基预聚物; 平均吸油量为每100克炭黑至少约80至至多约400立方厘米邻苯二甲酸二丁酯的炭黑; （c）反应性硅，其量为粘合剂组合物重量的约0.001％至约10％; 和（d）用于使异氰酸酯与羟基反应的一种或多种催化剂。 当加热时，本发明的粘合剂组合物令人惊奇地具有改善的下垂性能（即，减小的下垂），同时也使它们更容易地泵送。
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