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    Unsaturated polyester containing formal linkages
    1.
    发明授权
    Unsaturated polyester containing formal linkages 失效
    不饱和聚酯含正式键合

    公开(公告)号：US4074061A

    公开(公告)日：1978-02-14

    申请号：US735856

    申请日：1976-10-26

    申请人： Harry R. Musser

    发明人： Harry R. Musser

    IPC分类号： C08G4/00 ,  C08G63/676 ,  C07C69/60

    CPC分类号： C08G63/676 ,  C08G4/00

    摘要： Disclosed is an unsaturated polyester containing formal linkages. The polyester is comprised of the following repeating unit ##STR1## wherein X is a positive integer from 2 to 10, R is the divalent radical remaining after removal of the terminal carboxyl group from an .alpha.,.beta.-ethylenically unsaturated dicarboxylic acid, and R' is the divalent radical remaining after removal of the terminal hydroxyl groups from an aliphatic or cycloaliphatic glycol. The polyesters of this invention exhibit a combination of a desirable hardness and a desirable impact strength upon curing.

    摘要翻译： 公开了含有正式键合的不饱和聚酯。 聚酯由下列重复单元组成：其中X为2-10的正整数，R为从α，β-烯属不饱和二羧酸除去末端羧基后剩余的二价基团 酸，R'是从脂肪族或脂环族二醇除去末端羟基后剩余的二价基团。 本发明的聚酯在固化时表现出期望的硬度和期望的冲击强度的组合。

    Copolyetheresters
    2.
    发明授权
    Copolyetheresters 失效
    共聚酯

    公开(公告)号：US4256860A

    公开(公告)日：1981-03-17

    申请号：US106963

    申请日：1979-12-26

    申请人： Burns Davis ,  Robert B. Barbee ,  Harry R. Musser

    发明人： Burns Davis ,  Robert B. Barbee ,  Harry R. Musser

    IPC分类号： C08G63/672 ,  C08G63/76

    CPC分类号： C08G63/672

    摘要： Disclosed are high melt strength, blow-moldable polymers that can be formed into bottles, tubing, film and the like. The polymers are copolyetheresters having an inherent viscosity of from 1.0 to about 2.5 comprisingA. a dicarboxylic acid component consisting essentially of 1,4-cyclohexanedicarboxylic acid, andB. a diol component comprising(1) at least 70 mole percent 1,4-cyclohexanedimethanol, and(2) from about 15 to about 60 weight percent, based on the weight of the polyetherester, of polypropyleneether glycol having a molecular weight of 1000 to 4000.

    摘要翻译： 公开了可以形成瓶，管，膜等的高熔体强度的可吹塑聚合物。 聚合物是具有1.0至约2.5的特性粘度的共聚醚酯，包括A.基本上由1,4-环己烷二羧酸组成的二羧酸组分和B.一种二醇组分，其包含（1）至少70摩尔％ 环己烷二甲醇，和（2）基于聚醚酯重量的约15至约60重量％的分子量为1000至4000的聚丙二醇二醇。

    Poly(hydrazone-hydrazine)
    4.
    发明授权
    Poly(hydrazone-hydrazine) 失效
    聚（腙 - 肼）

    公开(公告)号：US4181793A

    公开(公告)日：1980-01-01

    申请号：US931227

    申请日：1978-08-07

    申请人： Harry R. Musser

    发明人： Harry R. Musser

    IPC分类号： C08G73/08 ,  C08G69/08

    CPC分类号： C08G73/08

    摘要： Disclosed is a poly(hydrazone-hydrazide) prepared from difunctional acid chlorides and 4-(hydrazonomethyl)benzoic acid hydrazide. The poly(hydrazone-hydrazide) contains repeating units corresponding to the structure: ##STR1## Films of this polymer have unobviously high tensile and tear strengths without the necessity of biaxially orienting the film.

    摘要翻译： 公开了由双官能酰氯和4-（肼基甲基）苯甲酸酰肼制备的聚（腙 - 酰肼）。 聚（腙 - 酰肼）含有对应于以下结构的重复单元：该聚合物的膜具有非常显着的高拉伸强度和撕裂强度，而不需要双轴取向薄膜。

    4-(Hydrazonomethyl)benzoic acid hydrazide
    5.
    发明授权
    4-(Hydrazonomethyl)benzoic acid hydrazide 失效
    4-（肼基甲基）苯甲酸酰肼

    公开(公告)号：US4158014A

    公开(公告)日：1979-06-12

    申请号：US931226

    申请日：1978-08-07

    申请人： Harry R. Musser

    发明人： Harry R. Musser

    IPC分类号： C08G73/08 ,  C07C109/10

    CPC分类号： C07C251/72 ,  C08G73/08

    摘要： Disclosed is 4-(hydrazonomethyl)benzoic acid hydrazide having the structure ##STR1## This compound can be prepared from methyl formyl benzoate and hydrazine. This compound can be prepared into a polymer by condensation with difunctional acid chlorides. Films of the polymer have unobviously high tensile and tear strengths without the necessity of biaxially orienting the film.

    摘要翻译： 公开了具有结构的4-（肼基甲基）苯甲酸酰肼

    Stabilized copolyesterether compositions suitable for outdoor applications
    8.
    发明授权
    Stabilized copolyesterether compositions suitable for outdoor applications 失效
    适用于室外应用的稳定的共聚酯组合物

    公开(公告)号：US4524165A

    公开(公告)日：1985-06-18

    申请号：US544035

    申请日：1983-10-24

    申请人： Harry R. Musser ,  Thomas H. Strickland ,  Joseph S. Zannucci

    发明人： Harry R. Musser ,  Thomas H. Strickland ,  Joseph S. Zannucci

    IPC分类号： C08K5/00 ,  C08K5/3435 ,  C08K5/3462 ,  C08K5/34 ,  C08K5/07 ,  C08K5/10

    CPC分类号： C08K5/3435 ,  C08K5/00 ,  C08K5/3462

    摘要： Disclosed are stabilized polyester compositions having significantly improved weatherability. These polyesters consist of copolyesterethers derived from a dicarboxylic acid component comprising about 80-100 mole % 1,4-cyclohexanedicarboxylic acid having a trans isomer content of at least 70% and about 0-20 mole % of a second dicarboxylic acid and a glycol component comprising about 70-95 mole % 1,4-cyclohexanedimethanol and about 5-30 mole % of a polyalkylene ether glycol having a molecular weight of about 600 to about 3000. The copolyesterether compositions further comprise a stabilizing effective amount of the combination of (1) at least one hindered phenolic antioxidant, (2) at least one ultraviolet light stabilizing compound compatible with said copolyesterether and (3) at least one hindered amine light stabilizing compound having the formulae ##STR1## the groups shown as R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently selected from various substituents.

    摘要翻译： 公开了具有显着改善的耐候性的稳定的聚酯组合物。 这些聚酯由衍生自二羧酸组分的共聚酯组成，所述二羧酸组分包含约80-100摩尔％的反式异构体含量为至少70％和约0-20摩尔％的第二二羧酸和二醇组分的1,4-环己烷二羧酸 其包含约70-95摩尔％的1,4-环己烷二甲醇和约5-30摩尔％的分子量为约600至约3000的聚亚烷基醚二醇。共聚内酯组合物还包含稳定有效量的（1 ）至少一种受阻酚抗氧化剂，（2）至少一种与所述共聚酯相容的紫外线稳定化合物和（3）至少一种具有下式的受阻胺光稳定化合物： ，R 2，R 3和R 4各自独立地选自各种取代基。

    Copolyesterethers
    9.
    发明授权
    Copolyesterethers 失效
    共聚醚醚共聚酯

    公开(公告)号：US4349469A

    公开(公告)日：1982-09-14

    申请号：US235385

    申请日：1981-02-17

    申请人： Burns Davis ,  Theodore F. Gray ,  Harry R. Musser

    发明人： Burns Davis ,  Theodore F. Gray ,  Harry R. Musser

    IPC分类号： C08G63/66 ,  C08G63/18

    CPC分类号： C08G63/66

    摘要： Disclosed are copolyesterethers having an inherent viscosity of from about 0.8 to about 1.5 comprisingA. a dicarboxylic acid component consisting essentially of 1,4-cyclohexanedicarboxylic acid having a trans isomer content of at least 70%, andB. a glycol component consisting essentially of(1) 1,4-cyclohexanedimethanol, and(2) from about 15 to about 50 weight percent, based on the weight of the polyesterether, of polytetramethyleneether glycol having a molecular weight of about 500 to about 1100,C. from about 0.1 to about 1.5 mole %, based on the mole % of the acid or glycol component, of a branching agent having at least three COOH or OH functional groups and from 3 to 60 carbon atoms,said copolyesterethers being characterized by having a die swell of between about -90% and about +100% and a minimum crystallization time of less than 2.5 minutes.

    摘要翻译： 公开的具有约0.8至约1.5的特性粘度的共聚醚醚醚包括A.基本上由反式异构体含量为至少70％的1,4-环己烷二羧酸组成的二羧酸组分，以及B.一种二醇组分，主要由 （1）1,4-环己烷二甲醇，和（2）约15至约50重量％，基于聚酯醚的重量，分子量为约500至约1100的聚四亚甲基醚二醇，约0.1至 约1.5摩尔％，基于酸或二醇组分的摩尔％，具有至少三个COOH或OH官能团和3-60个碳原子的支化剂，所述共聚醚醚的特征在于具有介于约 -90％和约+ 100％，最小结晶时间小于2.5分钟。