公开(公告)号：US06922007B2

公开(公告)日：2005-07-26

申请号：US10463975

申请日：2003-06-17

Applicant: Heinz Geier ,  Rudolf Pollner

Inventor： Heinz Geier ,  Rudolf Pollner

IPC: C04B41/86 ,  H01T13/38 ,  H01T21/02 ,  H01T13/20

CPC classification number: H01T13/38 ,  H01T21/02

Abstract: A spark plug includes a ceramic component, whose surface is at least in part coated with a glaze, with the glaze containing 0.6% to 4% by weight of fluoride and 6% to 11.2% by weight of zinc oxide.

Abstract translation: 火花塞包括陶瓷组分，其表面至少部分地涂覆有釉料，釉料含有0.6重量％至4重量％的氟化物和6重量％至11.2重量％的氧化锌。

公开(公告)号：US20050227567A1

公开(公告)日：2005-10-13

申请号：US11147585

申请日：2005-06-07

Applicant: Heinz Geier ,  Rudolf Pollner

Inventor： Heinz Geier ,  Rudolf Pollner

IPC: C04B41/86 ,  H01T13/38 ,  H01T21/02

CPC classification number: H01T13/38 ,  H01T21/02

Abstract: A spark plug includes a ceramic component, whose surface is at least in part coated with a glaze, with the glaze containing 0.6% to 4% by weight of fluoride and 6% to 11.2% by weight of zinc oxide.

Abstract translation: 火花塞包括陶瓷组分，其表面至少部分地涂覆有釉料，釉料含有0.6重量％至4重量％的氟化物和6重量％至11.2重量％的氧化锌。

公开(公告)号：US06699807B2

公开(公告)日：2004-03-02

申请号：US09980893

申请日：2002-03-23

Applicant: Heinz Geier ,  Rudolf Pollner ,  Imke Koengeter ,  Ulrich Eisele

Inventor： Heinz Geier ,  Rudolf Pollner ,  Imke Koengeter ,  Ulrich Eisele

IPC: C03C1004

CPC classification number: C03C10/0036 ,  C03C14/00 ,  C03C14/004 ,  C03C2214/08 ,  H01T13/34

Abstract: A glass ceramic, for use as a resistor or a gas-tight glass ceramic solder for use in a spark plug, includes a fused seal of a starting glass fused from a starting mixture containing SiO2, Al2O3, TiO2 and CaO, the fused seal including crystalline phases in at least some areas. A method for producing such a glass ceramic provides for the starting glass to be processed in a first method step to form a starting material, which is heated for a first period of time in a second method step from a starting temperature, which is below the softening temperature of the starting glass, to a fusion temperature, which is above the softening temperature of the starting glass, and is kept at that temperature for a second period of time and finally is cooled again. A spark plug may include a terminal stud and a center electrode, which are electrically connected across a resistor that is formed in at least some areas by the glass ceramic.

Abstract translation: 用作火花塞中的电阻器或气密玻璃陶瓷焊料的玻璃陶瓷包括从含有SiO 2，Al 2 O 3，TiO 2和CaO的起始混合物熔融的起始玻璃的熔融密封，所述熔融密封包括 在至少一些区域的结晶相。 制造这种玻璃陶瓷的方法在第一方法步骤中提供要加工的起始玻璃，以形成起始材料，其在第二方法步骤中从起始温度加热第一时间段，起始温度低于 起始玻璃的软化温度达到高于起始玻璃的软化温度的熔融温度，并在该温度下保持第二个时间段，最后再次冷却。 火花塞可以包括端子柱和中心电极，它们跨越由玻璃陶瓷在至少一些区域形成的电阻器电连接。

公开(公告)号：US06693053B2

公开(公告)日：2004-02-17

申请号：US09980896

申请日：2002-03-22

Applicant: Heinz Geier ,  Rudolf Pollner ,  Ulrich Eisele ,  Peter Wange

Inventor： Heinz Geier ,  Rudolf Pollner ,  Ulrich Eisele ,  Peter Wange

IPC: C03C1004

CPC classification number: C03C8/02 ,  C03C3/062 ,  C03C3/087 ,  C03C10/0036

Abstract: A glass or glass powder is fused from a starting mixture containing approximately 38 wt % to 48 wt % SO2, 15 wt % to 19 wt % Al2O3, 4.5 wt % to 11 wt % TiO2, 0 wt % to 1.5 wt % Na2O, 0 wt % to 1.5 wt % K2O and 23 wt % to 30 wt % CaO. In addition, a glass powder mixture includes two glass powders, a carbon black powder and an organic binder, the first glass powder having a mean particle size of approximately 150 &mgr;m to 250 &mgr;m, the second glass powder having a mean particle size of less than approximately 100 &mgr;m, which may be 10 &mgr;m to 70 &mgr;m. The glass or glass powder mixture is suitable for producing a glass ceramic, such as that used as a resistor seal and/or a gas-tight glass ceramic solder in a spark plug.

Abstract translation: 将玻璃或玻璃粉末从含有约38重量％至48重量％的SO 2，15重量％至19重量％的Al 2 O 3，4.5重量％至11重量％的TiO 2，0重量％至1.5重量％的Na 2 O，0 wt％至1.5wt％的K 2 O和23wt％至30wt％的CaO。 此外，玻璃粉末混合物包括两个玻璃粉末，炭黑粉末和有机粘合剂，第一玻璃粉末的平均粒度为约150μm至250μm，第二玻璃粉末的平均粒度小于 大约100个妈妈，可能是10到70个妈妈。 玻璃或玻璃粉末混合物适用于制造玻璃陶瓷，例如在火花塞中用作电阻密封和/或气密玻璃陶瓷焊料。

公开(公告)号：US07128630B2

公开(公告)日：2006-10-31

申请号：US11147585

申请日：2005-06-07

Applicant: Heinz Geier ,  Rudolf Pollner

Inventor： Heinz Geier ,  Rudolf Pollner

IPC: H01T21/02

CPC classification number: H01T13/38 ,  H01T21/02

Abstract: A spark plug includes a ceramic component, whose surface is at least in part coated with a glaze, with the glaze containing 0.6% to 4% by weight of fluoride and 6% to 11.2% by weight of zinc oxide.

Abstract translation: 火花塞包括陶瓷组分，其表面至少部分地涂覆有釉料，釉料含有0.6重量％至4重量％的氟化物和6重量％至11.2重量％的氧化锌。

公开(公告)号：US20060162422A1

公开(公告)日：2006-07-27

申请号：US10516723

申请日：2003-05-15

Applicant: Heinz Geier ,  Helmut Weyl ,  Siegfried Nees ,  Bernhard Wild ,  Rainer Maier ,  Michael Liebler ,  Peter Dettling ,  Bettina Schneider ,  Craig Magera

Inventor： Heinz Geier ,  Helmut Weyl ,  Siegfried Nees ,  Bernhard Wild ,  Rainer Maier ,  Michael Liebler ,  Peter Dettling ,  Bettina Schneider ,  Craig Magera

IPC: G01N33/497

CPC classification number: G01N27/4078 ,  G01N27/407

Abstract: A gas sensor, whose purpose is to determine a physical property of a measuring gas, e.g., to determine the concentration of a gas component or the temperature of an exhaust gas. The gas sensor includes a sensor element arranged in a metal housing which is sealed by at least one sealing element arranged in a metal receptacle. The metal receptacle is affixed to the housing. The sealing element surrounds the sensor element in a centered position along its longitudinal extension L or on its half facing the measuring gas.

Abstract translation: 气体传感器的目的是确定测量气体的物理性能，例如确定气体成分的浓度或废气的温度。 气体传感器包括布置在金属壳体中的传感器元件，其被布置在金属容器中的至少一个密封元件密封。 金属插座固定在外壳上。 密封元件围绕传感器元件沿着其纵向延伸部L在其中心位置或其半个面对测量气体的中心位置。

公开(公告)号：US06636142B2

公开(公告)日：2003-10-21

申请号：US09980472

申请日：2001-11-30

Applicant: Heinz Geier ,  Gert Lindemann ,  Friederike Lindner ,  Thomas Brinz ,  Ulrich Eisele

Inventor： Heinz Geier ,  Gert Lindemann ,  Friederike Lindner ,  Thomas Brinz ,  Ulrich Eisele

IPC: H01C104

CPC classification number: G01K7/183

Abstract: A sensor element, especially a temperature sensor (5) is proposed, having a sensitive area (11), whose electrical resistance changes under the influence of a temperature to which the sensitive area (11) is exposed. In this case, sensitive area (11) has a glass ceramic fusion (15) of a starting material containing at least one component which is furnished at least substantially with a surface metallization. The proposed temperature sensor (5) is especially suitable for use at temperatures in excess of 1000° C., at which it shows resistance characteristics like that of a platinum resistor.

Abstract translation: 提出了一种传感器元件，特别是温度传感器，其具有敏感区域，其敏感区域在敏感区域暴露的温度的影响下变化。 在这种情况下，敏感区域具有包含至少基本上具有表面金属化的至少一种成分的起始材料的玻璃陶瓷熔合。 所提出的温度传感器特别适合在超过1000℃的温度下使用，在此温度传感器显示出如铂电阻器的电阻特性。

公开(公告)号：US4418661A

公开(公告)日：1983-12-06

申请号：US267516

申请日：1981-05-27

Applicant: Friedrich Esper ,  Thomas Frey ,  Heinz Geier ,  Gerhard Holfelder ,  Gunther Knoll

Inventor： Friedrich Esper ,  Thomas Frey ,  Heinz Geier ,  Gerhard Holfelder ,  Gunther Knoll

IPC: F02B3/06 ,  F23Q7/00 ,  F23G7/00 ,  F02P19/02

CPC classification number: F23Q7/001 ,  F02B3/06

Abstract: To decrease the preheat time and power requirements in preheater-type glow plugs for Diesel engines, a closed ceramic tube (20), for example of aluminum oxide and of about 5 mm diameter has, on the bottom (21) thereof applied a layer or film-like heater element (24, 24'), for example in an undulating or zig-zag configuration (FIG. 2) or in form of a constriction or pinch (FIG. 4: 24') to provide a concentrated point or strip source of heat. The heater layer itself is protected by a protective coating (25) and, to provide for the required heat distribution, the underlying bottom (21, 21') of the tube (20, 20') supports an insulating intermediate layer and possibly a heat conductive layer is intermediate. Preheat times in the order of 1-2 seconds, with lower current consumption than prior wound-wire plugs can be obtained.

Abstract translation: 为了减少用于柴油发动机的预热器型电热塞中的预热时间和功率要求，其底部（21）上的封闭陶瓷管（例如氧化铝）和约5mm直径的陶瓷管（20）应用一层或 膜状加热器元件（24,24'），例如以起伏或锯齿形构造（图2）或收缩或夹紧（图4：24'）的形式提供集中点或条带 热源。 加热器层本身由保护涂层（25）保护，并且为了提供所需的热分布，管（20,20'）的下面的底部（21,21'）支撑绝缘中间层和可能的热 导电层是中间的。 可以获得大约1-2秒的预热时间，其电流消耗比现有的缠绕线塞更低。

公开(公告)号：US5773894A

公开(公告)日：1998-06-30

申请号：US769182

申请日：1996-12-18

Applicant: Karl-Hermann Friese ,  Heinz Geier ,  Werner Gruenwald ,  Claudio De La Prieta

Inventor： Karl-Hermann Friese ,  Heinz Geier ,  Werner Gruenwald ,  Claudio De La Prieta

IPC: B32B18/00 ,  G01N27/406 ,  G01N27/407 ,  H01B3/12 ,  C04B35/48

CPC classification number: G01N27/407 ,  B32B18/00 ,  C04B37/001 ,  C04B37/021 ,  G01N27/4067 ,  G01N27/4071 ,  G01N27/4075 ,  H01B3/12 ,  C04B2237/064 ,  C04B2237/068 ,  C04B2237/32 ,  C04B2237/341 ,  C04B2237/343 ,  C04B2237/348 ,  C04B2237/40 ,  C04B2237/401 ,  C04B2237/68 ,  C04B2237/704 ,  C04B2237/708 ,  C04B2237/72 ,  C04B2237/76 ,  C04B2237/86

Abstract: An insulation layer system, in particular for gas sensors, is proposed, having at least one electrically conductive solid-electrolyte layer (10), an electrically conductive layer (20) and at least one electrically insulating layer (13) between the solid-electrolyte layer (10) and the electrically conductive layer (20). The material of the insulating layer (13) contains, prior to sintering, pentavalent metal oxides of niobium or tantalum as an additive, it being possible for the additive to diffuse into the adjoining solid-electrolyte layer (10) during sintering.

Abstract translation: 提出了一种特别用于气体传感器的绝缘层系统，其具有至少一个导电固体电解质层（10），导电层（20）和固体电解质之间的至少一个电绝缘层（13） 层（10）和导电层（20）。 绝缘层（13）的材料在烧结之前含有铌或钽的五价金属氧化物作为添加剂，在烧结期间添加剂可能扩散到相邻的固体电解质层（10）中。

公开(公告)号：US4221650A

公开(公告)日：1980-09-09

申请号：US910385

申请日：1978-05-30

Applicant: Karl-Hermann Friese ,  Friedrich J. Esper ,  Heinz Geier

Inventor： Karl-Hermann Friese ,  Friedrich J. Esper ,  Heinz Geier

IPC: C04B35/48 ,  C04B14/32 ,  C04B35/119 ,  C04B35/488 ,  G01N27/12 ,  G01N27/407 ,  G01N27/409 ,  G01N27/413 ,  H01M8/1253 ,  G01N27/58

CPC classification number: G01N27/4073 ,  C04B35/119 ,  C04B35/4885 ,  H01M8/1253 ,  Y02E60/525 ,  Y02P70/56

Abstract: Oxygen sensors having a fine-grained stabilized cubic zirconium dioxide electrolyte contact respective electrodes. The zirconium dioxide contains between 15% and 50% by volume of Al.sub.2 O.sub.3 in a crystalline state and has good mechanical and thermal properties. The oxygen sensor may have a composite zirconium dioxide solid electrolyte element. The invention also includes a wider range of related Al.sub.2 O.sub.3 - containing stabilized cubic zirconium dioxides containing between about 8% and 85% by volume Al.sub.2 O.sub.3. The invention further provides methods of manufacturing such Al.sub.2 O.sub.3 - containing zirconium dioxide and for manufacturing oxygen sensors.

Abstract translation: 具有细粒度稳定的立方二氧化锆电解质的氧传感器与相应的电极接触。 二氧化锆在结晶状态下含有15体积％至50体积％的Al 2 O 3，具有良好的机械和热性能。 氧传感器可以具有复合二氧化锆固体电解质元件。 本发明还包括含有约8％至85％（体积）Al 2 O 3的更广泛的相关的含Al 2 O 3的稳定的立方二氧化锆。 本发明还提供制造这种含Al 2 O 3的二氧化锆和用于制造氧传感器的方法。