摘要:
A method for increasing adhesion between a substrate and a polymeric imprintable material during an imprinting procedure. The method includes chemically bonding a plurality of molecules to a surface of a substrate to form a self-assembled monolayer thereon. A monomer is copolymerized with the self-assembled monolayer to form a polymeric imprintable material that is chemically bonded to the self-assembled monolayer. Adhesion between the polymeric imprintable material and the substrate is substantially increased by the self-assembled monolayer.
摘要:
A method is provided for coating a surface having features thereon with a self-assembled monolayer for aiding release of the surface during an imprinting procedure. The method comprises exposing the surface to a vapor of a mold release agent.
摘要:
A method of forming features on substrates by imprinting is provided. The method comprises: (a) forming a polymer solution comprising at least one polymer dissolved in at least one polymerizable monomer; and (b) depositing the polymer solution on a substrate to form a liquid film thereon; and then either: (c) curing the liquid film by causing the monomer(s) to polymerize and optionally cross-linking the polymer(s) to thereby form a polymer film, the polymer film having a glass transition temperature (Tg); and imprinting the polymer film with a mold having a desired pattern to form a corresponding negative pattern in the polymer film, or (d) imprinting the liquid film with the mold and curing it to form the polymer film. The temperature of imprinting is as little as 10° C. above the Tg, or even less if the film is in the liquid state. The pressure of the imprinting can be within the range of 100 to 500 psi.
摘要:
An improved method of forming features on substrates by imprinting is provided. In the method, a polymer solution that contains at least one polymer dissolved in at least one polymerizable monomer and the polymer solution is deposited on the substrate to form a liquid film thereon. Further, the liquid film is cured by causing the at least one monomer to polymerize and optionally cross-linking the at least one polymer to thereby form a polymer film, the polymer film having a glass transition temperature of less than 100° C., and the polymer film is imprinted with a mold having a desired pattern to form a corresponding negative pattern in the polymer film. Alternatively, the liquid film is imprinted with the mold and the liquid film is cured in the presence of the mold to form the polymer film with the negative pattern.
摘要:
A method for increasing adhesion between a substrate and a polymeric imprintable material during an imprinting procedure. The method includes chemically bonding a plurality of molecules to a surface of a substrate to form a self-assembled monolayer thereon. A monomer is copolymerized with the self-assembled monolayer to form a polymeric imprintable material that is chemically bonded to the self-assembled monolayer. Adhesion between the polymeric imprintable material and the substrate is substantially increased by the self-assembled monolayer.
摘要:
The present invention is drawn to surface-crosslinked latex particulates, corresponding latex suspensions, ink-jet inks, and methods for making the latex particulates. A latex suspension can include a fluid medium and surface-crosslinked latex particulates. The surface-crosslinked latex particulates can be devoid of substantially all crosslinking below the particulate surface. Such surface-crosslinked latex particulates can be prepared with a plurality of monomers and at least one crosslinking agent.
摘要:
The present disclosure is drawn to methods and compositions directed at durable ink-jet inks. As such, an ink-jet ink can have a liquid vehicle, a colorant dispersed or dissolved in the liquid vehicle, a high Tg polymer having a Tg of at least 45.degree. C. dispersed in the liquid vehicle, and a near-infrared absorbing dye in the liquid vehicle. The ink can be formulated such that when printed on a substrate and irradiated with a near-infrared energy source, the near-infrared absorbing dye generates enough heat to uniformly melt the high Tg polymer, thereby enhancing the durability of ink-jet ink printed on the substrate.
摘要:
The present disclosure includes compositions, methods, and systems having an ink-jet ink including a liquid vehicle, a colorant dispersed or dissolved in the liquid vehicle, inter-crosslinkable latex particles dispersed in the liquid vehicle, and an inter-particle crosslinker. The inter-crosslinkable latex particles can have at least one hydrophobic monomer; at least one acidic monomer; at least one inter-crosslinkable monomer including at least one keto group; the inter-crosslinkable monomer having the structure described in Formula 1. Additionally, the inter-crosslinkable latex particles can be intra-crosslinked forming an inter-particle crosslinked latex polymer film after printing and upon at least partial depletion of the liquid vehicle or liquid vehicle component.
摘要:
An ink is disclosed. The ink includes a carrier fluid; an encapsulated metallic pigment particle further including a metallic pigment particle and a polymer, wherein the polymer covers between 70% and 100%, inclusive, of the surface area of the metallic pigment particle and wherein the morphology of the metallic pigment particle by itself is substantially the same as the morphology of the metallic pigment particle covered by the polymer; and a polymer resin.
摘要:
A water-soluble phthalocyanine dye or naphthalocyanine dye with near-infrared absorption comprises at least one complexed unit. Each unit comprises a phthalocyanine or a naphthalocyanine moiety and a metal atom complexed thereto and having a valency of at least three, with two valencies complexed to the phthalocynanine ring or the naphthalocyanine ring, each unit joined to another through a fused ring, at least one valency attached to water-soluble axial ligands. The dyes to may be employed in inkjet inks in conjunction with colorants.