-
公开(公告)号：US4585798A
公开(公告)日：1986-04-29
申请号：US635911
申请日：1984-07-30
CPC分类号： C07C1/0445 , B01J23/75 , B01J23/894 , B01J37/14 , B01J37/18 , C07C2521/04 , C07C2523/10 , C07C2523/12 , C07C2523/46 , C07C2523/75
摘要： Synthesis gas comprising carbon monoxide and hydrogen is converted to a liquid hydrocarbon by contacting the synthesis gas under conversion conditions with a supported cobalt-ruthenium catalyst in which the cobalt to ruthenium molar ratio is greater than about 200:1. The catalyst is preferably prepared by using a non-aqueous impregnation solution and using an activation procedure involving reduction, oxidation and reduction.
摘要翻译： 包含一氧化碳和氢的合成气体通过在转化条件下与合成气与其中钴与钌摩尔比大于约200:1的负载型钴 - 钌催化剂接触而转化为液态烃。 催化剂优选通过使用非水性浸渍溶液并使用包括还原，氧化和还原的活化方法来制备。
-
2.发明授权Process for preparing gasoline range hydrocarbons from synthesis gas and catalyst used therefor 失效从合成气制备汽油范围烃的方法和用于其的催化剂
公开(公告)号：US4399234A
公开(公告)日：1983-08-16
申请号：US310972
申请日：1981-10-13
IPC分类号： C07C1/04
CPC分类号： C07C1/0435 , C07C2521/06 , C07C2523/10 , C07C2523/12 , C07C2523/83 , C07C2529/035
摘要： Synthesis gas is converted to a gasoline boiling range product high in branched chain paraffins and olefins utilizing a catalyst consisting essentially of (A) silicalite and (B) cobalt, preferably promoted with a Group IIIB or IVB metal oxide on an alumina support of gamma-alumina, eta-alumina or mixtures thereof.
摘要翻译： 使用基本上由（A）硅沸石和（B）钴组成的催化剂将合成气体转化为支链链烷烃和烯烃的高沸点汽油沸点产物，优选在γ-Al2O3的氧化铝载体上用IIIB或IVB族金属氧化物促进， 氧化铝，η-氧化铝或其混合物。
-
公开(公告)号：US4605680A
公开(公告)日：1986-08-12
申请号：US768923
申请日：1985-08-23
CPC分类号： C10G63/02 , B01J23/75 , B01J23/83 , C07C1/0445 , C07C2521/04 , C07C2521/06 , C07C2523/10 , C07C2523/12 , C07C2523/40 , C07C2523/46 , C07C2523/75 , C07C2527/06
摘要： Synthesis gas is converted to diesel fuel and a high octane gasoline in two stages. In the first stage the synthesis gas is converted to straight chain paraffins mainly boiling in the diesel fuel boiling range utilizing a catalyst consisting essentially of cobalt, preferably promoted with a Group IIIB or IVB metal oxide, on a support of gamma-alumina, eta-alumina or mixtures thereof. A straight chain paraffin portion of the effluent in the C.sub.5 -C.sub.9 range is converted in a second stage to a highly aromatic and branched chain paraffinic gasoline using a platinum group metal catalyst.
摘要翻译： 合成气体分两个阶段转化为柴油和高辛烷值汽油。 在第一阶段，使用主要由钴组成的催化剂，优选用IIIB或IVB族金属氧化物促进，将催化剂转化为主要以柴油燃料沸腾沸腾的直链烷烃，在γ-氧化铝， 氧化铝或其混合物。 在C5-C9范围内的流出物的直链石蜡部分在第二阶段中使用铂族金属催化剂转化成高度芳族和支链链烷烃汽油。
-
4.发明授权
公开(公告)号：US4717702A
公开(公告)日：1988-01-05
申请号：US876458
申请日：1986-06-20
CPC分类号： C07C1/0445 , B01J23/75 , B01J23/83 , B01J35/002 , B01J35/0053 , B01J35/023 , C07C2521/04 , C07C2521/06 , C07C2523/10 , C07C2523/12 , C07C2523/75
摘要： A catalyst for the conversion of synthesis gas comprising cobalt on a high surface area, high purity, low acidity alumina support of gamma-alumina, eta-alumina or mixtures thereof, whereby the catalyst is prepared by (A) impregnation of the alumina support with a non-aqueous, organic solvent impregnation solution of cobalt nitrate containing sufficient amounts of a Group IIIB or IVB metal salt to provide said catalyst with from about 0.05 to about 100 parts by weight of a Group IIIB or IVB metal oxide per 100 parts by weight cobalt, (B) reduction of the impregnated alumina support by heating, in the presence of hydrogen, at a heating rate of from about 0.5.degree. to about 5.degree. C. per minute to a maximum temperature in the range of 180.degree. to about 220.degree. C. for a hold time of 6 to about 24 hours and thereafter heating the impregnated alumina support in the presence of hydrogen while heating up to a maximum hold temperature of from about 250.degree. to about 400.degree. C. for a hold time of 6 to about 65 hours.
摘要翻译： 用于在高表面积上转化包含钴的合成气的催化剂，γ-氧化铝，η-氧化铝或其混合物的高纯度，低酸度氧化铝载体，由此通过（A）将氧化铝载体浸渍 含有足够量的IIIB或IVB族金属盐的硝酸钴的非水性有机溶剂浸渍溶液，以使所述催化剂每100重量份提供约0.05至约100重量份的IIIB或IVB族金属氧化物 钴，（B）在氢存在下，以每分钟约0.5℃至约5℃的加热速率加热浸渍的氧化铝载体的还原，至180℃至约220℃的最高温度 保持时间为6至约24小时，然后在氢气存在下加热浸渍的氧化铝载体，同时加热至约250℃至约400℃的最大保持温度，保持时间为6 t 约65小时。
-
公开(公告)号：US4605679A
公开(公告)日：1986-08-12
申请号：US734188
申请日：1985-05-15
CPC分类号： B01J37/0203 , B01J23/75 , B01J23/8913 , B01J23/894 , B01J37/14 , B01J37/18 , C07C1/0445 , C07C2521/04 , C07C2523/10 , C07C2523/12 , C07C2523/46 , C07C2523/75
摘要： Synthesis gas comprising carbon monoxide and hydrogen is converted to a liquid hydrocarbon by contacting the synthesis gas under conversion conditions with a catalyst prepared by subjecting a cobalt carbonyl-impregnated alumina or silica support to an activation procedure at a temperature not exceeding 500.degree. C. comprising, in sequence, (A) reduction in hydrogen, (B) oxidation in an oxygen-containing gas, and (C) reduction in hydrogen.
-
公开(公告)号：US4670414A
公开(公告)日：1987-06-02
申请号：US876730
申请日：1986-06-20
CPC分类号： C07C1/0445 , B01J23/75 , B01J23/894 , B01J37/14 , B01J37/18 , C07C2521/04 , C07C2523/10 , C07C2523/12 , C07C2523/46 , C07C2523/75
摘要： Synthesis gas comprising carbon monoxide and hydrogen is converted to a liquid hydrocarbon by contacting the synthesis gas under conversion conditions with a catalyst prepared by subjecting a cobalt carbonyl-impregnated alumina or silica support to an activation procedure at a temperature not exceeding 500.degree. C. comprising, in sequence, (A) reduction in hydrogen, (B) oxidation in an oxygen-containing gas, and (C) reduction in hydrogen.
摘要翻译： 包含一氧化碳和氢的合成气体通过使转化条件下的合成气与通过在不超过500℃的温度下使羰基浸渍的氧化铝或二氧化硅载体进行活化程序制备的催化剂而转化为液体烃，包括 ，（A）氢的还原，（B）含氧气体中的氧化，和（C）氢的还原。
-
公开(公告)号：US4605676A
公开(公告)日：1986-08-12
申请号：US734189
申请日：1985-05-15
CPC分类号： C07C1/0445 , B01J23/75 , B01J23/83 , B01J23/894 , B01J37/14 , B01J37/18 , C07C2521/04 , C07C2521/06 , C07C2523/10 , C07C2523/12 , C07C2523/46 , C07C2523/75
摘要： Synthesis gas comprising carbon monoxide and hydrogen is converted to a liquid hydrocarbon by contacting the synthesis gas under conversion conditions with a catalyst prepared by subjecting cobalt or nickel on a refractory metal oxide support to an activation procedure at a temperature below 500.degree. C. comprising, in sequence, (A) reduction in hydrogen, (B) oxidation in an oxygen-containing gas, and (C) reduction in hydrogen.
摘要翻译： 包含一氧化碳和氢的合成气体通过使转化条件下的合成气与在难熔金属氧化物载体上的钴或镍在低于500℃的温度下进行活化程序制备的催化剂而转化为液体烃， （A）氢的还原，（B）含氧气体中的氧化，和（C）氢的还原。
-
公开(公告)号：US4729981A
公开(公告)日：1988-03-08
申请号：US869705
申请日：1986-06-02
CPC分类号： C07C1/0445 , B01J23/75 , B01J23/894 , B01J37/14 , B01J37/18 , C07C2521/04 , C07C2523/10 , C07C2523/12 , C07C2523/46 , C07C2523/75
摘要： Catalyst for synthesis gas conversion in which a gas comprising carbon monoxide and hydrogen is converted to a liquid hydrocarbon is prepared by subjecting cobalt or nickel on a refractory metal oxide support to an activation procedure at a temperature of from about 100.degree. to about 450.degree. C. comprising, in sequence, (A) reduction in hydrogen, (B) oxidation in an oxygen-containing gas, and (C) reduction in hydrogen.
摘要翻译： 将含有一氧化碳和氢气的气体转化为液态烃的合成气转化催化剂是通过将钴或镍在难熔金属氧化物载体上进行活化程序制备的，该活化程序在约100至约450℃ （A）还原氢，（B）含氧气体中的氧化，和（C）氢的还原。
-
9.发明授权Activated cobalt-substituted layered aluminosilicate for synthesis gas conversion 失效用于合成气转化的活性钴取代层状硅铝酸盐
公开(公告)号：US4497903A
公开(公告)日：1985-02-05
申请号：US451612
申请日：1982-12-17
CPC分类号： B01J21/16 , C07C1/0445 , B01J23/75 , B01J37/036 , B01J37/10 , B01J37/18 , C07C2521/16 , C07C2523/75
摘要： Synthesis gas conversion catalyst prepared from synthetic layered aluminosilicate having a montmorillonite-type structure and containing cobalt substituted in the crystal lattice are activated for the conversion of synthesis gas by a sequential reduction, oxidation and reduction treatment. A Group VIII noble metal such as ruthenium can be impregnated on the catalyst prior to the final reduction stage. The catalyst is used in the production of liquid hydrocarbons from synthesis gas.
摘要翻译： 合成气转化催化剂由具有蒙脱石型结构的合成层状铝硅酸盐制备并含有在晶格中取代的钴的合成气体转化催化剂通过顺序还原，氧化和还原处理而被活化用于合成气的转化。 可以在最终还原阶段之前将VIII族贵金属如钌浸渍在催化剂上。 该催化剂用于从合成气生产液态烃。
-
10.发明授权Method for converting synthesis gas using an activated cobalt-substituted layered aluminosilicate 失效使用活化的钴取代层状硅铝酸盐转化合成气的方法
公开(公告)号：US4492774A
公开(公告)日：1985-01-08
申请号：US453139
申请日：1982-12-27
CPC分类号： B01J29/049 , B01J21/16 , C07C1/0445 , C07C2521/16 , C07C2523/75
摘要： A process for converting synthesis gas to liquid hydrocarbons using a catalyst prepared from synthetic layered aluminosilicate having a montmorillonite-type structure and containing cobalt substituted in the crystal lattice and activated for the conversion by a sequential reduction, oxidation and reduction treatment.
摘要翻译： 使用由具有蒙脱土型结构的合成层状硅铝酸盐制备的催化剂将合成气转化为液体烃的方法，并且含有在晶格中取代的钴并通过顺序还原，氧化和还原处理而被活化以进行转化。
-
-
-
-
-
-
-
-
-
搜索结果
67 条记录 (耗时 0.035 秒)
