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公开(公告)号：USRE32628E
公开(公告)日：1988-03-22
申请号：US934459
申请日：1986-11-24
申请人： Helmut Tesch , Manfred Heym , Walter Doerflinger , Herbert Stutz , Peter Neumann , Dietmar Nissen , Gerhard Schaefer
发明人： Helmut Tesch , Manfred Heym , Walter Doerflinger , Herbert Stutz , Peter Neumann , Dietmar Nissen , Gerhard Schaefer
IPC分类号： C08G59/00 , C08G59/18 , C08G59/50 , C08J3/24 , C09D163/00 , C09J163/00
CPC分类号： C08J3/24 , C08G59/18 , C08G59/5033 , C08J2363/00
摘要： A solvent-free curable composition has a long shelf life and consists ofA 100 parts by weight of an epoxy resin andB from 10 to 100 parts by weight of .[.,.]. .Iadd.4,4-bis-(para-aminobenzoyl)-piperazine .Iaddend.as a curing agent for the epoxy resin, .[.an aromatic diamine containing ##STR1## groups,.]. with or without C from 0.01 to 5 parts by weight of an accelerator, the curing agent for the epoxy resin being finely dispersed in the latter and preferably having a particle size of less than 10 .mu.m. .[.The preferred epoxy resin curing agent is 4,4'-diaminodiphenyl ketone..]. The curable composition is used in particular for the preparation of fiber-reinforced materials.
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公开(公告)号：US4607069A
公开(公告)日：1986-08-19
申请号：US751389
申请日：1985-07-03
申请人： Helmut Tesch , Manfred Heym , Walter Doerflinger , Herbert Stutz , Peter Neumann , Dietmar Nissen , Gerhard Schaefer
发明人： Helmut Tesch , Manfred Heym , Walter Doerflinger , Herbert Stutz , Peter Neumann , Dietmar Nissen , Gerhard Schaefer
IPC分类号： C08G59/00 , C08G59/18 , C08G59/50 , C08J3/24 , C09D163/00 , C09J163/00
CPC分类号： C08J3/24 , C08G59/18 , C08G59/5033 , C08J2363/00
摘要： A solvent-free curable composition has a long shelf life and consists ofA 100 parts by weight of an epoxy resin andB from 10 to 100 parts by weight of, as a curing agent for the epoxy resin, an aromatic diamine containing ##STR1## groups, with or without C from 0.01 to 5 parts by weight of an accelerator, the curing agent for the epoxy resin being finely dispersed in the latter and preferably having a particle size of less than 10 .mu.m. The preferred epoxy resin curing agent is 4,4'-diaminodiphenyl ketone. The curable composition is used in particular for the preparation of fiber-reinforced materials.
摘要翻译： 无溶剂的可固化组合物具有长的保质期，由A 100重量份的环氧树脂组成，B为10-100重量份，作为环氧树脂的固化剂，含有
基团，有或没有C为0.01〜5重量份的促进剂，环氧树脂的固化剂在后者中精细分散，优选具有小于10μm的粒径。 优选的环氧树脂固化剂是4,4'-二氨基二苯酮。 可固化组合物特别用于制备纤维增强材料。 -
公开(公告)号：US5364825A
公开(公告)日：1994-11-15
申请号：US64428
申请日：1993-05-21
IPC分类号： B01J23/31 , B01J23/00 , B01J23/88 , B01J23/887 , B01J27/057 , B01J27/18 , B01J27/199 , B01J35/00 , C07B61/00 , C07C45/32 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/37 , C07C45/38 , C07C47/22 , C07C51/25 , C07C57/04 , C07C57/05 , B01J21/02 , B01J21/08 , B01J23/28 , B01J23/30 , B01J27/192 , B01J37/04
CPC分类号： C07C51/252 , B01J23/002 , B01J23/8876 , B01J35/0006 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/37 , C07C45/38 , B01J2523/00
摘要： Multimetal oxide compositions of the formula I[X.sup.1.sub.a X.sup.2.sub.b O.sub.x ].sub.p [X.sup.3.sub.c X.sup.4.sub.d X.sup.5.sub.e X.sup.6.sub.f X.sup.7.sub.g X.sup.2.sub.h O.sub.y ].sub.q(I)whereX.sup.1 is bismuth, tellurium, antimony, tin and/or copper,X.sup.2 is molybdenum and/or tungsten,X.sup.3 is an alkali metal, thallium and/or samarium,X.sup.4 is an alkaline earth metal, nickel, cobalt, copper, manganese, zinc, tin, cadmium and/or mercury,X.sup.5 is iron, chromium, cerium and/or vanadium,X.sup.6 is phosphorus, arsenic, boron and/or antimony,X.sup.7 is a rare-earth metal, titanium, zirconium, niobium, tantalum, rhenium, ruthenium, rhodium, silver, gold, aluminum, gallium, indium, silicon, germanium, lead, thorium and/or uranium,a is from 0.01 to 8,b is from 0.1 to 30,c is from 0 to 4,d is from 0 to 20,e is from 0 to 20,f is from 0 to 6,g is from 0 to 15,h is from 8 to 16,x and y are numbers determined by the valency and frequency of the elements in I other than oxygen, and p and q are numbers whose ratio p/q is from 0.1 to 10, containing three-dimensional regions with a chemical composition X.sup.1.sub.a X.sup.2.sub.b O.sub.x which are delimited from their local environment due to their chemical composition which is different from their local environment, and whose maximum diameter is from 1 to 25 .mu.m.
摘要翻译： 式I的多金属氧化物组合物[X1aX2bOx] p [X3cX4dX5eX6fX7gX2hOy] q（I）其中X1是铋，碲，锑，锡和/或铜，X2是钼和/或钨，X3是碱金属，铊和/ 或钐，X4是碱土金属，镍，钴，铜，锰，锌，锡，镉和/或汞，X5是铁，铬，铈和/或钒，X6是磷，砷，硼和/或 锑，X7是稀土金属，钛，锆，铌，钽，铼，钌，铑，银，金，铝，镓，铟，硅，锗，铅，钍和/或铀， 至8，b为0.1至30，c为0至4，d为0至20，e为0至20，f为0至6，g为0至15，h为8至 如图16所示，x和y是除了氧以外的I中的元素的化合价和频率确定的数字，p和q是比值p / q为0.1至10的数字，其含有化学成分为X1aX2bOxw的三维区域 由于其化学成分与当地环境不同，其最大直径为1〜25亩，与当地环境有区别。
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公开(公告)号：US5449821A
公开(公告)日：1995-09-12
申请号：US268504
申请日：1994-06-30
IPC分类号： B01J23/31 , B01J23/00 , B01J23/88 , B01J23/887 , B01J27/057 , B01J27/18 , B01J27/199 , B01J35/00 , C07B61/00 , C07C45/32 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/37 , C07C45/38 , C07C47/22 , C07C51/25 , C07C57/04 , C07C57/05 , C07C51/16
CPC分类号： C07C51/252 , B01J23/002 , B01J23/8876 , B01J35/0006 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/37 , C07C45/38 , B01J2523/00
摘要： A process for the gas phase catalytic oxidation of a C.sub.3-6 alkane, alkanol, alkene or alkenal using as a catalyst multimetal oxide compositions of the formula I, [X.sup.1.sub.a X.sup.2.sub.b O.sub.x ].sub.p [X.sup.3.sub.c X.sup.4.sub.d X.sup.5.sub.e X.sup.6.sub.f X.sup.7.sub.g X.sup.2.sub.h O.sub.y ].sub.q, where X.sup.1 is bismuth, tellurium, antimony, tin and/or copper, X.sup.2 is molybdenum and/or tungsten, X.sup.3 is an alkali metal, thallium and/or samarium, X.sup.4 is an alkaline earth metal, nickel, cobalt, copper, manganose, zinc, tin, cadmium and/or mercury, X.sup.6 is iron, chromium, cerium and/or vanadium, X.sup.6 is phosphorus, arsenic, boron and/or antimony, X.sup.7 is a rare-earth metal, titanium, zirconium, niobium, tantalum, rhenium, ruthenium, rhodium, silver, gold, aluminum, gallium, indium, silicon, geranium, lead, thorium and/or uranium, a is from 0.01 to 8, b is from 0.1 to 30, c is from 0 to 4, d is from 0 to 20, e is from 0 to 20, f is from 0 to 6, g is from 0 to 15, h is from 8 to 16, x and y are numbers determined by the valency and frequency of the elements in I other than oxygen, and p and q are numbers whose ratio p/q is from 0.1 to 10, containing three-dimensional regions with a chemical composition X.sup.1.sub.a X.sup.2.sub.b O.sub.x which are delimited from their local environment due to their chemical composition which is different from their local environment, and whose maximum diameter is from 1 to 25 .mu.m.
摘要翻译： 使用式I的催化剂多金属氧化物组合物[X1aX2bOx] p [X3cX4dX5eX6fX7gX2hOy] q进行气相催化氧化C3-6烷烃，链烷醇，烯烃或烯烃的方法，其中X1是铋，碲，锑， 锡和/或铜，X2是钼和/或钨，X3是碱金属，铊和/或钐，X4是碱土金属，镍，钴，铜，锰，锌，锡，镉和/或汞 X6是铁，铬，铈和/或钒，X6是磷，砷，硼和/或锑，X7是稀土金属，钛，锆，铌，钽，铼，钌，铑，银，金 ，铝，镓，铟，硅，天竺葵，铅，钍和/或铀，a为0.01至8，b为0.1至30，c为0至4，d为0至20，e为 0至20，f为0至6，g为0至15，h为8至16，x和y为除氧以外的I中的元素的化合价和频率确定的数，p和q为 数 s，其比率p / q为0.1至10，包含化学成分X1aX2bOx的三维区域，其化学成分与其局部环境不同，其局部环境由于其局部环境而界定，其最大直径为1〜 25亩。
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5.发明授权Regeneration of spent multimetal oxide oxidation catalysts from the catalytic gas-phase oxidation of lower organic compounds 失效废多余氧化物氧化催化剂从低级有机化合物的催化气相氧化中的再生
公开(公告)号：US5512525A
公开(公告)日：1996-04-30
申请号：US189734
申请日：1994-02-01
摘要： A process for regenerating spent multimetal oxide oxidation catalysts from the catalytic gas-phase oxidation of lower organic compounds and which, in fresh form, contain as basic constituents the elements Mo, W, V and Cu in oxidic form, by the action of oxidizing agents or means and solubilizing, aqueous ammonia to which acetic acid and/or the ammonium salt thereof has been added, with subsequent drying and calcination, comprises quantitatively determining the content of metallic constituents during the process and making this content up to the respective original value.
摘要翻译： 一种从低级有机化合物的催化气相氧化中再生废多元氧化物氧化催化剂的方法，其以新鲜形式含有氧化剂中的Mo，W，V和Cu元素作为基本成分的元素Mo，W，V和Cu， 或手段和溶解其中加入了乙酸和/或其铵盐的氨水，随后进行干燥和煅烧，包括在该过程中定量测定金属成分的含量并使其含量达到相应的原始值。
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