摘要:
A water-absorbing, expanded, crosslinked polymer obtainable by (I) foaming a polymerizable aqueous mixture which comprises (a) monoethylenically unsaturated monomers which contain acidic groups and are optionally neutralized, (b) optionally other monoethylenically unsaturated monomers, (c) crosslinkers, (d) initiators, (e) 0.1-20% by weight of at least one surfactant, (f) optionally at least one solubilizer and (g) optionally thickeners, foam stabilizers, polymerization regulators, fillers and/or cell nucleating agents, where the foaming takes place by dispersing fine bubbles of a gas which is inert to free radicals in the polymerizable aqueous mixture, and (II) polymerizing the foamed mixture to form an expanded hydrogel, whereby at least 20 mol % of the monomers (a) which contain acidic groups have been neutralized with tertiary alkanolamines and/or the free acidic groups of the expanded hydrogel have been at least 20 mol % neutralized with at least one alkalolamine after the polymerization, and, where appropriate, adjusting the water content of the expanded polymer to 1-60% by weight, the production thereof and the use thereof in hygiene articles employed to absorb body fluids and in dressing material for covering wounds.
摘要:
Disclosed is a method for determining the swellability and the swelling kinetics of superabsorbent material (9) such as polymer gels, for example, which comprises introducing a defined volume of the dry superabsorbent material (9) into a measuring vessel (7), using a movable element (4) within said measuring vessel (7) to apply a restraining force (12) to said superabsorbent material (9) and capturing the expansion of said superabsorbent material (9) contactlessly within a chamber (14) in a continuous manner by capturing the change in height of a piston (4) which bounds said chamber (14), travels in a measuring vessel (7) and is marked with a height scale (6).
摘要:
Hydrophilic open-celled resilient foams containing melamine-formaldehyde resins, characterized by a droplet absorption rate of less than 5 seconds and an EU standard EN ISO 14184-1 formaldehyde emission of less than 100 mg of formaldehyde/kg of foam, and obtainable by (a) heating an aqueous solution or dispersion each containing at least a melamine-formaldehyde precondensate, an emulsifier, a blowing agent and a curing agent to form a foam and crosslink the precondensate, (b) then conditioning the foam at from 120 to 300° C. for from 1 to 180 minutes to remove volatiles, and (c) treating the foam during the conditioning or thereafter with at least one hydrophilicizer and/or with ozone, a corona discharge or a plasma, are useful in hygiene articles to acquire, distribute and immobilize body fluids.
摘要:
Foams composed of water-absorbing basic polymers, obtainable by (I) foaming a crosslinkable aqueous mixture including (a) at least one basic polymer whose basic groups have optionally been neutralized, (b) at least one crosslinker, (c) at least one surfactant, (d) optionally at least one solubilizer, (e) optionally thickeners, foam stabilizers, fillers, fibers and/or cell nucleators, and (f) optionally particulate water-absorbing acidic polymers, by dissolving a gas which is inert toward free radicals in the crosslinkable aqueous mixture under a pressure from 2 to 400 bar and subsequently decompressing the crosslinkable aqueous mixture to atmospheric or by dispersing fine bubbles of a gas which is inert toward free radicals, and (II) crosslinking the foamed mixture to form a hydrogel foam and if applicable adjusting the water content of the polymer foam to 1-60% by weight. Preparation of the foams by application of the abovementioned measures (I) and (II) and use of the thus obtainable foams in hygiene articles to absorb body fluids, in dressing material to cover wounds, as a sealing material, as a packaging material, as a soil improver, as a soil substitute, to dewater sludges, to absorb aqueous acidic wastes, to thicken waterborne paints or coatings in the course of disposing of residual quantities thereof, to dewater water-containing oils or hydrocarbons or as a material for filters in ventilation systems.
摘要:
A device for filling and compacting pourable products is proposed, comprising: —at least one product feed (16) for feeding a pourable product to a container (12) that is to be filled, —at least one ram (14) for compacting the product supplied to the container (10), characterized by means for applying a predetermined force to the ram (14) and for detecting the force acting on the ram.
摘要:
The invention relates to a printable composition having a viscosity of 1-1000 mPas and comprising a) 5-50% by weight of superabsorbent polymeric particles, b) 10-40% by weight of at least one organic, water-insoluble binder, c) 0-10% by weight of at least one additive and d) 40-80% by weight of at least one organic solvent. The invention further relates to sheetlike materials printed with the printable composition on at least one surface. The invention further relates to the use of the printed sheetlike materials for food packaging, for packaging moisture-sensitive goods, for moisture control in rooms, or as a membrane in textiles.
摘要:
The present invention relates to polymerized hydrogels and processes to make such hydrogels, in particular hydrogel adhesives which are capable of attaching to mammalian skin and can be used in various personal care products, such as waste-management articles, and a variety of functional articles to be worn by a human. The hydrogels described herein are characterized by very low amount of residual starting monomers, impurities, and/or by-products that could be formed during polymerization. Specifically, the hydrogels are made by adding scavengers and/or chain transfer agent prior to polymerization. It has been found, that upon addition of same scavengers the material properties of the polymerized hydrogel differ from the properties of gels polymerized without the scavenger. This is due to the fact, that these specific scavengers act also as chain transfer agents in the radical polymerization. Further studies showed that also chain transfer agents, that are no scanvengers for residual monomer(s), impurities or byproducts influence the material properties of the polymerized hydrogel adhesive.
摘要:
A fluorescent lamp 1 for exterior lighting having a discharge tube 2 of less than or equal to 26 mm outside diameter. Starting from a fluorescent lamp for interior use having a discharge tube 2 of less than or equal to 26 mm, it is possible to achieve optimum operation of the fluorescent lamp 1 in the case of exterior use by applying a thermally conducting material in the form of a coating of foil 15, 16 outside on the discharge tube 2 in the region of one or both electrodes 3, 4.
摘要:
An electronic circuit for processing measured values obtained from a vortex sequence produced by a Karman vortex path, wherein the ultrasonically sensed signals are processed both digitally in a first circuit branch for a computer and analogously in a second circuit branch for the connection of a two-channel continuous recorder. An adjustable frequency transforming arrangement is serially connected in the computer branch for balancing the circuit, and an additional frequency-voltage converter and and integrator are serially connected in the recorder branch along with a control logic circuit inserted between the two branches for starting the recorder after activation of the computer only when signals which can be evaluated are present.
摘要:
A diverter for a rain barrel includes a scoop portion configured to fit within a gutter downspout, a rain barrel fitting portion configured to fluidly attach the scoop portion to the rain barrel, and a wing extending outwardly from the scoop portion to direct a flow of water in the gutter downspout towards the scoop portion.