公开(公告)号：US20240100495A1

公开(公告)日：2024-03-28

申请号：US17768924

申请日：2020-10-16

Applicant: HTE GmbH The High Throughput Experimentation Company ,  Consejo Superior de Investigaciones Cientificas (CSIC) ,  Universitat Politecnica de Valencia (UPV)

Inventor： Marius Kirchmann ,  Edgar Jordan ,  Alfred Haas ,  Sascha Hubert Vukojevic ,  Michael Dejmek ,  Oliver Koechel ,  Avelino Corma

IPC: B01J8/08 ,  B01J8/00 ,  C10G11/16

CPC classification number: B01J8/087 ,  B01J8/0015 ,  C10G11/16 ,  B01J2208/00292 ,  B01J2208/00752

Abstract: The invention relates to a process for carrying out reactions on preheated particles, comprising: (a) providing particles in a buffer container; (b) feeding the particles from the buffer container into a reactor via a feed line; (c) withdrawing the particles from the reactor, wherein the particles are heated in the feed line.

公开(公告)号：US20210003502A1

公开(公告)日：2021-01-07

申请号：US16978333

申请日：2019-03-15

Applicant: hte GmbH the high throughput experimentation company

Inventor： Marius Kirchmann ,  Christoph Hauber

IPC: G01N21/3504 ,  G01N21/85 ,  G01N30/02 ,  G01N33/28 ,  G06N20/00

Abstract: The invention relates to a method for investigating process streams comprising five or more different hydrocarbon-containing components. In the method at least one process flow line (35) is in operative connection with an online IR spectrometer (2) and an online gas chromatograph (1). The process stream passed through the process stream conduit (35) is subjected to an online characterization which comprises measurements both with the online IR spectrometer and with an online gas chromatograph. The spectral data and the chromatography data are mathematically related to one another by suitable statistical models, thus allowing training of a model used for evaluating the analytical data and for characterizing the process streams. The method according to the invention is characterized by short measurement times in the range of seconds and milliseconds and a high accuracy. The method according to the invention for investigating process streams preferably relates to investigation of process streams deriving from processes proceeding in parallel, the process streams preferably deriving from reaction spaces arranged in parallel.

公开(公告)号：US20230226509A1

公开(公告)日：2023-07-20

申请号：US17919617

申请日：2021-04-19

Applicant: HTE GMBH THE HIGH THROUGHPUT EXPERIMENTATION COMPANY

Inventor： Marius Kirchmann ,  Kurt-Erich Finger ,  Markus Friess

IPC: B01J8/18 ,  B01J8/22 ,  B01J8/00 ,  G01N31/10 ,  C10G11/18 ,  B01D45/08

CPC classification number: B01J8/1809 ,  B01D45/08 ,  B01J8/0065 ,  B01J8/228 ,  B01J8/1863 ,  B01J8/1881 ,  C10G11/187 ,  G01N31/10 ,  B01J2208/00539 ,  B01J2208/00628

Abstract: The invention relates to an apparatus for analyzing heterogeneously catalyzed reactions comprising at least one reactor (3) through which a particulate catalyst flows and at least one reactant feed, wherein arranged downstream of each reactor (3) is a separation apparatus (17) for separating the particulate catalyst from a reaction product comprising condensable gases and arranged downstream of the separation apparatus (17) is a liquid separator (31) for separating liquid constituents from the reaction product, wherein the liquid separator (31) comprises a metallic tube (103) and a deflection body (119), wherein the metallic tube (103) is closed at its ends and the deflection body (119) is accommodated in the metallic tube (103) and the metallic tube (103) comprises a side feed (135) at a first end (105) and a gas outlet (113) at a second end (107) and the gas outlet (113) is connected to at least one sample vessel (37). The invention further relates to a process for analyzing heterogeneously catalyzed reactions in the apparatus.

公开(公告)号：US20210379553A1

公开(公告)日：2021-12-09

申请号：US17286320

申请日：2019-10-15

Applicant: hte GmbH the high throughput experimentation company

Inventor： Marius Kirchmann ,  Christoph Hauber ,  Edgar Jordan ,  Kurt-Erich Finger ,  Markus Friess ,  Oliver Koechel

IPC: B01J19/00 ,  G01N1/14 ,  G01N1/24

Abstract: The invention relates to an apparatus for analyzing reactions, comprising at least one reactor (1) and at least two sample vessels (13), wherein, in the case of an apparatus having one reactor (1), the reactor (1) is connected to at least two sample vessels (13), and, in the case of an apparatus having more than one reactor (1), each reactor (1) is connected to at least one sample vessel (13). The invention further relates to a method of analyzing reactions in such an apparatus.

公开(公告)号：US10774275B2

公开(公告)日：2020-09-15

申请号：US15541403

申请日：2015-12-22

Applicant: hte GmbH the high throughput experimentation company

Inventor： Marius Kirchmann ,  Christoph Hauber

IPC: C10G59/06 ,  C10G35/24 ,  B01J19/00 ,  B01J19/24 ,  G01N31/10 ,  G01N33/28

Abstract: An apparatus and a method are used for investigating the naphtha reforming process in catalyst test devices with reactors arranged in parallel. The apparatus has a plurality of reactors arranged in parallel with reaction chambers (R1, R2, . . . ), a product fluid supply, a process control, and at least one analysis unit. Each individual reactor has an outlet line for the product fluid stream, wherein the analysis unit is operatively connected to each outlet line for the product fluid stream and the apparatus is functionally connected to the control of the apparatus. In carrying out the method, naphtha-containing reactant fluid streams are brought into contact with catalysts in the individual reactors and the product fluid streams are subsequently supplied to the online analysis unit from the respective outlet lines of the individual reactors and analyzed. Using the evaluation of the online analytical characterization data, the process parameters of the respective reactor unit are adapted. The process steps of analytical characterization, evaluation, and adaptation of process parameters are repeated for the duration of the investigation.

公开(公告)号：US11953433B2

公开(公告)日：2024-04-09

申请号：US16978333

申请日：2019-03-15

Applicant: hte GmbH the high throughput experimentation company

Inventor： Marius Kirchmann ,  Christoph Hauber

IPC: G01N21/61 ,  G01N21/3504 ,  G01N21/85 ,  G01N30/02 ,  G01N33/28 ,  G06N20/00 ,  G01N21/84 ,  G01N30/88

CPC classification number: G01N21/3504 ,  G01N21/85 ,  G01N30/02 ,  G01N33/2829 ,  G06N20/00 ,  G01N2021/8411 ,  G01N2030/025 ,  G01N2030/8886

Abstract: The invention relates to a method for investigating process streams comprising five or more different hydrocarbon-containing components. In the method at least one process flow line (35) is in operative connection with an online IR spectrometer (2) and an online gas chromatograph (1). The process stream passed through the process stream conduit (35) is subjected to an online characterization which comprises measurements both with the online IR spectrometer and with an online gas chromatograph. The spectral data and the chromatography data are mathematically related to one another by suitable statistical models, thus allowing training of a model used for evaluating the analytical data and for characterizing the process streams. The method according to the invention is characterized by short measurement times in the range of seconds and milliseconds and a high accuracy. The method according to the invention for investigating process streams preferably relates to investigation of process streams deriving from processes proceeding in parallel, the process streams preferably deriving from reaction spaces arranged in parallel.