Layered body for the absorption of liquids and its production
    1.
    发明授权
    Layered body for the absorption of liquids and its production 失效
    分层体吸收液体及其生产

    公开(公告)号:US5763067A

    公开(公告)日:1998-06-09

    申请号:US757953

    申请日:1996-11-22

    摘要: The present invention relates to layered bodies consisting of at least one plastic foam and/or latex foam layer and particulate, superabsorbent polymers for the absorption of water and aqueous liquids, which bodies comprise the superabsorber on, between, or below the foamed plastic and/or latex layer in a quantitatively and/or locally predetermined and fixed area, configuration at a quantity ratio of plastic and/or latex foam to the superabsorber of 1:500 to 50:1. The plastic/latex foam may comprise fillers, pigments and/or synthetic fibers. The layered bodies have an increased absorption capacity for water and aqueous liquids, in particular under load. They are manufactured by spreading out the foam, applying the superabsorber in the predetermined quantity ratio, optionally by using a stencil, and by fixing it by means of a heat treatment. These layered bodies are used in hygienic articles, as components in natural or artificial soils, as insulating material for pipes and ducts, primarily for cables and constructional elements, as liquid-absorbing and liquid-storing component in packaging materials, and as a part in garments.

    摘要翻译: 本发明涉及由至少一种塑料泡沫和/或胶乳泡沫层和用于吸收水和含水液体的颗粒状超吸收性聚合物组成的层状体,该主体在发泡塑料之间,之间或之下包含超吸收体和/ 或胶体层在定量和/或局部预定和固定的区域中,塑料和/或胶乳泡沫与超吸收体的量比为1:500至50:1的构型。 塑料/乳胶泡沫可以包括填料,颜料和/或合成纤维。 层状体对水和含水液体的吸收能力增加,特别是在负荷下。 它们通过铺展泡沫,以预定量比施加超吸收器,任选地使用模板,并通过热处理固定来制造。 这些层状体用作卫生制品,作为天然或人造土壤中的组分,作为用于管道和管道的绝缘材料,主要用于电缆和结构元件,作为包装材料中的液体吸收和液体储存组分,以及作为 服装。

    Layered body for the absorption of liquids and its production
    2.
    发明授权
    Layered body for the absorption of liquids and its production 失效
    分层体吸收液体及其生产

    公开(公告)号:US6103358A

    公开(公告)日:2000-08-15

    申请号:US3355

    申请日:1998-01-06

    摘要: The present invention relates to layered bodies consisting of at least one plastic foam and/or latex foam layer and particulate, superabsorbent polymers for the absorption of water and aqueous liquids, which bodies comprise the superabsorber on, between, or below the foamed plastic and/or latex layer in a quantitatively and/or locally predetermined and fixed areal configuration at a quantity ratio of plastic and/or latex foam to the superabsorber of 1:500 to 50:1. The plastic/latex foam may comprise fillers, pigments and/or synthetic fibers. The layered bodies have an increased absorption capacity for water and aqueous liquids; in particular under load. They are manufactured by spreading out the foam, applying the superabsorber in the predetermined quantity ratio, optionally by using a stencil, and by fixing it by means of a heat treatment. These layered bodies are used in hygienic articles, as components in natural or artificial soils, as insulating material for pipes and ducts, primarily for cables and constructional elements, as liquid-absorbing and liquid-storing component in packaging materials, and as a part in garments.

    摘要翻译: 本发明涉及由至少一种塑料泡沫和/或胶乳泡沫层和用于吸收水和含水液体的颗粒状超吸收性聚合物组成的层状体,该主体在发泡塑料之间,之间或之下包含超吸收体和/ 或胶乳层,其定量和/或局部预定和固定的面层结构以塑料和/或胶乳泡沫与超吸收体的量比为1:500至50:1。 塑料/乳胶泡沫可以包括填料,颜料和/或合成纤维。 层状体对水和含水液体的吸收能力增加; 特别是在负载下。 它们通过铺展泡沫,以预定量比施加超吸收器,任选地使用模板,并通过热处理固定来制造。 这些层状体用于卫生制品中,作为天然或人造土壤中的组分,作为用于管道和管道的绝缘材料,主要用于电缆和结构元件,作为包装材料中的液体吸收和液体储存组分,以及作为 服装。

    Method for producing water-soluble or water-swellable polymerizates with a very low residual monomer content, products produced according to this method and the use thereof
    3.
    发明授权
    Method for producing water-soluble or water-swellable polymerizates with a very low residual monomer content, products produced according to this method and the use thereof 失效
    制备具有非常低残留单体含量的水溶性或水溶胀性聚合物的方法,根据该方法生产的产品及其用途

    公开(公告)号:US07030199B1

    公开(公告)日:2006-04-18

    申请号:US09554090

    申请日:1998-11-13

    IPC分类号: C08F2/00

    CPC分类号: C08F6/001 C08F6/006 C08L33/00

    摘要: The invention relates to a process for producing water-soluble or water-swellable polymer products from acrylic acid and/or acrylic acid derivatives partially or completely neutralized with nitrogen compounds and with exceedingly low levels of residual monomers, which process is characterized by subsequent heating of the polymer product at temperatures of from 120 to 240° C. The polymers produced accordingly are suitable for use as flocculants, dispersants and absorbers.

    摘要翻译: 本发明涉及由用氮化合物部分或完全中和的丙烯酸和/或丙烯酸衍生物制备水溶性或水溶胀性聚合物产物的方法,该方法的特征在于随后加热 聚合物产物的温度为120-240℃。因此生产的聚合物适合用作絮凝剂,分散剂和吸收剂。

    Absorbing agents for water and aqueous liquids and process for their production and use
    4.
    发明授权
    Absorbing agents for water and aqueous liquids and process for their production and use 失效
    用于水和含水液体的吸收剂及其生产和使用过程

    公开(公告)号:US06403700B1

    公开(公告)日:2002-06-11

    申请号:US09532085

    申请日:2000-03-21

    IPC分类号: C08J300

    摘要: The present invention relates to a powdery, cross-linked polymer absorbing water and aqueous liquids formed of polymerized, unsaturated, acid groups-containing monomers that are present as salts neutralized to the extent of at least 50 mol-% and which optionally comprise further monomers which are copolymerizable with the acid groups-containing monomers as well as water-soluble polymers, the polymer being formed of acidic, polymerized monomers partially neutralized to the extent of 5-30 mol-%, relative to the acid groups-containing monomer portion. The polymer has a high retention, high liquid absorption under pressure, high swelling pressure, and a low content of soluble components. The present invention further relates to a process for the production of said polymer and to its use as a component in sanitary articles which absorb body fluids and in wound dressings, in current-conducting and light-transmitting cables, as soil conditioners, as a component in packaging materials and in depot materials for the controlled release of active substances.

    摘要翻译: 本发明涉及一种粉末状交联聚合物,其吸收水和由聚合的,不饱和的含酸基团的单体形成的含水液体,其以中和至少为50摩尔%的程度存在,并且任选地包含另外的单体 其可与含酸基团的单体以及水溶性聚合物共聚,所述聚合物由相对于含酸性基团的单体部分部分中和到5-30mol%程度的酸性聚合单体形成。 该聚合物具有高保留性,在压力下的高液体吸收,高溶胀压力和低含量的可溶性组分。 本发明还涉及生产所述聚合物的方法及其作为卫生制品中用作吸收体液和伤口敷料的导电和透光电缆作为土壤调节剂作为组分的组分的方法 在包装材料和储存材料中控制活性物质的释放。

    Process for softening/stuffing leather and fur skins
    5.
    发明授权
    Process for softening/stuffing leather and fur skins 失效
    软化/填充皮革和皮毛皮的过程

    公开(公告)号:US5575939A

    公开(公告)日:1996-11-19

    申请号:US325184

    申请日:1995-06-09

    CPC分类号: C14C9/00 C08F8/14

    摘要: The invention relates to a process for the fat liquoring/softening of leathers and furs by treatment with an aqueous dispersion of a copolymer obtainable by polymerization of a) maleic anhydride, b) C.sub.12 -C.sub.30 alpha-olefins, esters of (meth)acrylic acid and/or maleic acid with C.sub.12 -C.sub.30 alcohols and c) optionally, further hydrophilic, ethylenically unsaturated monomers which are copolymerizable with a) and b), reaction of the anhydride groups with monovalent alcohols comprising at least one ether functionality, and partial neutralization or hydrolysis of the residual acid or anhydride groups and manufacture of a flowable dispersion having an active substance content of at least 40%-wt.

    摘要翻译: PCT No.PCT / EP93 / 02880第 371日期:1995年6月9日 102(e)1995年6月9日PCT 1993年10月19日PCT公布。 公开号WO94 / 10346 日期:1994年5月11日本发明涉及一种通过用可通过a)马来酸酐聚合获得的共聚物的水分散体处理来对皮革和毛皮进行脂肪液化/软化的方法,b)C 12 -C 30α-烯烃,( 甲基)丙烯酸和/或马来酸与C 12 -C 30醇反应,和c)任选的可与a)和b)共聚的亲水性烯属不饱和单体,酸酐基团与包含至少一个醚官能团的一价醇的反应, 并且残留的酸或酸酐基团的部分中和或水解,并制备活性物质含量为至少40重量%的可流动分散体。

    Cross-linked, water-absorbing polymer and its use in the production of
hygiene items
    7.
    发明授权
    Cross-linked, water-absorbing polymer and its use in the production of hygiene items 失效
    交联,吸水聚合物及其在卫生用品生产中的应用

    公开(公告)号:US5408019A

    公开(公告)日:1995-04-18

    申请号:US191742

    申请日:1994-02-01

    CPC分类号: C08F220/04 A61L15/60

    摘要: The invention relates to a cross-linked, water-absorbent polymer obtainable by the polymerization of a mixture consisting of a) 60-99%-wt. unsaturated, polymerizable monomers with acid groups which are neutralized to the extent of at least 30 mol-%, b) 0-37%-wt. monomers copolymerizable with a), c) 0.1-3.0%-wt. of a cross-linking agent and d) 0-10%-wt. of a water-soluble polymer, in which polymerization is conducted with a redox catalyst system containing formamidine sulfinic acid as reducing agent. The polymer is distinguished by a retention of greater than or equal to 28 g 0.9% aqueous NaCl-solution per 1 g of polymer, an absorption of greater than or equal to 26 g 0.9% aqueous NaCl-solution per 1 g of polymer at a load of 20 g/cm.sup.2 and a residual monomer content of less than 700 ppm, and preferably less than 500 ppm. The invention also relates to the use of this polymer in the production of hygiene articles.

    摘要翻译: 本发明涉及一种交联的吸水聚合物,其通过以下混合物的聚合获得:a)60-99重量% 具有酸性基团的不饱和的可聚合单体,其被中和到至少30mol%的程度,b)0-37wt% 可与a)共聚的单体,c)0.1-3.0%重量 的交联剂和d)0-10%-wt。 的水溶性聚合物,其中使用含有甲脒亚磺酸作为还原剂的氧化还原催化剂体系进行聚合。 该聚合物的特征在于每1g聚合物保留大于或等于28g 0.9%的NaCl水溶液,在1g聚合物中每1g聚合物吸收大于或等于26g 0.9%的NaCl水溶液 负载为20g / cm 2,残留单体含量小于700ppm,优选小于500ppm。 本发明还涉及这种聚合物在卫生制品生产中的应用。

    Water-swelling polymers cross-linked with unsaturated amino alcohols,
the production and use of same
    8.
    发明授权
    Water-swelling polymers cross-linked with unsaturated amino alcohols, the production and use of same 失效
    水膨胀聚合物与不饱和氨基醇交联,生产和使用相同

    公开(公告)号:US6087450A

    公开(公告)日:2000-07-11

    申请号:US68562

    申请日:1998-05-20

    摘要: The present invention relates to cross-linked polymers absorbing aqueous liquids, which are built up of partially neutralized, mono-ethylenically unsaturated, acid groups-containing monomers, optionally further monomers copolymerizable with these, as well as optional polymers suitable as a graft basis, and that can be produced by using cross-linking agents of polyunsaturated amino alcohols. The used cross-linking agents are reaction products of (meth)allylamines with monoglycidyl compounds, di-, tri- or tetraglycidyl compounds, and optional alkylene oxide; reaction products of (meth)allylamines or saturated primary amines with (meth)acrylglycide esters and/or (meth)allyl glycidyl ethers and optional alkylene oxide; as well as reaction products of di- and polyamides with (meth)allyl glycide esters and/or (meth)acrylglycide esters and optional alkylene oxide. The polymers according to the present invention provide superabsorbers whose property level meets the practice-oriented requirements with respect to retention, absorption under pressure, swelling pressure, and permeability for aqueous liquids. Such polymers are used as absorbents for water and aqueous liquids in constructions for the absorption or body fluids, in current-conducting and light-transmitting cables, and in the cultivation of plants.

    摘要翻译: PCT No.PCT / EP96 / 05073 Sec。 371日期:1998年5月20日 102(e)日期1998年5月20日PCT 1996年11月18日PCT PCT。 公开号WO97 / 18889 日期:1997年5月29日本发明涉及吸收水性液体的交联聚合物,其由部分中和的,单烯属不饱和的含酸基团的单体,任选地可与其共聚的其它单体以及任选的聚合物构成, 移植物基础,并且可以通过使用多不饱和氨基醇的交联剂制备。 使用的交联剂是(甲基)烯丙胺与单缩水甘油基化合物,二,三或四缩水甘油基化合物和任选的环氧烷烃的反应产物; (甲基)烯丙基胺或饱和伯胺与(甲基)丙烯酰氨基酯和/或(甲基)烯丙基缩水甘油醚和任选的环氧烷烃的反应产物; 以及二酰胺和聚酰胺与(甲基)烯丙基糖苷酯和/或(甲基)丙烯酰氧基酯和任选的环氧烷烃的反应产物。 根据本发明的聚合物提供超吸收剂,其性能水平符合关于水分液体的保留,吸收压力,溶胀压力和渗透性的实践取向要求。 这种聚合物用作用于吸收或体液,导电和透光电缆以及植物培养的结构中的水和含水液体的吸收剂。

    Alkoxy group containing copolymers and their use in retanning leather
    9.
    发明授权
    Alkoxy group containing copolymers and their use in retanning leather 失效
    含烷氧基的共聚物及其在复鞣皮革中的应用

    公开(公告)号:US5873908A

    公开(公告)日:1999-02-23

    申请号:US735987

    申请日:1996-10-25

    摘要: The present invention relates to alkoxy-groups-containing copolymers of a) 1 to 99%-wt. water soluble ethylenically unsaturated, acid-groups-containing monomers, b) 1 to 50%-wt. monomers having a polyalkoxy sequence and c) 0 to 60%-wt. water soluble monomers which are copolymerizable with a) and b); and to the use of said copolymers for retanning leathers previously tanned by a mineral or combined method. The leathers treated with the retanning agents according to the invention in particular stand out for an improved fullness and good grain tightness.The acid groups of monomers a) preferably are carboxyl groups.

    摘要翻译: 本发明涉及a)1至99重量%的含烷氧基基团的共聚物。 水溶性烯属不饱和的含酸基团的单体,b)1〜50重量% 具有聚烷氧基序列的单体和c)0至60重量% 可与a)和b)共聚的水溶性单体; 以及所述共聚物用于复鞣以前由矿物或组合方法鞣制的皮革的用途。 用根据本发明的复鞣剂处理的皮革特别突出,以改善丰满度和良好的颗粒紧密度。 单体的酸基a)优选为羧基。

    Use of copolymers having polysiloxane units in the treatment of leather
and furs
    10.
    发明授权
    Use of copolymers having polysiloxane units in the treatment of leather and furs 失效
    使用具有聚硅氧烷单元的共聚物来处理皮革和毛皮

    公开(公告)号:US5433753A

    公开(公告)日:1995-07-18

    申请号:US244187

    申请日:1994-05-25

    CPC分类号: C08F290/148 C14C9/00

    摘要: The present invention discloses the use of polymers which have built-in by polymerization 20 to 70%-wt. of a hydrophobic monomer selected from long-chain alpha-olefins, long-chain alkyl(meth)acrylates, vinyl esters of long-chain carboxylic acids, long-chain vinyl ethers, or mixtures of these monomers, 1 to 60%-wt. of a monomer with a specific polysiloxane group, and 20 to 35%-wt. water-soluble, unsaturated acids, unsaturated C.sub.4 -C.sub.6 dicarboxylic anhydrides, semi-esters or semi-amides of unsaturated C.sub.4 -C.sub.6 dicarboxylic acids, or mixtures of these monomers, in partially neutralized form as aqueous solution or dispersion, for softening, fat-liquoring and greasing, or hydrophobing leathers and furs.

    摘要翻译: PCT No.PCT / EP92 / 02698 371日期:1994年5月25日 102(e)日期1994年5月25日PCT提交1992年11月24日PCT公布。 公开号WO93 / 11268 PCT 日期:1993年6月10日。本发明公开了通过聚合反应20〜70重量%的聚合物的用途。 的选自长链α-烯烃,长链烷基(甲基)丙烯酸酯,长链羧酸的长链乙烯基醚,长链乙烯基醚或这些单体的混合物的疏水性单体,1至60重量% 的具有特定聚硅氧烷基团的单体和20至35重量% 水溶性不饱和酸,不饱和C 4 -C 6二羧酸酐,不饱和C 4 -C 6二羧酸的半酯或半酰胺或这些单体的混合物,作为水溶液或分散体部分中和形式,用于软化, 浸泡和润滑,或疏水皮革和毛皮。