Process for producing polyester polyols having secondary OH end groups
    2.
    发明授权
    Process for producing polyester polyols having secondary OH end groups 有权
    制备具有次级OH端基的聚酯多元醇的方法

    公开(公告)号:US09193822B2

    公开(公告)日:2015-11-24

    申请号:US13318157

    申请日:2010-05-04

    摘要: The invention relates to a process for producing polyester polyols with secondary hydroxyl end groups, including the step of the reaction of a polyester including carboxyl end groups with an epoxide of the general formula (1): wherein R1 stands for an alkyl residue or an aryl residue and the reaction is carried out in the presence of a catalyst that includes at least one nitrogen atom per molecule. The process is distinguished in that the polyester including carboxyl end groups exhibits an acid value from ≧25 mg KOH/g to ≦400 mg KOH/g and a hydroxyl value from ≦5 mg KOH/g and in that the polyester including carboxyl end groups is produced by ≧1.03 mol to ≦1.90 mol carboxyl groups or carboxyl-group equivalents of an acid component being employed per mol hydroxyl groups of an alcohol. The polyester polyols obtained, including secondary hydroxyl end groups, can be used for the purpose of producing polyurethane polymers.

    摘要翻译: 本发明涉及一种生产具有仲羟基端基的聚酯多元醇的方法,包括包括羧基端基的聚酯与通式(1)的环氧化物反应的步骤:其中R1代表烷基或芳基 残基,反应在每分子包含至少一个氮原子的催化剂存在下进行。 该方法的区别在于包括羧基端基的聚酯显示出≥25mgKOH / g至≥1000的KOH值,400mg KOH / g的酸值和来自< NEE的5K KOH / g的羟值,并且包括羧基的聚酯 端基是由醇的每摩尔羟基使用的≥1.03摩尔至1升; 1.90摩尔羧基或酸组分的羧基当量。 得到的聚酯多元醇(包括仲羟基端基)可用于制备聚氨酯聚合物。

    PROCESS FOR THE PREPARATION OF A POLYURETHANE POLYMER WITH SECONDARY HYDROXYL END GROUPS COMPRISING POLYESTER POLYOLS
    3.
    发明申请
    PROCESS FOR THE PREPARATION OF A POLYURETHANE POLYMER WITH SECONDARY HYDROXYL END GROUPS COMPRISING POLYESTER POLYOLS 有权
    制备聚氨酯聚合物的方法,该聚合物与包含聚酯多元醇的二级羟基末端基团

    公开(公告)号:US20120123008A1

    公开(公告)日:2012-05-17

    申请号:US13381139

    申请日:2010-06-29

    IPC分类号: C08G18/76 C08J9/00

    摘要: The invention relates to a process for the preparation of a polyurethane polymer, comprising the step of reaction ofA) polyester polyols with secondary hydroxyl end groups, which are obtainable from the reaction of a polyester comprising carboxyl end groups with an epoxide of the general formula (1): wherein R1 represents an alkyl radical or an aryl radical and wherein the polyester comprising carboxyl end groups has an acid number of from ≧25 mg of KOH/g to ≦400 mg of KOH/g and a hydroxyl number of ≦5 mg of KOH/g, with B) polyisocyanates which are chosen from the group comprising toluoylene-diisocyanate, diphenylmethane-diisocyanate, polymeric diphenylmethane-diisocyanate, xylylene-diisocyanate, naphthylene-diisocyanate, hexamethylene-diisocyanate, diisocyanatodicyclohexylmethane and/or isophorone-diisocyanate. The invention furthermore relates to polyurethane polymers prepared by such a process.

    摘要翻译: 本发明涉及一种制备聚氨酯聚合物的方法,包括A)聚酯多元醇与仲羟基端基反应的步骤,其可从包含羧基端基的聚酯与通式 (1)表示:其中R1表示烷基或芳基,其中包含羧基端基的聚酯的酸值为≥25mgKOH / g至< NlE; 400mg KOH / g,羟值为& ; B)多异氰酸酯,其选自甲苯二异氰酸酯,二苯基甲烷二异氰酸酯,聚合二苯基甲烷二异氰酸酯,亚二甲苯基二异氰酸酯,亚萘基二异氰酸酯,六亚甲基二异氰酸酯,二异氰酸二环己基甲烷和/或异佛尔酮 - 二异氰酸酯。 本发明还涉及通过这种方法制备的聚氨酯聚合物。

    PROCESS FOR PRODUCING POLYESTER POLYOLS HAVING SECONDARY OH END GROUPS
    8.
    发明申请
    PROCESS FOR PRODUCING POLYESTER POLYOLS HAVING SECONDARY OH END GROUPS 有权
    生产具有二级OH末端组的聚酯多元醇的方法

    公开(公告)号:US20120116114A1

    公开(公告)日:2012-05-10

    申请号:US13318157

    申请日:2010-05-04

    摘要: The invention relates to a process for producing polyester polyols with secondary hydroxyl end groups, including the step of the reaction of a polyester including carboxyl end groups with an epoxide of the general formula (1): wherein R1 stands for an alkyl residue or an aryl residue and the reaction is carried out in the presence of a catalyst that includes at least one nitrogen atom per molecule. The process is distinguished in that the polyester including carboxyl end groups exhibits an acid value from ≧25 mg KOH/g to ≦400 mg KOH/g and a hydroxyl value from ≦5 mg KOH/g and in that the polyester including carboxyl end groups is produced by ≧1.03 mol to ≦1.90 mol carboxyl groups or carboxyl-group equivalents of an acid component being employed per mol hydroxyl groups of an alcohol. The polyester polyols obtained, including secondary hydroxyl end groups, can be used for the purpose of producing polyurethane polymers.

    摘要翻译: 本发明涉及一种生产具有仲羟基端基的聚酯多元醇的方法,包括包括羧基端基的聚酯与通式(1)的环氧化物反应的步骤:其中R1代表烷基或芳基 残基,反应在每分子包含至少一个氮原子的催化剂存在下进行。 该方法的区别在于包括羧基端基的聚酯显示出≥25mgKOH / g至≥1000的KOH值,400mg KOH / g的酸值和来自< NEE的5K KOH / g的羟值,并且包括羧基的聚酯 端基是由醇的每摩尔羟基使用的≥1.03摩尔至1升; 1.90摩尔羧基或酸组分的羧基当量。 得到的聚酯多元醇(包括仲羟基端基)可用于制备聚氨酯聚合物。