Pyrazole-3-carboxamides, herbicidal compositions and use
    2.
    发明授权
    Pyrazole-3-carboxamides, herbicidal compositions and use 失效
    吡唑-3-甲酰胺,除草组合物和用途

    公开(公告)号:US5217523A

    公开(公告)日:1993-06-08

    申请号:US877366

    申请日:1992-05-04

    摘要: Pyrazole-3-carboxamides of the general formula I ##STR1## where the substituents have the following meaning: R.sup.1 hydrogen;substituted or unsubstituted C.sub.3 -C.sub.8 -cycloalkyl or C.sub.1 C.sub.6 -alkyl;R.sup.2 hydroxy; amino; C.sub.1 -C.sub.4 -alkylamino; di-C.sub.1 -C.sub.4 -alkylamino, aminocarbonyl-C.sub.1 -C.sub.6 -alkyl; substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxy, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, phenyl or naphthyl,a substituted or unsubstituted 5- to 6-membered heterocyclic ring;one of the groups mentioned for R.sup.1 orR.sup.1 and R.sup.2 together denote a 4- to 7-membered chain which may contain, in addition to methylene groups one of the following groups as ring member: oxygen, sulfur N-methyl or carbonyl;R.sup.3 a substituted or unsubstituted 5- to 6-membered heterocyclic ring.substituted or unsubstituted C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 alkynyl, 5,6,7,8-tetrahydronaphthyl or phenyl orone of the groups mentioned for R.sup.1 ;R.sup.4 nitro; cyano; carboxyl; halogen; substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkylthio, orone of the groups mentioned for R.sup.3 ;R.sup.5 4,5-dihydroxazol-2-yl or a group COYR.sup.6 ;Y hydrogen;R.sup.6 C.sub.3 -C.sub.8 -cycloalkyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.5 -C.sub.7 -cycloalkenyl or phenyl,a substituted or unsubstituted 5- or 6-membered heterocyclic ring; phthalimido; tetrahydrophthalimido; succinimido; maleiimido; benzotriazolyl ora group --N.dbd.CR.sup.7 R.sup.8, whereR.sup.7 is hydrogen or C.sub.1 -C.sub.6 -alkyl andR.sup.8 is C.sub.3 -C.sub.6 -cycloalkyl, phenyl, furyl or a radical R.sup.7 orR.sup.7, R.sup.8 together denote a 4- to 7-membered alkylene chain,and their agriculturally useful salts, Y not denoting oxygen and R.sup.1 not denoting hydrogen when R.sup.3 is hydrogen and R.sup.4 is nitro, trifluoromethyl, halogen or C.sub.1 -C.sub.4 -alkoxy and --YR.sup.6 not denoting ethoxy when R.sup.1 is hydrogen, R.sup.4 is methyl and R.sup.2 is phenyl or substituted phenyl.

    摘要翻译: 吡唑-3-甲酰胺,其通式为Ⅰ,其中取代基具有下列含义:R 1氢; 取代或未取代的C 3 -C 8 - 环烷基或C 1 -C 6烷基; R2羟基; 氨基; C 1 -C 4烷基氨基; 二-C 1 -C 4烷基氨基,氨基羰基-C 1 -C 6 - 烷基; 取代或未取代的C 1 -C 4 - 烷氧基,C 3 -C 6 - 烯基,C 3 -C 6 - 炔基,苯基或萘基,取代或未取代的5至6元杂环; 对于R1或R1和R2提及的基团之一一起表示4至7元链,除了亚甲基之外,还可以含有以下基团之一作为环成员:氧,硫,N-甲基或羰基; R3是取代或未取代的5至6元杂环。 取代或未取代的C 3 -C 6 - 烯基,C 3 -C 6炔基,5,6,7,8-四氢萘基或苯基或提及的R 1的一个基团; R4硝基; 氰基; 羧基; 卤素; 取代或未取代的C 1 -C 4 - 烷氧基或C 1 -C 4 - 烷硫基,或提及的基团之一; R5 4,5-二羟基恶唑-2-基或COYR 6基; Y氢; R 6 C 3 -C 8 - 环烷基,取代或未取代的C 1 -C 6 - 烷基,C 3 -C 6 - 烯基,C 3 -C 6 - 炔基,C 5 -C 7 - 环烯基或苯基,取代或未取代的5元或6元杂环; 邻苯二甲酰亚氨基; 四氢邻苯二甲酰亚胺 琥珀酰亚胺 马来西亚 苯并三唑基或基团-N = CR 7 R 8,其中R 7是氢或C 1 -C 6烷基,R 8是C 3 -C 6环烷基,苯基,呋喃基或基团R 7或R 7,R 8一起表示4至7元亚烷基链 和其农业上有用的盐,Y不表示氧,当R 3为氢时,R 1不表示氢,R 4为硝基,三氟甲基,卤素或C 1 -C 4 - 烷氧基,而R 1为氢时未表示乙氧基,R 4为甲基,R 2为R 2 是苯基或取代的苯基。

    Substituted sulfonylureas
    6.
    发明授权
    Substituted sulfonylureas 失效
    取代磺酰脲类

    公开(公告)号:US5032167A

    公开(公告)日:1991-07-16

    申请号:US448984

    申请日:1989-12-12

    CPC分类号: C07D521/00 A01N47/36

    摘要: Substituted sulfonylureas of the formula I ##STR1## where the substituents and indices have the following meanings: x is oxygen or sulfur;z is nitrogen or methine (=CH--);R.sup.1 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxycarbonyl or C.sub.1 -C.sub.3 -alkoxy, or a radical --CONR.sup.6 R.sup.7, whereR.sup.6 is hydrogen, C.sub.1 -C.sub.8 -alkyl or C.sub.1 -C.sub.6 -alkoxy andR.sup.7 is hydrogen or C.sub.1 -C.sub.8 -alkyl;R.sup.2 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkyl;R.sup.3 is C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkylthio, halogen, cyano, nitro, amino, mono-C.sub.1 -C.sub.4 -alkylamino, di-C.sub.1 -C.sub.4 -alkylamino, C.sub.2 -C.sub.6 -alkenyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkanoyl or benzyl; a 5- or 6-membered saturated heterocycle which is attached by its nitrogen atom and which, besides methylene and a nitrogen, may also contain an oxygen or a sulfur atom; or, bonded to adjacent ring positions, --OCRR'O--, where R and R' are each hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.5 is halogen C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio or C.sub.1 -C.sub.4 -haloalkyl;m is from 0 to 3 or, when R.sup.3 is halogen, from 0 to 5, differences among the R.sup.3 radicals being possible when m is 2 or 3; andn is from 0 to 2, a difference between the R.sup.5 radicals being possible when n is 2;and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.

    摘要翻译: 取代基和指数具有以下含义的式I的取代磺酰脲类:x是氧或硫; z是氮或次甲基(= CH-); R 1是卤素或取代或未取代的C 1 -C 4 - 烷氧基羰基或C 1 -C 3 - 烷氧基或基团-CONR 6 R 7,其中R 6是氢,C 1 -C 8 - 烷基或C 1 -C 6 - 烷氧基,并且R 7是氢或C 1 -C 8 - 烷基; R2是卤素或取代或未取代的C1-C4-烷氧基或C1-C4-烷基; R 3是C 1 -C 4烷基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷基,C 1 -C 4卤代烷氧基,C 1 -C 4卤代烷硫基,卤素,氰基,硝基,氨基,单-C 1 -C 4烷基氨基, C 1 -C 4 - 烷基氨基,C 2 -C 6 - 烯基,C 1 -C 4 - 烷氧基羰基,C 1 -C 4 - 烷酰基或苄基; 通过其氮原子连接的5-或6-元饱和杂环,除了亚甲基和氮之外,还可以含有氧或硫原子; 或者,与相邻的环位置键合,-OCRR'O-,其中R和R'各自为氢或C1-C4-烷基; R4是氢或C1-C4-烷基; R5是卤素C1-C4-烷基,C1-C4-烷氧基,C1-C4-烷硫基或C1-C4卤代烷基; m为0至3,或当R3为卤素时为0至5,当m为2或3时,R3基团之间的差异是可能的; n为0〜2,当n为2时,R5基团之间的差异是可能的; 及其环境可接受的盐,其制备方法,以及它们作为除草剂的用途。