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    PROCESS AND APPARATUS FOR IMPROVING LIGHT OLEFIN YIELD FROM A FLUID CATALYTIC CRACKING PROCESS
    5.
    发明申请
    PROCESS AND APPARATUS FOR IMPROVING LIGHT OLEFIN YIELD FROM A FLUID CATALYTIC CRACKING PROCESS 审中-公开
    从流体催化裂化过程中改进轻油脂的工艺和装置

    公开(公告)号：US20160176782A1

    公开(公告)日：2016-06-23

    申请号：US14578167

    申请日：2014-12-19

    申请人： UOP LLC

    发明人： Kirk Liu ,  Zhihao Fei ,  Charles P. Luebke

    IPC分类号： C07C4/06

    CPC分类号： C07C4/06 ,  C07C7/08 ,  C07C2529/035 ,  C07C2529/40 ,  C10G51/026 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/06

    摘要： The present invention discloses a process optimizing the yield of ethylene and propylene from a fluid catalytic cracking unit. The method combines a first catalytic reactor, a fractionation zone, a separation unit and a second catalytic reactor. The separation unit produces a first separate stream comprising C4 olefins and a second separate stream comprising C5 olefins. The separate streams may be combined and are passed to a second catalytic reactor for additional conversion to ethylene and propylene.

    摘要翻译： 本发明公开了一种从流化催化裂化装置优化乙烯和丙烯的产率的方法。 该方法结合了第一催化反应器，分馏区，分离单元和第二催化反应器。 分离单元产生包含C4烯烃的第一分离流和包含C5烯烃的第二分离流。 单独的物流可以组合并且被传递到第二催化反应器以进一步转化成乙烯和丙烯。

    Germanium Silicalite Catalyst and Method of Preparation and Use
    6.
    发明申请
    Germanium Silicalite Catalyst and Method of Preparation and Use 有权
    锗硅沸石催化剂及其制备方法

    公开(公告)号：US20140005453A1

    公开(公告)日：2014-01-02

    申请号：US13537184

    申请日：2012-06-29

    申请人： Alla Khanmamedova ,  Scott Stevenson ,  Dustin Farmer ,  Mike Mier

    发明人： Alla Khanmamedova ,  Scott Stevenson ,  Dustin Farmer ,  Mike Mier

    IPC分类号： B01J29/04 ,  C07C5/367 ,  C01B39/00

    CPC分类号： B01J23/42 ,  B01J29/047 ,  C07C2/76 ,  C07C2523/42 ,  C07C2529/035 ,  Y02P20/52 ,  C07C15/04 ,  C07C15/06 ,  C07C15/08 ,  C07C15/073

    摘要： A catalyst and its preparation and use are disclosed. The catalyst is a silicalite having germanium (Ge) included within the framework of the silicalite prepared in a particular manner. The catalyst may be used in a method of converting hydrocarbons wherein a hydrocarbon feed is contacted with the catalyst. The catalyst may be formed by preparing an aqueous reaction mixture of a silica-containing silicalite precursor material and a germanium source. The reactants of the reaction mixture are allowed to react. The reacted reaction mixture is heated under conditions to form crystals of a silicalite having germanium included within the framework of the silicalite. The crystals are then calcined to form the catalyst. In certain embodiments, a noble metal may be deposited upon the germanium-containing silicalite.

    摘要翻译： 公开了催化剂及其制备和用途。 该催化剂是在特定方式制备的硅沸石的框架内包含锗（Ge）的硅沸石。 催化剂可用于转化烃的方法，其中烃进料与催化剂接触。 可以通过制备含二氧化硅的硅沸石前体材料和锗源的含水反应混合物来形成催化剂。 使反应混合物的反应物反应。 将反应的反应混合物在条件下加热以形成包含在硅沸石框架内的锗的硅沸石晶体。 然后将晶体煅烧以形成催化剂。 在某些实施方案中，贵金属可沉积在含锗硅沸石上。

    Alkylation process with reduced heavy residue
    10.
    发明授权
    Alkylation process with reduced heavy residue 失效
    烷基化过程减少重残渣

    公开(公告)号：US6137020A

    公开(公告)日：2000-10-24

    申请号：US127025

    申请日：1998-07-31

    申请人： James R. Butler ,  Mark E. Kuchenmeister

    发明人： James R. Butler ,  Mark E. Kuchenmeister

    IPC分类号： C07C2/66 ,  C07C15/073 ,  C07C15/067

    CPC分类号： C07C15/073 ,  C07C2/66 ,  C07C2529/035

    摘要： A process for reducing the amount of undesirable byproducts, for example multi-ring compounds known as heavy residue in a process for the alkylation of an aromatic hydrocarbon with an olefin using a silicalite catalyst is disclosed. The process comprises supplying a feedstock containing benzene to a reaction zone with an alkylating agent in a molar ratio of benzene to alkylating agent of from about 2:1 to about 20:1 and into contact with an aluminosilicate alkylation catalyst having an average crystallite size of less than about 0.50 .mu.m and wherein the size of about 90% of the crystallites is less than 0.70 .mu.m. The catalyst is characterized by an Si/Al atomic ratio in the range from between 50 and 150 and a maximum pore size in the range from about 1000 to 1800 .ANG.. The catalyst has a sodium content of less than about 50 ppm and the reaction is carried out under conversion conditions including a temperature of from about 250.degree. C. to about 550.degree. C. and a pressure of from about 200 psi to about 500 psi.

    摘要翻译： 公开了一种减少不需要的副产物的方法，例如在使用硅沸石催化剂的烯烃烷基化芳族烃的方法中称为重残基的多环化合物。 该方法包括将含苯的原料与苯与烷基化剂的摩尔比为约2:1至约20:1的烷基化剂供应到反应区，并与平均微晶尺寸为的硅铝酸盐烷基化催化剂接触 小于约0.50μm，其中约90％的微晶的尺寸小于0.70μm。 催化剂的特征在于Si / Al原子比在50至150之间，最大孔径在约1000至1800安培的范围内。 催化剂的钠含量小于约50ppm，反应在包括温度为约250℃至约550℃，压力为约200psi至约500psi的转化条件下进行。