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1.发明授权
公开(公告)号：US4789752A
公开(公告)日：1988-12-06
申请号：US878198
申请日：1986-06-25
CPC分类号： C07F7/006
摘要： The present invention relates to the esterification of the halides of titanium, zirconium or hafnium. The esterification takes place in two steps. The first step is performed in the absence of acid acceptors, and the alcohol is introduced into the metal halide dissolved in a solvent, without any appreciable contact with the gas phase. The reactor must be held at the boiling temperature. In this step at least half of the alcohol needed for the entire reaction is used. The second esterification step is performed in a known manner with the addition of acid acceptors after the hydrogen halide that formed in the first esterification step has been removed.
摘要翻译： 本发明涉及钛，锆或铪的卤化物的酯化。 酯化反应分两步进行。 第一步是在不存在酸受体的情况下进行，并且将醇引入溶解在溶剂中的金属卤化物中，而不与气相明显接触。 反应器必须保持在沸腾温度。 在该步骤中，使用整个反应所需的醇的至少一半。 第二酯化步骤在已经除去在第一酯化步骤中形成的卤化氢之后，以已知的方式加入酸受体来进行。
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公开(公告)号：US4642363A
公开(公告)日：1987-02-10
申请号：US769943
申请日：1985-08-27
IPC分类号： C07F7/18
CPC分类号： C07F7/188
摘要： A method for the continuous or batch preparation of trialkyl organo-oxysilanes by reaction of organic hydroxy compounds with trialkyl halogen silanes in the absence of acid-binding substances is disclosed. The organic hydroxy compound is added directly to the trialkoxy halogen silane in an amount which corresponds to no more than the stoichiometrically necessary amount. The trialkyl halogen silane, or the resultant mixture is always at the boiling temperature or above the boiling temperature in the gaseous state. The reaction mixture is subjected, no later than toward the end of the reaction, to a column distillation in which the column temperature is held such that the reaction is carried to the end within the column. In continuous operation, the trialkyl halogen silane is introduced in gaseous form into the bottom of a column and either kept under reflux or introduced into a reactor into which corresponding stoichiometric amounts of organic hydroxy compound are simultaneously introduced. In the column, either a raw product or freshly introduced organic hydroxy compound in liquid form flows against the gaseous trialkyl halogen silane, and the desired trailkyl organo-oxysilane collects at ebullition on the floor of the column and is continuously removed.
摘要翻译： 公开了通过在不存在酸结合物质的情况下通过有机羟基化合物与三烷基卤素硅烷的反应连续或分批制备三烷基有机 - 氧代硅烷的方法。 将有机羟基化合物直接加入到三烷氧基卤代硅烷中，其量不超过化学计量所需量。 三烷基卤硅烷或所得混合物总是处于沸腾温度或高于气态沸点温度。 将反应混合物在不迟于反应结束的条件下进行柱馏分，其中保持柱温，使得反应进行到塔内的末端。 在连续操作中，三烷基卤代硅烷以气态形式引入塔的底部，并保持回流或引入反应器中，同时引入相应化学计量的有机羟基化合物。 在柱中，原料或新引入的液体形式的有机羟基化合物流向气态三烷基卤代硅烷，并且所需的烷基有机 - 氧代硅烷在塔的底部沸腾收集并连续除去。
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3.发明授权
公开(公告)号：US4824979A
公开(公告)日：1989-04-25
申请号：US810514
申请日：1985-12-18
CPC分类号： C07F7/006
摘要： Disclosed is a new method for the preparation of metallic acid esters of titanium, zirconium or hafnium wherein a halide of the metal reacts with an organosilane ester, resulting in the formation of partial esters of the metallic acids. The degree of esterification of the metallic acid ester can be controlled based on the organosilane ester and it is possible to obtain complete esterification of the metal halides. The metallic acid partial esters prepared by the method are very pure, and can be separated selectively from the mixture in a simple manner. The metallic acid alkyl esters obtained can very easily be further esterified to the metallic acid tetraalkyl esters with the formation of very pure tetraalkyl esters.
摘要翻译： 公开了一种制备钛，锆或铪的金属酸酯的新方法，其中金属的卤化物与有机硅烷酯反应，导致形成金属酸的偏酯。 可以基于有机硅烷酯来控制金属酸酯的酯化程度，并且可以获得金属卤化物的完全酯化。 通过该方法制备的金属酸偏酯是非常纯的，并且可以以简单的方式从混合物中选择性地分离。 获得的金属酸性烷基酯可以非常容易地进一步酯化成金属酸四烷基酯，形成非常纯的四烷基酯。
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4.发明授权公开(公告)号：US06294682B1
公开(公告)日：2001-09-25
申请号：US09077671
申请日：2000-06-19
申请人： Hartwig Rauleder , Burkhard Standke , Michael Horn , Hans-Joachim Kotzsch , Hans-Gunther Srebny
发明人： Hartwig Rauleder , Burkhard Standke , Michael Horn , Hans-Joachim Kotzsch , Hans-Gunther Srebny
IPC分类号： C07F1900
CPC分类号： D21H25/18 , C07F7/003 , C08F10/00 , C08F4/6548
摘要： The invention concerns solutions of alkoxides containing titanium and/or zirconium and/or hafnium and magnesium and/or calcium and/or strontium and/or barium of general formula (I): [MII(OR)2-y(OR1)y]n.[MIV(OR1)4-z(OR)2], in which: MII means magnesium and/or calcium and/or strontium and/or barium; MIV titanium and/or zirconium and/or hafnium; R is an alkyl group with 1 to 18 carbon atoms; R1 is an alkyl group with 1 to 18 carbon atoms, y has a value of between 0 to 2; z has a value of 0 and 4; and n is a number between 0.001 and 3, with the exception that n cannot be 1 when y is 2 and z is 0, or when y is 0 and z is 4. The invention further concerns the production of these alkoxides and their use.
摘要翻译： 本发明涉及含有钛和/或铪和/或铪以及通式（I）的镁和/或钙和/或锶和/或钡的醇盐的溶液：[MII（OR）2-y（OR 1）y] n。[MIV（OR1）4-z（OR）2]，其中：MII表示镁和/或钙和/或锶和/或钡; MIV钛和/或锆和/或铪; R是具有1至18个碳原子的烷基; R1是具有1至18个碳原子的烷基，y具有在0至2之间的值; z的值为0和4; 并且n是0.001至3之间的数字，除了当y为2且z为0时，或当y为0且z为4时，n不能为1时。本发明还涉及这些醇盐的生产及其用途。
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公开(公告)号：US4647681A
公开(公告)日：1987-03-03
申请号：US800996
申请日：1985-11-22
CPC分类号： C07F7/1896 , C07F7/10
摘要： Disclosed is a method of preparing bis-trimethylsilylamides of carboxylic acids from the carboxylic acid amide by mixing two equivalents of trimethylchlorosilane and an excess of hexamethyldisilazane, heating the mixture to 40.degree. to 80.degree. C. and adding two equivalents of a tertiary amine as acid acceptor. The method results in substantially improved purity and yield of end product.
摘要翻译： 公开了通过混合两当量的三甲基氯硅烷和过量的六甲基二硅氮烷从羧酸酰胺制备羧酸的双三甲基甲硅烷基酰胺的方法，将该混合物加热至40℃至80℃，并加入两当量的叔胺作为酸 受体。 该方法导致最终产物的纯度和产率显着提高。
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公开(公告)号：US4467105A
公开(公告)日：1984-08-21
申请号：US422612
申请日：1982-09-24
IPC分类号： C07F7/18 , C08G65/336 , C08G77/60 , C07F7/04 , C07F7/08
CPC分类号： C07F7/1824 , C08G65/336 , C08G77/60 , C10M2227/04 , C10N2240/08
摘要： The present invention relates to a method of preparing dimeric or polymeric organosilane esters whose ester component is at least one glycol moiety and whose silicon atoms are linked together by a glycol moiety. These compounds are known and are used as hydraulic fluids whose preparation involves considerable difficulty. The present invention avoids these difficulties by setting out from organosilane diglycol esters or triglycol esters and transposing them with diglycols or polyglycols. In this transposition the glycol ether corresponding to the glycols is formed and is removed by distillation. The degree of condensation of the organosilane ester products depends on the weight-ratio of the organosilane glycol ester to the diglycols or polyglycols.
摘要翻译： 本发明涉及一种制备二聚或聚合的有机硅烷酯的方法，其酯组分是至少一个二醇部分，其硅原子通过二醇部分连接在一起。 这些化合物是已知的并且用作其制备涉及相当困难的液压油。 本发明通过从有机硅烷二甘醇酯或三甘醇酯中排出并用二甘醇或聚二醇转置来避免这些困难。 在这种转置中，形成对应于二醇的二醇醚，并通过蒸馏除去。 有机硅烷酯产物的缩合度取决于有机硅烷二醇酯与二甘醇或聚二醇的重量比。
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7.发明授权Siliceous dioxolane derivatives and their application to the manufacture of organosilane esters containing epoxy groups 失效二氧化硅二氧化硅衍生物及其在制备含环氧基团的有机硅烷酯中的应用
公开(公告)号：US4213908A
公开(公告)日：1980-07-22
申请号：US635533
申请日：1975-11-26
CPC分类号： C07F7/1804 , B22C1/205 , C07F7/182
摘要： Glycidyloxypropylalkoxysilanes are produced by thermal treatment of novel siliceous dioxolane derivatives of the formula: ##STR1## wherein a is 0 or 1 and R represents an oxygen radical or two hydrogen atoms and R' and R" each represents an alkyl radical, wherein the R" 's can be the same or different. The glycidyl products are useful as adhesives.
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公开(公告)号：US4028384A
公开(公告)日：1977-06-07
申请号：US418793
申请日：1973-11-23
IPC分类号： B01J31/22 , C07F7/14 , C07F7/18 , C07D307/12 , C07F7/02
CPC分类号： C07F7/1804 , B01J31/2208 , B01J31/2291 , C07F7/14 , B01J2231/323 , B01J2531/828
摘要： The use of certain chloroplatinic complex compounds of the formula:[Pt R.sup.1 Cl.sub.2 ].sub.awherein a is 1 or 2 and R.sup.1 is an unsaturated ketone residue, to catalyze the addition of alkoxy, aryloxy or halo hydrogen silanes to aliphatically unsaturated compounds (carbon to carbon unsaturation such as olefins and/or acetylenes). The products of the reaction can be used as additives for plastics and synthetic resins.
摘要翻译： 使用下列化学式的某些氯铂配合物：
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9.发明授权
公开(公告)号：US4226793A
公开(公告)日：1980-10-07
申请号：US946464
申请日：1978-09-28
CPC分类号： C07F7/04
摘要： An improvement in a process for forming an orthosilicic acid ester or an oligomer thereof by contacting a tetrachlorosilane or higher homolog thereof with a primary alcohol, the improvement which comprises introducing the alcohol directly into a tetrachlorosilane liquid phase without said alcohol touching the gas phase and, after completion of the reaction, removing hydrogen chloride formed during the reaction from the reaction zone.
摘要翻译： 通过使四氯硅烷或其高级同系物与伯醇接触来形成正硅酸酯或其低聚物的方法的改进，其包括将醇直接引入四氯硅烷液相中而没有所述醇与气相接触， 反应完成后，从反应区除去反应期间形成的氯化氢。
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公开(公告)号：US4161486A
公开(公告)日：1979-07-17
申请号：US880903
申请日：1978-02-24
CPC分类号： C07F7/123
摘要： In a process for preparing a halogen alkyl silane by contacting an alkyl silane of the formulaR.sub.n SiR'.sub.4-nwhereinR represents a substituted or unsubstituted alkyl or alkenyl group,R' represents an alkyl group, andN represents 0, 1, or 2With a hydrogen halide in the presence of a catalyst, the improvement which comprises employing as the catalyst an aluminum oxide-containing composition.
摘要翻译： 在制备卤代烷基硅烷的方法中，通过使式R n SiR'4-n的烷基硅烷接触，其中R表示取代或未取代的烷基或烯基，R'表示烷基，N代表0,1或2 在催化剂存在下氢化氢，其包含作为催化剂包含氧化铝的组合的使用的改进。
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