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1.发明授权Catalysts support, a supported group VIII metal catalyst and precursor thereof, processes for their preparations, and use of the supported group VIII metal catalyst 失效催化剂载体，负载的VIII族金属催化剂及其前体，其制备方法和使用负载的VIII族金属催化剂公开(公告)号：US07282467B2
公开(公告)日：2007-10-16
申请号：US10332094
申请日：2001-07-10
申请人： Hans Michiel Huisman , Gerardus Petrus Lambertus Niesen , Johannes Jacobus Maria Van Vlaanderen
发明人： Hans Michiel Huisman , Gerardus Petrus Lambertus Niesen , Johannes Jacobus Maria Van Vlaanderen
CPC分类号： C10G2/332 , B01J23/74 , B01J23/8892 , B01J37/0045 , B01J37/0236
摘要： A process for preparing a catalyst support or a supported Group VIII metal catalyst or a precusor of the supported Group VIII metal catalyst, which process comprises (a) exerting mechanical power on a mixture comprising a refractory oxide and a first liquid to obtain a dough, (b) admixing the dough with a second liquid to obtain a slurry, (c) shaping and drying the slurry, and (d) calcining.
摘要翻译： 制备催化剂载体或负载的VIII族金属催化剂或负载的VIII族金属催化剂的前体的方法，该方法包括（a）在包含难熔氧化物和第一液体的混合物上施加机械动力以获得面团， （b）将面团与第二液体混合以获得浆料，（c）成型并干燥浆料，和（d）煅烧。
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公开(公告)号：US06861383B2
公开(公告)日：2005-03-01
申请号：US10181597
申请日：2001-01-19
IPC分类号： B01J21/06 , B01J21/20 , B01J38/12 , B01J38/60 , B01J38/64 , B01J38/66 , B01J38/68 , C07B61/00 , C07D301/12 , C07D301/19 , B01J20/34
CPC分类号： C07D301/19 , B01J21/20 , B01J38/12 , B01J38/60 , B01J38/66 , Y02P20/584
摘要： A process for the preparation of a catalyst support material involving the steps of: (a) subjecting a used titania-on-silica catalyst to a decoking treatment, (b) washing the decoked catalyst with a washing liquid selected from an aqueous solution of a mineral acid, an aqueous solution of an ammonium salt and combinations thereof, and (c) drying and calcining the washed and decoked catalyst to yield the catalyst support material. The support material thus obtained is suitably used as support material for titania in a heterogeneous catalyst for the epoxidation of olefins into alkylene oxides.
摘要翻译： 一种制备催化剂载体材料的方法，包括以下步骤：（a）使用二氧化钛 - 二氧化硅催化剂进行脱焦处理，（b）用选自以下的洗涤液体洗涤脱色催化剂： 无机酸，铵盐的水溶液及其组合，以及（c）干燥和煅烧洗涤过的和经过开馏的催化剂以产生催化剂载体材料。 由此获得的载体材料适合用作用于将烯烃环氧化成环氧烷烃的非均相催化剂中的二氧化钛的载体材料。
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3.发明授权公开(公告)号：US07763564B2
公开(公告)日：2010-07-27
申请号：US11743003
申请日：2007-05-01
IPC分类号： B01J27/135 , B01J27/045 , B01J27/06 , B01J21/00 , C01B33/12 , C07D303/00
CPC分类号： C07D301/19 , B01J21/063 , B01J37/0209 , B01J37/0238 , B01J37/08
摘要： The invention relates to a process for the preparation of a titanium catalyst which process comprises: (a) drying a silica carrier at a temperature of from 300 to 800° C. to obtain a dried carrier; (b) contacting the dried carrier obtained in step (a) with a gas stream containing titanium halide at a temperature in the range from 125° C. lower to 125° C. higher than the drying temperature of step (a) and at a pressure higher than 0.8 bar to obtain an impregnated carrier; (c) calcining the impregnated carrier obtained in step (b) to obtain the titanium catalyst.
摘要翻译： 本发明涉及一种制备钛催化剂的方法，该方法包括：（a）在300至800℃的温度下干燥二氧化硅载体以获得干燥的载体; （b）使步骤（a）中获得的干燥载体与步骤（a）的干燥温度比125℃低至125℃的温度范围内与含有卤化钛的气流接触，并且在 压力高于0.8巴，得到浸渍载体; （c）煅烧步骤（b）中获得的浸渍载体以获得钛催化剂。
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公开(公告)号：US07713906B2
公开(公告)日：2010-05-11
申请号：US10312099
申请日：2001-06-21
申请人： Paul Blankenstein , Mark Crocker , Carl Johan Gerrit Van Der Grift , Johannes Jacobus Maria Van Vlaanderen
发明人： Paul Blankenstein , Mark Crocker , Carl Johan Gerrit Van Der Grift , Johannes Jacobus Maria Van Vlaanderen
IPC分类号： B01J21/00 , C07D301/14 , C07D301/12 , C07D301/06
CPC分类号： C07D301/19 , B01J21/063 , B01J21/08 , B01J37/0009 , B01J37/0203 , B01J37/0238
摘要： A catalyst composition comprising titanium incorporated into a silica support, characterized in that the silica support is a shaped extrudate of silica powder. The catalyst composition is useful in the epoxidation of olefins into alkylene oxides using organic hydroperoxides. The composition can be prepared by extruding silica powder into an extrudate having a selected shape; calcining the extrudate; impregnating the extrudate with a titanium-containing impregnating agent; and drying and calcining the impregnated extrudate.
摘要翻译： 一种包含掺入二氧化硅载体中的钛的催化剂组合物，其特征在于二氧化硅载体是二氧化硅粉末的成形挤出物。 催化剂组合物可用于使用有机氢过氧化物将烯烃环氧化成烯化氧。 可以通过将二氧化硅粉末挤出到具有选定形状的挤出物中来制备组合物; 煅烧挤出物; 用含钛浸渍剂浸渍挤出物; 并干燥和煅烧浸渍的挤出物。
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5.发明申请公开(公告)号：US20070260074A1
公开(公告)日：2007-11-08
申请号：US11743003
申请日：2007-05-01
IPC分类号： B01J21/00 , C07D301/19
CPC分类号： C07D301/19 , B01J21/063 , B01J37/0209 , B01J37/0238 , B01J37/08
摘要： The invention relates to a process for the preparation of a titanium catalyst which process comprises: (a) drying a silica carrier at a temperature of from 300 to 800° C. to obtain a dried carrier; (b) contacting the dried carrier obtained in step (a) with a gas stream containing titanium halide at a temperature in the range from 125° C. lower to 125° C. higher than the drying temperature of step (a) and at a pressure higher than 0.8 bar to obtain an impregnated carrier; (c) calcining the impregnated carrier obtained in step (b) to obtain the titanium catalyst.
摘要翻译： 本发明涉及一种制备钛催化剂的方法，该方法包括：（a）在300至800℃的温度下干燥二氧化硅载体以获得干燥的载体; （b）使步骤（a）中获得的干燥载体与步骤（a）的干燥温度比125℃低至125℃的温度范围内与含有卤化钛的气流接触，并且在 压力高于0.8巴，得到浸渍载体; （c）煅烧步骤（b）中获得的浸渍载体以获得钛催化剂。
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