摘要:
An aqueous cadmium oxide paste of high flowability for the vibration filling of foam-structure and fiber-structure electrode plaques is characterized by a cadmium oxide content of about 25 to 35% by volume, a pH of about 10 to 12.5, a content of about 0.5 to 2.5% by weight, based on cadmium oxide, of one or more dispersants from the group comprising the water-soluble salts of polyphosphoric acids, di- and polyphosphonic acids and their derivatives, gluconic acid or of antimonyl tartrate. The paste has a plastic viscosity of about 0.1 to 1 Pa.s and also a yield value of between about 10 and 120 Pa. This cadmium oxide paste makes it possible to fill foam-structure and fiber-structure electrode plaques completely in one operation.
摘要:
A nickel-cadmium storage battery with improved electrical properties is described in which one or more copolymers of vinyl pyrrolidone is/are added as expander to the active material with which the negative electrode is filled or to the electrolyte. The polymers have a mean molecular weight of 10,000 g/mol to 100,000 g/mol, with a vinyl pyrrolidone content of between 5 and 95 mol-%. The copolymers are added to the active material or to the electrolyte in an amount of 0.1 to 1.0% by weight, based on the active material. As a result of adding the copolymers, a malfunction-free operation of the storage battery is achieved, accompanied by a simultaneously equally as good degree of utilization of the cadmium active material compared with a storage battery which contains homopolymeric polyvinyl pyrrolidone.
摘要:
A gas tightly sealed nickel-cadmium cell is provided which works on the oxygen cycle principle and has a charge and discharge reserve at the negative electrode. Further, the partial pressure of the gases which cannot be reacted in the cell is below 0.4 bar. As a result of this substantial removal of the gases which cannot be reacted from the interior space of the cell, there is a considerable rise in the oxygen consumption rate, i.e., the rate at which the oxygen generated in the cell is reacted at the negative electrode, so that higher charge current densities are possible.
摘要:
An aqueous cadmium oxide paste of high flowability for the vibration filling of foam-structure and fiber-structure electrode plaques is characterized by a cadmium oxide content of about 25 to 35% by volume, a pH of about 10 to 12.5, a content of about 0.5 to 2.5% by weight, based on cadmium oxide, of one or more dispersants from the group comprising the water-soluble salts of polyphosphoric acids, di- and polyphosphonic acids and their derivatives, gluconic acid or of antimonyl tartrate. The paste has a plastic viscosity of about 0.1 to 1 Pa.s and also a yield value of between about 10 and 120 Pa. This cadmium oxide paste makes it possible to fill foam-structure and fiber-structure electrode plaques completely in one operation.
摘要:
An aqueous nickel-hydroxide paste of high flowability for the vibration filling of foam-structure and fiber-structure electrode plaques has a content of about 30 to 50% by volume of nickel hydroxide, a maximum particle size of about 0.04 mm, a plastic viscosity of about 0.1 to 1 Pa.s and a yield value of between about 10 and 120 Pa, a pH of between about 9 and 12 and a content of about 0.5 to 5, in particular about 1 to 5, % by weight, based on the nickel hydroxide content, of a dispersant from the group comprising the water-soluble salts of polhphosphoric acids or di- and polyphosphonic acids and their derivatives. Very particularly suitable as a dispersant is 1-hydroxyethane-1, 1-diphosphonic acid in the form of its cobalt/alkali salt complex. This paste makes it possible to completely fill foam-structure and fiber-structure electrode plaques in one operation.
摘要:
An alkaline nickel-cadmium storage battery in which the active material with which the negative electrode is filled with, or the electrolyte in the storage battery, contains polyvinylpyrrolidone as an expander. Polyvinylpyrrolidone compounds having a mean molecular weight of 5,000 to 35,000 g/mol have proved particularly advantageous.
摘要:
An electrochemical cell comprises a cell casing defining a negative electrode compartment for containing an alkali metal negative electrode; and a plurality of flat plate solid electrolyte electrode holders in the casing and extending parallel to opposed walls of the casing. Each electrode holder comprises a pair of spaced plates and provides a positive electrode compartment containing a liquid electrolyte, and a positive electrode. The positive electrodes are electrically connected in parallel and define, together with envelopes, a positive plate stack. When the cell is fully charged, the major portion of the liquid alkali metal is contained in the negative electrode compartment outside the positive plate stack. Wicking means for the liquid alkali metal are provided adjacent at least the plates of the holders. The level of the liquid alkali metal remains substantially constant in the wicking means.
摘要:
A membrane module for hydrogen separation includes a stack of flat membrane packs disposed adjacent one another so as not to exert a force on one another and a rotationally symmetrical pressure shell enclosing the stack of flat membrane packs. A feed space for a reformate gas is disposed between every two membrane packs in the stack. Each membrane pack has a pair of membrane assemblies and a support structure disposed therebetween and each membrane assembly includes a hydrogen-selective flat membrane supported by at least one membrane frame.
摘要:
A moisture exchange module includes a bundle of moisture-permeable hollow fibre membranes. It is provided with a feedline for supplying a gas stream that flows through the hollow fibre membranes in an inner flow. According to the present invention, a separating device for separating out liquid particles from the gas flow are provided in the region between the feedline and the bundle of hollow fibre membranes. The separating device may have the form of a groove and are arranged in such a way that the gas flow is guided in such a manner that the centrifugal force assists movement of the liquid particles towards the separating device. The moisture exchange module preferably forms part of a fuel cell system to humidify feed air for the fuel cell system.
摘要:
The invention relates to a method of producing color pastes, in which a component comprising colorant particles is dispersed in a binder. In the method of the invention the dispersing operation is controlled by beaming excitational light of a defined wavelength range into a mixture of the component comprising colorant particles and the binder, detecting the light transmitted, reflected and/or scattered by the mixture and determining a sample spectrum, evaluating the sample spectrum and hence determining parameters of the color paste, and monitoring changes in the sample spectrum over time and terminating the dispersing operation when predetermined target parameters are attained.