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公开(公告)号：US07138469B2
公开(公告)日：2006-11-21
申请号：US10473313
申请日：2002-12-10
申请人： Gianni Collina , Ofelia Fusco , Eduardo Chicote Carrion , Alberto Gil , Volker Dolle , Horst Klassen , Karl-Heinz Kagerbauer
发明人： Gianni Collina , Ofelia Fusco , Eduardo Chicote Carrion , Alberto Gil , Volker Dolle , Horst Klassen , Karl-Heinz Kagerbauer
CPC分类号： C08F10/06 , C08F110/06 , C08F4/646 , C08F4/6545 , C08F2500/18 , C08F2500/24
摘要： Process for the polymerization of olefins CH2═CHR, in which R is hydrogen or a hydrocarbon radical with 1–12 carbon atoms, carried out in the presence of a catalyst component (A) comprising Mg, Ti and halogen as essential elements and of a catalyst component (B) capable to produce, under the same polymerization conditions, a polymer with an average particle size lower than that obtainable with the said catalyst component A. The said process provides polymers with increased bulk density.
摘要翻译： 烯烃CH 2 R 2的聚合方法，其中R是氢或具有1-12个碳原子的烃基，在包含Mg，Ti的催化剂组分（A）的存在下进行 和作为必需元素的卤素和能够在相同聚合条件下生产平均粒度低于用所述催化剂组分A获得的聚合物的催化剂组分（B）。所述方法提供具有增加的堆积密度的聚合物 。
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公开(公告)号：US06362298B1
公开(公告)日：2002-03-26
申请号：US08804063
申请日：1997-02-21
IPC分类号： C08F21016
摘要： The invention relates to a high-molecular-weight copolymer comprising ethylene and propylene units which has an ethylene content in the range from 1 to 10% by weight, a melt flow rate MFR (230/5) of
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公开(公告)号：US06218504B1
公开(公告)日：2001-04-17
申请号：US09380404
申请日：1999-09-01
IPC分类号： C08F626
CPC分类号： B29B13/00 , B29C2071/0027 , B29K2023/00 , C08F6/005 , C08L23/00
摘要： A gaseous mixture of steam and air, a gaseous mixture of steam and nitrogen, or pure steam are passed around polyolefin granules in a deodorizing apparatus. The result is that the polyolefin granules have markedly improved properties with respect to odor and taste, and these are retained in moldings produced from the granules.
摘要翻译： 蒸汽和空气的气体混合物，蒸气和氮气的气体混合物或纯蒸汽在除臭装置中通过聚烯烃颗粒。 结果是聚烯烃颗粒在气味和味道方面具有显着改善的性能，并且这些颗粒保留在由颗粒制成的模制品中。
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4.发明授权公开(公告)号：US08569434B2
公开(公告)日：2013-10-29
申请号：US13148041
申请日：2010-02-16
申请人： Fabiana Fantinel , Shahram Mihan , Volker Dolle , Andreas Maus
发明人： Fabiana Fantinel , Shahram Mihan , Volker Dolle , Andreas Maus
IPC分类号： C08L23/08
CPC分类号： C08F210/16 , C08F4/63912 , C08F4/6392 , C08F2420/01 , C08L23/0815 , C08L2205/02 , C08L2308/00 , C08L2314/06 , C08L2666/06 , C08F210/14 , C08F2500/20 , C08F2500/17 , C08F2500/12 , C08F2500/03 , C08F2500/05 , C08F2500/08 , C08F4/63904
摘要： An ethylene copolymer, a catalyst system suitable to prepare the ethylene copolymer, and a process to prepare such ethylene copolymer are described. The use of the ethylene copolymer as impact modifier in polyethylene and as compatibilizer in a polymer blend are also described. The ethylene copolymer has a density from 0.855 g/cm3 to 0.910 g/cm3, a polydispersity Mw/Mn lower than 3.5, comprises at least one first ethylene polymer component and at least one second ethylene polymer component having different comonomer contents so as to show at least two predetermined CRYSTAF peak temperatures.
摘要翻译： 描述了乙烯共聚物，适于制备乙烯共聚物的催化剂体系，以及制备这种乙烯共聚物的方法。 还描述了在聚乙烯中使用乙烯共聚物作为抗冲改性剂和在聚合物共混物中作为增容剂。 乙烯共聚物的密度为0.855g / cm 3至0.910g / cm 3，多分散性Mw / Mn低于3.5，包含至少一种第一乙烯聚合物组分和至少一种具有不同共聚单体含量的第二乙烯聚合物组分，以显示 至少两个预定的CRYSTAF峰值温度。
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5.再颁专利Metallocenes containing ligands of 2-substituted indenyl derivatives, process for their preparation, and their use as catalysts 失效含有2-取代茚基衍生物配体的金属茂，其制备方法及其作为催化剂的用途公开(公告)号：USRE39532E1
公开(公告)日：2007-03-27
申请号：US08895909
申请日：1997-07-17
IPC分类号： C07F7/28 , C07F9/00 , C07F11/00 , C07C13/465
CPC分类号： C07F17/00 , C07F7/0805 , C08F4/63912 , C08F4/63927 , C08F10/00 , C08F110/06 , C08F2500/03 , C08F2500/17 , C08F2500/15
摘要： The novel metallocenes of the formula I in which, preferably, M1 is Zr or Hf, R1 and R2 are alkyl or halogen, R3 and R4 are hydrogen, R5 and R6 are alkyl or haloalkyl, —(CR8R9)m—R7—(CR8R9)n— is a single- or multi-membered chain in which R7 may also be a (substituted) hetero atom, m+n is zero or 1, and R10 is hydrogen, form, together with aluminoxanes as cocatalysts, a very effective catalyst system for the preparation of polyolefins of high stereospecificity and high melting point.
摘要翻译： 配方的新金属茂
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公开(公告)号：US5328969A
公开(公告)日：1994-07-12
申请号：US980643
申请日：1992-11-24
申请人： Andreas Winter , Jurgen Rohrmann , Volker Dolle , Frank Kuber
发明人： Andreas Winter , Jurgen Rohrmann , Volker Dolle , Frank Kuber
IPC分类号： C07F7/00 , C07C13/465 , C07C45/46 , C07C45/67 , C07F17/00 , C08F4/60 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/655 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06
CPC分类号： C08F10/06 , C07C13/465 , C07C45/46 , C07C45/67 , C07F17/00 , C08F10/00 , C07C2102/08 , C08F110/06 , C08F210/06 , C08F4/63912 , C08F4/63927 , C08F4/65908 , Y10S526/943
摘要： A very active catalyst system for olefin polymerization comprises a cocatalyst, preferably an aluminoxane, and a metallocene of the formula I ##STR1## in which, preferably, M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.3 is hydrogen, R.sup.4 to R.sup.6 are alkyl or aryl, --(CR.sup.8 R.sup.9).sub.m --R.sup.7 --(CR.sup.8 R.sup.9).sub.n is a single- or multi-membered chain, in which R.sup.7 can also be a (substituted) hetero atom, and m+n is zero or 1.
摘要翻译： 用于烯烃聚合的非常活泼的催化剂体系包括助催化剂，优选铝氧烷和式I（I）的茂金属，其中优选地，M1是Zr或Hf，R1和R2是烷基或卤素，R3是 氢，R4至R6是烷基或芳基， - （CR8R9）m-R7-（CR8R9）n是单或多元链，其中R7也可以是（取代的）杂原子，m + n是 零或1。
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7.发明授权Process for the preparation of an olefin polymer using metallocenes having specifically substituted indenyl ligands 失效使用具有特异取代的茚基配体的金属茂制备烯烃聚合物的方法
公开(公告)号：US5304614A
公开(公告)日：1994-04-19
申请号：US960893
申请日：1992-10-14
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A very active catalyst system for olefin polymerization comprises a cocatalyst, preferably an aluminoxane, and a metallocene of the formula I or Ia ##STR1## in which, preferably, M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.3 and R.sup.4 are hydrogen or alkyl, R.sup.5 and R.sup.6 are alkyl, --(CR.sup.8 R.sup.9).sub.m --R.sup.7 --(CR.sup.8 R.sup.9).sub.n is a chain with one or more members, in which R.sup.7 can also be a (substituted) heteroatom, and m+n is zero or 1.
摘要翻译： 用于烯烃聚合的非常活泼的催化剂体系包括助催化剂，优选铝氧烷和式I或Ia的茂金属（*化学结构*），其中优选地是M1是Zr或Hf，R1和R2是烷基或卤素， R3和R4是氢或烷基，R5和R6是烷基， - （CR8R9）m-R7-（CR8R9）n是具有一个或多个成员的链，其中R7也可以是（取代的）杂原子，并且m + n为零或1。
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8.发明授权Metallocenes containing ligands of 2-substituted idenyl derivatives, process for their preparation, and their use as catalysts 失效含有2-取代的烯基衍生物的配体的金属茂，其制备方法及其作为催化剂的用途
公开(公告)号：US5276208A
公开(公告)日：1994-01-04
申请号：US789361
申请日：1991-11-08
IPC分类号： C07F7/00 , C07F7/08 , C07F17/00 , C08F4/60 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/70 , C08F10/00 , C08F110/06 , C07F7/28 , C07F9/00 , C07F11/00
CPC分类号： C07F17/00 , C07F7/0809 , C08F10/00 , C08F110/06 , C08F4/63912 , C08F4/63927 , Y10S526/943
摘要： The novel metallocenes of the formula I ##STR1## in which, preferably, M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.3 and R.sup.4 are hydrogen, R.sup.5 and R.sup.6 are alkyl or haloalkyl, --(CR.sup.8 R.sup.9).sub.m --R.sup.7 --(CR.sup.8 R.sup.9).sub.n -- is a single- or multi-membered chain in which R.sup.7 may also be a (substituted) hetero atom, m+n is zero or 1, and R.sup.10 is hydrogen, form, together with aluminoxanes as cocatalysts, a very effective catalyst system for the preparation of polyolefins of high stereospecificity and high melting point.
摘要翻译： 其中优选M1是Zr或Hf，R1和R2是烷基或卤素的式Ⅰ'（Ⅰ）的新金属茂，R3和R4是氢，R5和R6是烷基或卤代烷基， - （CR8R9） m-R7-（CR8R9）n-是单或多元链，其中R7也可以是（取代的）杂原子，m + n是0或1，R10是氢，与铝氧烷一起形成， 助催化剂，用于制备高立体定向性和高熔点的聚烯烃的非常有效的催化剂体系。
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公开(公告)号：US5232993A
公开(公告)日：1993-08-03
申请号：US630262
申请日：1990-12-19
IPC分类号： C08L23/16 , C08F2/00 , C08F4/60 , C08F4/622 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F210/06 , C08F210/16 , C08F297/08 , C08L23/00 , C08L23/10 , C08L23/14 , C08L53/00
CPC分类号： C08L23/10 , C08F297/083 , C08L23/142 , C08L23/14 , C08L23/16 , C08L2308/00 , Y10S526/943
摘要： A polypropylene molding composition having syndiotactic polymer chains is obtained in a high yield by the copolymerization of propylene with ethylene or a 1-olefin of the formula R.sup.a --CH.dbd.CH--R.sup.b in the presence of a catalyst comprising a metallocene of the formula I ##STR1## in which M.sup.1 is titanium, zirconium, hafnium, vanadium, riobium or tantalum, and an aluminoxane. This molding composition has a very high molecular weight, a very narrow molecular-weight distribution and very high syndiotaxy. Shaped articles produced from the molding composition are distinguished by high transparency, flexibility, bear strength and excellent surface luster.
摘要翻译： 通过丙烯与乙烯或式Ra-CH = CH-Rb的1-烯烃在含有式I的茂金属的催化剂的存在下共聚而获得具有间同立构聚合物链的聚丙烯模塑组合物， （I）其中M1是钛，锆，铪，钒，核锂或钽，铝氧烷。 该成型组合物具有非常高的分子量，非常窄的分子量分布和非常高的间规。 由模塑组合物制成的成型品的特征在于高透明度，柔韧性，承载强度和优异的表面光泽。
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公开(公告)号：US5216095A
公开(公告)日：1993-06-01
申请号：US697771
申请日：1991-05-09
申请人： Volker Dolle , Martin Antberg , Jurgen Rohrmann , Andreas Winter
发明人： Volker Dolle , Martin Antberg , Jurgen Rohrmann , Andreas Winter
IPC分类号： C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F8/00 , C08F10/00 , C08F110/06
CPC分类号： C08F10/00 , C08F110/06 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： Olefins of the formulaR.sup.11 --CH.dbd.CH--R.sup.12(R.sup.11 and R.sup.12 =H or C.sub.1 -C.sub.14 -alkyl) are polymerized in the presence of a catalyst comprising at least one metallocene of the formula I ##STR1## (M=zirconium or hafnium) and an aluminoxane, giving polymers of high molecular weight in high yield.
摘要翻译： 在包含至少一种式I的茂金属（I）的催化剂存在下，使式R 11 -CH = CH-R 12（R 11和R 12 = H或C 1 -C 14 - 烷基）的烯烃聚合（M = 锆或铪）和铝氧烷，以高产率得到高分子量的聚合物。
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