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1.发明授权Coating processes, compositions and substrates coated with maleic anhydride copolymers having the anhydride moieties reacted with hydrozine or its derivatives 失效用酸酐部分与马来酸酐共聚物涂覆的涂布方法，组合物和基材与氢化锌或其衍生物反应
公开(公告)号：US4083835A
公开(公告)日：1978-04-11
申请号：US699931
申请日：1976-06-25
CPC分类号： D21H17/455 , C08F8/30 , C08F8/32 , D21H17/43 , Y10T428/263 , Y10T428/31699 , Y10T428/3188 , Y10T428/31935
摘要： Copolymers which have a molecular weight of from 600 to 24,500, and which contain from 0.1 to 60 per cent by weight of succinic acid hydrazide units and from 99.9 to 40% by weight of one or more ethylenically unsaturated monomers which are copolymerizable with maleic anhydride, are used as coating agents and binders.
摘要翻译： 共聚物的分子量为600至24,500，并含有0.1至60重量％的琥珀酸酰肼单元和99.9至40重量％的一种或多种烯键式不饱和单体，其可与马来酸酐共聚， 用作包衣剂和粘合剂。
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公开(公告)号：US4696996A
公开(公告)日：1987-09-29
申请号：US797884
申请日：1985-11-14
申请人： Hermann Brandt , Hermann Fischer , Hermann Dreher , Eduard Heil , Juergen Hambrecht , Herbert Naarmann , Adolf Echte , Hermann Gausepohl , Peter Siebel , Johann Swoboda , Gerd Schwoebel , Albert Nikles
发明人： Hermann Brandt , Hermann Fischer , Hermann Dreher , Eduard Heil , Juergen Hambrecht , Herbert Naarmann , Adolf Echte , Hermann Gausepohl , Peter Siebel , Johann Swoboda , Gerd Schwoebel , Albert Nikles
CPC分类号： C08G65/44 , B01J19/1862 , B01J19/1881 , B01J2219/00094 , B01J2219/00103 , B01J2219/0011
摘要： Polyphenylene ethers are prepared from monohydric phenols, which possess alkyl substituents in the two ortho-positions and, if desired, in the meta-position, but not in the para-position, by an oxidative coupling reaction with oxygen at from 15.degree. to 50.degree. C. and under from 1 to 10 bar in the presence of a catalyst complex, of a solvent and, if required, of an activator, by a method in which the conversion of the phenols is carried out in two more reaction zones, in which some or all of the solvent, the catalyst complex and the phenols and, where relevant, the activator is initially taken and is circulated by means of a conveying unit, and about 60-100% of the stoichiometric amount of oxygen required for the oxidative coupling is introduced into the first reaction zone and from 0 to about 40% of the said stoichiometric amount is introduced into the second reaction zone.
摘要翻译： 聚苯醚由单羟基苯酚制得，它们在两个邻位具有烷基取代基，如果需要，在间位，而不是在对位，通过与15至50的氧的氧化偶联反应， 在催化剂配合物存在下，在溶剂和如果需要的情况下，活化剂存在下，在1至10巴下，通过酚的转化在两个更多的反应区中进行，在 其中一些或全部溶剂，催化剂络合物和酚，并且在相关的情况下，活化剂最初被摄取并通过输送单元循环，并且约60-100％的化学计量量的氧化所需的氧 将偶联引入第一反应区，并将0至约40％的所述化学计量量引入第二反应区。
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3.发明授权Manufacture of heat-stable brominated oligomers of monovinyl-aromatic compounds 失效制备单乙烯基芳族化合物的热稳定溴化低聚物
公开(公告)号：US4074032A
公开(公告)日：1978-02-14
申请号：US705278
申请日：1976-07-14
摘要： A process for the manufacture of heat-stable, brominated oligostyrenes by brominating selectively hydrogenated oligostyrenes in halogenated solvents in the presence of Lewis acids at from -25.degree. to +20.degree. C. The brominated oligomers are highly heat-stable and can be processed, by themselves or as components of mixtures with other thermoplastics, to give various shaped articles.
摘要翻译： 在-25℃至+20℃的路易斯酸存在下，通过在卤代溶剂中溴化选择性氢化的低聚异丁烯来制造热稳定的溴化低聚物的方法。溴化低聚物是高度热稳定的， 自身或作为与其他热塑性塑料的混合物的组分，以产生各种成型制品。
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4.发明授权Method of preparing a low molecular weight paper size polymer by continuous polymerization in the absence of initiator 失效在不存在引发剂的情况下通过连续聚合制备低分子量纸尺寸聚合物的方法
公开(公告)号：US4060679A
公开(公告)日：1977-11-29
申请号：US675581
申请日：1976-04-09
IPC分类号： C08F210/00 , C08F212/06 , C08F216/14 , C08F220/34 , C08F220/60 , D21H17/45 , C08F20/70 , C08F226/00
CPC分类号： C08F220/60 , C08F210/00 , C08F212/06 , C08F216/14 , C08F220/34 , D21H17/455 , Y10T428/31906
摘要： A paper size comprising a water-soluble salt of a copolymer of from 30 to 85% by weight of olefins of 2 to 12 carbon atoms, having a terminal double bond, and/or vinyl ethers, and from 15 to 70% by weight of basic acrylic and/or methacrylic compounds, which copolymer has a molecular weight of from 600 to 4,500 and is manufactured by continuous copolymerization at from 130.degree. to 320.degree. C.
摘要翻译： 包含具有30至85重量％的具有末端双键的具有2至12个碳原子的烯烃的共聚物的水溶性盐和/或乙烯基醚的纸张尺寸和15至70重量％ 碱性丙烯酸和/或甲基丙烯酸类化合物，该共聚物的分子量为600至4,500，并通过在130℃至320℃的连续共聚制备。
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公开(公告)号：US4412037A
公开(公告)日：1983-10-25
申请号：US302040
申请日：1981-09-14
IPC分类号： C08L25/00 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L51/04 , C08L71/00 , C08L71/12 , C08L61/04
CPC分类号： C08L51/04 , C08L71/123
摘要： Thermoplastic molding materials based on styrene polymers which have been made impact-resistant and on polyphenylene ethers, wherein the particles of the soft component of the styrene polymer which has been made impact-resistant have a mean diameter of more than 1 micron, and wherein the proportion of particles which have a diameter of less than 0.6 micron is not less than 40% by weight and the proportion of particles which have a diameter of from 0.6 to 3 microns is less than 3% by weight.
摘要翻译： 基于已经制成抗冲击性的苯乙烯聚合物和聚苯醚的热塑性成型材料，其中已经制成抗冲击性的苯乙烯聚合物的软组分的颗粒具有大于1微米的平均直径，并且其中 直径小于0.6微米的颗粒的比例不小于40重量％，直径为0.6至3微米的颗粒的比例小于3重量％。
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公开(公告)号：US4200702A
公开(公告)日：1980-04-29
申请号：US912358
申请日：1978-06-05
摘要： Thermoplastic molding compositions based on rubber-modified styrene-acrylonitrile copolymers containing a halogenated styrene oligomer as the effective flame-proofing agent which is sufficiently heat-stable, does not interfere with processing on conventional machinery, does not corrode or cause coatings on such machinery, and has virtually no adverse effect on the impact strength of the polymers. The flameproofing agent as a rule has a degree of polymerization of from 3 to 200 and can be incorporated into the polymer by conventional methods; the polymer may or may not contain additional synergistic agents and processing auxiliaries, which are incorporated in the conventional manner and in the conventional amounts.
摘要翻译： 含有卤代苯乙烯低聚物作为充分热稳定性的有效阻燃剂的橡胶改性苯乙烯 - 丙烯腈共聚物的热塑性模塑组合物不影响常规机械的加工，不会在这种机械上腐蚀或引起涂层， 并且对聚合物的冲击强度几乎没有不利影响。 通常防火剂的聚合度为3〜200，可以通过常规方法加入到聚合物中; 聚合物可以包含或可以不含有以常规方式和常规量掺入的其它协同剂和加工助剂。
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公开(公告)号：US06410654B1
公开(公告)日：2002-06-25
申请号：US09719818
申请日：2000-12-18
IPC分类号： C08F446
CPC分类号： C08F287/00 , C08F279/02 , C08F212/08
摘要： An anionically polymerized impact-modified polystyrene has a yield stress of at least 24 MPa, measured at 23° C. to DIN 53455 and a hole impact strength of at least 11 kJ/m2, measured at 23° C. to DIN 53753, measured in each case on a specimen produced to ISO 3167. A preparation process is described.
摘要翻译： 阴离子聚合的冲击改性聚苯乙烯具有至少24MPa的屈服应力，在23℃下根据DIN 53455测量，并且在23℃根据DIN 53753测量的孔冲击强度为至少11kJ / m 2，测量 在每种情况下都是根据ISO 3167生产的样品。描述了制备过程。
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公开(公告)号：US06399703B1
公开(公告)日：2002-06-04
申请号：US09582879
申请日：2000-07-06
IPC分类号： C08F29700
CPC分类号： C08F279/02 , C08F287/00 , C08F212/08
摘要： A process for preparing impact-modified styrene polymers (HIPS) omprises anionic polymerization of styrene in the presence of a rubber in one or more polymerization reactors in succession. The rubber is prepared in solution in an immediately upstream process. The heat of polymerization is utilized to remove the solvent for the rubber, this solvent having a boiling point lower than those of styrene and ethylbenzene, from at least one of the polymerization reactors via distillation with distillative cooling, and the solvent is reintroduced into the process of rubber preparation.
摘要翻译： 制备冲击改性苯乙烯聚合物（HIPS）的方法在连续的一个或多个聚合反应器中在橡胶存在下进行苯乙烯的阴离子聚合。 橡胶在紧密上游过程中在溶液中制备。 使用聚合热来除去溶剂，该溶剂的沸点低于苯乙烯和乙苯的溶剂，来自至少一个聚合反应器通过蒸馏蒸馏冷却，并将溶剂重新引入该方法 的橡胶制剂。
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9.发明授权Method for the production of block copolymers by retarded anionic polymerization 失效通过延迟阴离子聚合制备嵌段共聚物的方法公开(公告)号：US06353056B1
公开(公告)日：2002-03-05
申请号：US09622175
申请日：2000-08-14
IPC分类号： C08F29704
CPC分类号： C08F297/04
摘要： In a process for the preparation of block copolymers from vinylaromatic monomers and dienes, the monomers are polymerized in the presence of at least one alkali metal organyl or alkali metal alkoxide and at least one magnesium, aluminum or zinc organyl.
摘要翻译： 在由乙烯基芳族单体和二烯制备嵌段共聚物的方法中，单体在至少一种碱金属有机碱金属醇盐和至少一种镁，铝或锌有机基团存在下聚合。
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10.发明授权Preparation of rubber-modified molding materials from reaction mixtures containing derivatives of acrylamides or of methacrylamides 失效由含有丙烯酰胺或甲基丙烯酰胺衍生物的反应混合物制备橡胶改性的成型材料
公开(公告)号：US5886105A
公开(公告)日：1999-03-23
申请号：US836318
申请日：1997-05-12
IPC分类号： C08L15/00 , C08F2/18 , C08F220/12 , C08F220/58 , C08F265/04 , C08L51/00 , C08L51/06 , C08L33/00 , C08L33/26
CPC分类号： C08F265/04 , C08L51/06
摘要： In the preparation of a rubber-modified molding material, in a first stage, a first mixture (A) contains at least one alkyl acrylate or methacrylate (a) of the formula (I) ##STR1## where R.sup.1 is hydrogen or methyl and R.sup.2 is alkyl of 1 to 32 carbon atoms, a compound (b) of the formula (II) ##STR2## where R.sup.3 is hydrogen or methyl, R.sup.4 is hydrogen or alkyl of 1 to 8 carbon atoms, R.sup.5 is hydrogen or methyl and R.sup.6 is hydrogen or alkyl of 1 to 10 carbon atoms, preferably hydrogen, and, if required, a first monomer (c) or a plurality thereof is polymerized with free radicals to give a rubber (B),in a second stage, the resulting rubber (B) is mixed with a second monomer (d) or with a plurality thereof, preferably dissolved or swollen therein, to form a second mixture (C), andin a third stage, the second mixture (C) formed by mixing is polymerized with free radicals to give the rubber-modified molding material (D).
摘要翻译： PCT No.PCT / EP95 / 04477 371日期1997年5月12日 102（e）日期1997年5月12日PCT提交1995年11月14日PCT公布。 出版物WO96 / 15168 日期1996年5月23日在橡胶改性成型材料的制备中，在第一阶段中，第一混合物（A）含有至少一种式（I）的丙烯酸烷基酯或甲基丙烯酸烷基酯（a）（I）其中 R1是氢或甲基，R2是1至32个碳原子的烷基，式（II）的化合物（b）R4是氢或1至8个碳原子的烷基，R5是氢或甲基，R6是氢或烷基 1至10个碳原子，优选为氢，如果需要，第一单体（c）或其多个与自由基聚合以得到橡胶（B），在第二阶段中，所得橡胶（B）为 与第二单体（d）或其多个混合，优选在其中溶解或溶胀以形成第二混合物（C），并且在第三阶段中，通过混合形成的第二混合物（C）与自由基聚合， 得到橡胶改性成型材料（D）。
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