摘要:
A coating composition comprising as binder a reaction product of a polyepoxide with more than one 1,2-epoxide group per molecule, wherein its epoxide groups have been reactedA. with 0.01 to 0.5 NH-equivalents, based on one epoxide equivalent, of ammonia or of an aliphatic or cycloaliphatic primary or secondary amine or of an amino carboxylic acid or of a mixture of the aforementioned nitrogen compounds; and subsequentlyB. with 0.40 to 0.90 carboxyl equivalents, based on one epoxide equivalent, of acrylic acid or methacrylic acid or of a mixture of acrylic amd methacrylic acid; and finallyC. with 0.09 to 0.50 carboxyl equivalents, based on one epoxide group, of a saturated aliphatic, a cycloaliphatic or an aromatic carboxylic acid, so that at least 80% of the epoxide groups originally present have been reacted through these three component stages. The binder may be used alone or together with additional monomers by radicals forming compounds or preferably by photopolymerization in the presence of a photoinitiator.
摘要:
The invention relates to a resin composition that is curable by ultra-violet light, which composition comprises(a) 10 to 99.7 percent by weight of a polyester that contains .alpha., .beta.-ethylenically unsaturated dicarboxylic acid radicals and .beta.,.gamma.-ethylenically unsaturated ether groupings, and(b) 0.3 to 10 percent by weight of a photoinitiator.
摘要:
An improved process for the production of lacquer binders from 1,2-polyepoxides having more than one 1,2-epoxide group per molecule, comprising the steps of:(a) reacting the 1,2-polyepoxide with from 0.01 to 0.6 NH-equivalents, based on one epoxide equivalent, of an optionally substituted active amine hydrogen containing ammonium carbonic acid salt;(b) reacting the thus obtained compound with from 0.40 to 0.90 carboxyl equivalent, based on on epoxide equivalent of acrylic acid, methacrylic acid or a mixture thereof; and optionally(c) reacting the compound obtained from step (b) with from 0.40 to 0.2 carboxyl equivalents, based on one epoxide group, or a saturated aliphatic monocarboxylic acid;so that at least 80% of the epoxide groups originally present are reacted.
摘要:
A radiation-hardenable binder consisting of a reaction product of:(A) 1 gramme equivalent of NCO of a polyisocyanate containing 2 to 3 isocyanate groups per molecule,(B) 0 to 0.7 gramme equivalents of OH of a polyol containing at least 2 OH-groups per molecule, free from organically combined sulphur,(C) 0.01 to 0.7 gramme equivalents of OH of a hydroxyalkyl acrylate containing 2 to 6 carbon atoms in the alkyl group characterized in that the reaction product additionally has incorporated therein:(D) 0.01 to 0.3 gramme equivalents of OH of a polyol containing thio or dithio groups or thio and dithio groups, with at least 2 OH-groups per molecule,the sum of the OH gramme equivalents B to D is from 1 to 1.2, and the content of organically combined sulphur, derived from the thio and dithio groups, is from 0.01 to 10% by weight, based on the binder.
摘要:
The invention relates to racemates of the formula (I) ##SPC1##in whichR.sub.1 and R.sub.2 are hydrogen, lower alkyl, methoxy, ethoxy or halogen,R.sub.3 is unsubstituted alkyl or lower alkyl substituted with alkoxy carbonyl carbonamido, cyano or hydroxyl or unsubstituted alkenyl or alkenyl substituted with halogen or halogen-, methyl-, ethyl-, methoxy- or ethoxy-substituted phenyl or unsubstituted cycloalkyl or cycloalkyl substituted with lower alkyl or unsubstituted phenylalkyl or phenylalkyl, the phenyl nucleus of which being substituted with methyl, methoxy, halogen or nitro, andR.sub.4 is unsubstituted alkyl or alkenyl or unsubstituted cycloalkyl or cycloalkyl substituted with lower alkyl or unsubstituted phenyl or phenyl substituted with lower alkyl methoxy, ethoxy or halogen or unsubstituted phenylalkyl or phenylalkyl, the phenyl nucleus of which being substituted with methyl, methoxy or halogen andX is oxygen or sulphur,Which are useful as photosensitizers for light induced polymerisations of vinyl monomers as well as for the light induced crosslinking of unsaturated polycondensates and polymers.
摘要:
Thermoplastic molding compositions containing thermoplastic, aromatic polycarbonates, graft polymers, special phosphorus compounds, antidripping agents and optionally other thermoplasts as well as conventional additives are disclosed. The compositions are characterized by their flame resistance and mechanical properties. Also disclosed is a process for the preparation of the molding compositions.
摘要:
The invention relates to powder-form polymer mixtures of silicone resins (B) and thermoplastic polymers (A), to their production and to their use for the modification of thermoplatics.
摘要:
The invention relates to flameproofed, non-dripping polyamide moulding compositions which contain certain amounts ofA) phosphinic acid esters of polyphenols based on phenol-aldehyde/ketone condensates,B) antidripping agents (such as polyfluoroethylene polymers or aramides) andC) zinc borateand if appropriate reinforcing agents and other additives for flameproofing and for processing etc.
摘要:
This invention relates to radiation hardenable primers based on prepolymers containing (meth) acryloyl groups and conventional auxiliary agents. The primers are characterized in that they contain organic and/or inorganic fibres having a fibre length distribution curve reaching its maximum in the region of from 50 to 600 .mu.m. These primers are suitable for coating articles which have absorbent surfaces, in particular for the continuous coating of wood-concrete articles such as wood-concrete boards.
摘要:
This invention relates to halogen-free flame retardant thermoplastic moulding compositions prepared from polycarbonate and graft polymer, which may optionally contain thermoplastic copolymer and/or polyalkylene terephthalate.The flame retardant used is a synergistic combination of silicone resin and polyphenylene oxide.