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    Polymerizate Comprising a Macromonomer
    5.
    发明申请
    Polymerizate Comprising a Macromonomer 审中-公开
    包含大分子单体的聚合物

    公开(公告)号：US20140135428A1

    公开(公告)日：2014-05-15

    申请号：US14126909

    申请日：2012-06-19

    申请人： Heinz-Peter Klein ,  Bo Gao ,  Peng Xu ,  Michael Schottler

    发明人： Heinz-Peter Klein ,  Bo Gao ,  Peng Xu ,  Michael Schottler

    IPC分类号： C08L29/04 ,  C04B24/26

    CPC分类号： C08L29/04 ,  C04B24/2623 ,  C04B24/2641 ,  C04B40/0608 ,  C04B2103/0057 ,  C08F220/18 ,  C08F261/04 ,  C08F290/147 ,  C08F2220/1825 ,  C08F2222/1086 ,  C09D151/08 ,  C09J133/08 ,  C08F220/14 ,  C04B28/02 ,  C04B28/14 ,  C08F222/10

    摘要： The present invention relates to a polymerizate in the form of an aqueous polymer dispersion, the polymerizate being obtainable by radical polymerization of monomers in an aqueous medium in the presence of a free radical initiator and a protective colloid, wherein the monomers comprise a) 50-99.99 wt. % of at least one vinyl monomer chosen from the group of vinyl esters, (meth)acrylic esters, vinyl aromatic compounds, vinyl halides, and olefins, and b) 0.01-30 wt. % of at least one macromonomer M, the macromonomer M being a reaction product of components (i), (ii), and (iii), said —component (i) having at least one olefinically unsaturated group and at least one hydroxyl, amine and/or thiol group, —component (ii) being a di- or triisocyanate, and —component (iii) having at least two terminal groups selected from hydroxyl, amine and/or thiol groups, c) 0-20 wt % of at least one vinyl monomer with at least one functional group, wherein the monomers a), b), and c) sum up to 100 wt. % of total monomers employed. The invention further provides a process to prepare the polymerizate, water-redispersible polymer powders obtainable from the polymerizate, and building material compositions containing the polymerizate and/or the water-redispersible polymer powders.

    摘要翻译： 本发明涉及以聚合物水分散体形式的聚合物，该聚合物可通过单体在水性介质中在自由基引发剂和保护胶体存在下的自由基聚合而获得，其中单体包括a）50- 99.99重量％ 至少一种选自乙烯基酯，（甲基）丙烯酸酯，乙烯基芳族化合物，乙烯基卤化物和烯烃的乙烯基单体的百分比，和b）0.01-30重量％ 至少一种大分子单体M的％，大分子单体M是组分（i），（ii）和（iii）的反应产物，所述组分（i）具有至少一个烯属不饱和基团和至少一个羟基胺 和/或硫醇基， - 组分（ii）是二异氰酸酯或三异氰酸酯，以及 - 组分（iii），其具有至少两个选自羟基，胺和/或硫醇基团的端基，c）0-20重量％ 至少一种具有至少一个官能团的乙烯基单体，其中单体a），b）和c）总计高达100wt。 占所用总单体的百分比。 本发明还提供一种制备聚合物，可从聚合物获得的水可再分散聚合物粉末和含有聚合物和/或水可再分散聚合物粉末的建筑材料组合物的方法。

    Redispersible dispersion powder composition, its use, and process for its preparation
    6.
    发明授权
    Redispersible dispersion powder composition, its use, and process for its preparation 失效
    可再分散粉末组合物，其用途及其制备方法

    公开(公告)号：US06900259B2

    公开(公告)日：2005-05-31

    申请号：US10647011

    申请日：2003-08-22

    申请人： Heinz-Peter Klein ,  Ulrich Geissler ,  Michael Schottler ,  Ludwig Schmitz

    发明人： Heinz-Peter Klein ,  Ulrich Geissler ,  Michael Schottler ,  Ludwig Schmitz

    IPC分类号： C04B24/04 ,  C04B24/26 ,  C08K5/103 ,  C08L101/12 ,  C09J11/04 ,  C09J11/06 ,  C09J11/08 ,  C09J201/00

    CPC分类号： C08K5/103 ,  C04B24/2641 ,  C04B24/2688 ,  C04B2103/0057

    摘要： A dispersion powder composition based on water-insoluble polymers with particularly low water absorption comprises, based on the total weight of the polymer, an amount in the range from 0.1 to 30% by weight of at least one carboxylic ester whose acid component has at least 6 carbon atoms and whose alcohol component is a polyhydroxy compound, preferably glycerol, diglycerol, or triglycerol. This is prepared by mixing polymer and protective colloid with the carboxylic ester to prepare a dispersion and then, where appropriate, drying this with simultaneous admixing of an anticaking agent, and gives good results when used for modifying wallpaper pastes, mortars, or concrete.

    摘要翻译： 基于具有特别低吸水率的水不溶性聚合物的分散粉末组合物包含基于聚合物总重量的0.1-30重量％的至少一种羧酸酯，其酸组分至少具有 6个碳原子，其醇组分是多羟基化合物，优选甘油，双甘油或三甘油。 这是通过将聚合物和保护胶体与羧酸酯混合以制备分散体制备的，然后在适当的情况下，同时混合抗结块剂将其干燥，并且当用于改变壁纸浆料，砂浆或混凝土时得到良好的结果。