公开(公告)号：US07157132B2

公开(公告)日：2007-01-02

申请号：US10182538

申请日：2001-01-10

申请人： Ursula Murschall ,  Ulrich Kern ,  Andreas Stopp ,  Guenther Crass ,  Herbert Peiffer

发明人： Ursula Murschall ,  Ulrich Kern ,  Andreas Stopp ,  Guenther Crass ,  Herbert Peiffer

IPC分类号： B32B27/08 ,  B32B27/18 ,  B32B27/20 ,  B32B27/36 ,  B32B37/15

CPC分类号： B32B27/18 ,  B32B27/36 ,  Y10S428/91 ,  Y10T428/24355 ,  Y10T428/24942 ,  Y10T428/2495 ,  Y10T428/24959 ,  Y10T428/24967 ,  Y10T428/24975 ,  Y10T428/25 ,  Y10T428/259 ,  Y10T428/28 ,  Y10T428/2813 ,  Y10T428/2817 ,  Y10T428/2826 ,  Y10T428/2924 ,  Y10T428/2947 ,  Y10T428/2969 ,  Y10T428/31565 ,  Y10T428/31616 ,  Y10T428/3162 ,  Y10T428/31786

摘要： Biaxially oriented, co-extruded polyester films comprising a base layer consisting of at least 90 wt. % thermoplastic polyester, preferably polyethylene terephthalate (PET), at least one sealable outer layer and a second non-sealable outer layer and, optionally, other intermediate layers, in addition to at least one flame-retardant agent, preferably organic phosphorous compounds. The inventive films are characterized by low inflammability, high UV stability, no embrittlement when subjected to thermal stress and a surface which is devoid of troublesome opacity. They are suitable for a multiplicity of uses both indoors and outside. The outer layers contain anti-blocking agents such as silicic acid having an average particle diameter of preferably less than 50 nm and/or 2 μm. Preferably, the sealable outer layer consists of a copolyester which is made of ethylene terephthalate and ethylene isophthalate units.

摘要翻译： 双轴取向的共挤出聚酯膜，其包含由至少90重量％ ％热塑性聚酯，优选聚对苯二甲酸乙二醇酯（PET），至少一个可密封外层和第二不可密封外层以及任选的其它中间层，除了至少一种阻燃剂，优选有机磷化合物。 本发明的薄膜的特征在于低的易燃性，高的UV稳定性，当受到热应力时没有脆化以及没有麻烦的不透明度的表面。 它们适用于室内和室外的多种用途。 外层含有平均粒径优选小于50nm和/或2μm的防粘连剂，例如硅酸。 优选地，可密封的外层由共聚酯由对苯二甲酸乙二醇酯和间苯二甲酸乙二醇酯单元组成。

公开(公告)号：US06881470B2

公开(公告)日：2005-04-19

申请号：US10182456

申请日：2001-01-10

申请人： Ursula Murschall ,  Ulrich Kern ,  Andreas Stopp ,  Guenther Crass ,  Herbert Peiffer

发明人： Ursula Murschall ,  Ulrich Kern ,  Andreas Stopp ,  Guenther Crass ,  Herbert Peiffer

IPC分类号： B32B27/36 ,  C08K3/36 ,  C08K5/13 ,  C08K5/5317 ,  C08L67/02 ,  B32B27/08 ,  B32B27/18 ,  B32B31/16 ,  B32B31/30

CPC分类号： B32B27/36 ,  Y10S428/91 ,  Y10T428/16 ,  Y10T428/24355 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/24975 ,  Y10T428/25 ,  Y10T428/259 ,  Y10T428/2813 ,  Y10T428/2817 ,  Y10T428/2826 ,  Y10T428/2852 ,  Y10T428/31681 ,  Y10T428/31786 ,  Y10T428/31906

摘要： Biaxially oriented, co-extruded polyester films comprising a base layer consisting of at least 90 wt. % thermoplastic polyester, preferably polyethylene terephthalate (PET), at least one sealable outer layer and a second non-sealable outer layer and, optionally, other intermediate layers, in addition to at least one flame-retardant agent, preferably organic phosphorous compounds. The inventive films are characterized by low inflammability, no embrittlement when subjected to thermal stress and a surface which is devoid of troublesome opacity, and are suitable for a multiplicity of uses both indoors and outside. The outer layers contain anti-blocking agents such as silicic acid having a particle diameter of preferably less than 50 nm and/or more than 2 μm. Preferably, the sealable outer layer consists of a copolyester which is made of ethylene terephthalate and ethylene isophthalate units.

摘要翻译： 双轴取向的共挤出聚酯膜，其包含由至少90重量％ ％热塑性聚酯，优选聚对苯二甲酸乙二醇酯（PET），至少一个可密封外层和第二不可密封外层以及任选的其它中间层，除了至少一种阻燃剂，优选有机磷化合物。 本发明的薄膜的特征在于低的易燃性，当受到热应力时没有脆化，并且表面没有麻烦的不透明度，并且适用于室内和室外的多种用途。 外层包含防粘连剂，例如粒径优选小于50nm和/或大于2μm的硅酸。 优选地，可密封的外层由共聚酯由对苯二甲酸乙二醇酯和间苯二甲酸乙二醇酯单元组成。

公开(公告)号：US06863954B2

公开(公告)日：2005-03-08

申请号：US10429307

申请日：2003-05-05

申请人： Herbert Peiffer ,  Guenther Crass ,  Ulrich Kern ,  Ursula Murschall ,  Andreas Stopp

发明人： Herbert Peiffer ,  Guenther Crass ,  Ulrich Kern ,  Ursula Murschall ,  Andreas Stopp

IPC分类号： C08J3/22 ,  B29C47/06 ,  B32B27/36 ,  C08J5/18 ,  C08K3/36 ,  C08K5/3475 ,  C08K5/3492 ,  C08L67/00 ,  G09F7/00 ,  G09F15/02 ,  B32B27/08 ,  B32B27/20 ,  B32B31/33

CPC分类号： G09F7/00 ,  G09F15/02 ,  Y10S428/91 ,  Y10T428/24355 ,  Y10T428/24942 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/24975 ,  Y10T428/25 ,  Y10T428/259 ,  Y10T428/2817 ,  Y10T428/2826 ,  Y10T428/31786 ,  Y10T428/31797

摘要： Biaxially oriented, coextruded polyester films with a base layer at least 90% by weight of which is composed of a thermoplastic polyester, preferably polyethylene terephthalate (PET), and with at least one sealable outer layer and a second nonsealable outer layer and, if desired, with other intermediate layers, and comprising at least one UV absorber, preferably hydroxybenzotriazoles and triazines, have high UV resistance, do not embrittle when exposed to high temperatures, have a surface without undesirable haze and are suitable for numerous indoor and outdoor applications. The outer layers comprise antiblocking agents, such as silica with an average particle diameter preferably below 50 nm and/or above 2 μm, and the sealable outer layer is preferably composed of a copolyester which has been built up from ethylene terephthalate units and ethylene isophthalate units.

摘要翻译： 双轴取向的共挤出聚酯膜，其基层至少90重量％由热塑性聚酯，优选聚对苯二甲酸乙二酯（PET）组成，并具有至少一个可密封外层和第二不可密封外层，如果需要 和其它中间层，并且包含至少一种UV吸收剂，优选羟基苯并三唑和三嗪，具有高抗紫外线性，当暴露于高温时不会脆化，具有无需不希望的雾度的表面，并且适用于许多室内和室外应用。 外层包含防粘连剂，例如平均粒径优选低于50nm和/或2μm以上的二氧化硅，并且可密封的外层优选由共聚酯组成，其由对苯二甲酸乙二醇酯单元和间苯二甲酸乙二醇酯单元构成 。

公开(公告)号：US07186455B2

公开(公告)日：2007-03-06

申请号：US10181505

申请日：2001-01-11

申请人： Ursula Murschall ,  Andreas Stopp ,  Guenther Crass ,  Ulrich Kern

发明人： Ursula Murschall ,  Andreas Stopp ,  Guenther Crass ,  Ulrich Kern

IPC分类号： B32B7/02 ,  B32B27/20 ,  B32B27/36 ,  B32B37/15

CPC分类号： B32B27/18 ,  B32B27/08 ,  B32B27/20 ,  B32B27/36 ,  B32B2272/00 ,  B32B2307/4026 ,  B32B2307/518 ,  B32B2307/71 ,  B32B2367/00 ,  B32B2419/06 ,  B32B2605/00 ,  C08J5/18 ,  C08J2367/02 ,  C08K5/005 ,  C08K5/0066 ,  C08K5/3475 ,  C08K5/3492 ,  C08K5/5333 ,  Y10S428/91 ,  Y10T428/24942 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/258 ,  Y10T428/259 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/31786 ,  C08L67/02

摘要： The invention relates to a white, biaxially oriented film which comprises a crystallizable thermoplastic as main componet and is characterized by further comprising at least one UV-stabilizer, at least one white pigment and at least one flame-proofing agent, which is soluble in the thermoplastic and introduced directly, during the film production, by masterbatch technology, whereby the masterbatch is pre-conditioned by gradual heating under reduced pressure and with stirring.

摘要翻译： 本发明涉及一种白色双轴取向膜，其包含可结晶热塑性塑料作为主要成分，其特征在于还包含至少一种UV稳定剂，至少一种白色颜料和至少一种阻燃剂，其可溶于 通过母料技术在薄膜生产过程中直接引入，并通过在减压下和搅拌下逐渐加热预处理母料。

公开(公告)号：US07138176B2

公开(公告)日：2006-11-21

申请号：US09760169

申请日：2001-01-12

申请人： Ursula Murschall ,  Ulrich Kern ,  Guenther Crass ,  Andreas Stopp

发明人： Ursula Murschall ,  Ulrich Kern ,  Guenther Crass ,  Andreas Stopp

IPC分类号： B32B23/04 ,  B32B23/16

CPC分类号： C08J3/226 ,  C08J5/18 ,  C08J2367/02 ,  C08J2467/00 ,  C09K21/12 ,  Y10S428/91 ,  Y10S428/921 ,  Y10T428/263 ,  Y10T428/265 ,  Y10T428/31786

摘要： The present invention relates to a transparent, low-flammability, UV-resistant, oriented film made from a crystallizable thermoplastic and having a thickness of from 5 to 300 μm. The film comprises at least one UV stabilizer and at least one flame retardant, and at least the flame retardant, and preferably also the UV stabilizer, is fed directly as a masterbatch to the crystallizable thermoplastic during production of the film. The film may have one or more layers, and the UV stabilizer may have been selected from the group consisting of the 2-hydroxybenzophenones, the 2-hydroxybenzotriazoles, the organonickel compounds, the salicylic esters, the cinnamic ester derivatives, the resorcinol monobenzoates, the oxanilides, the hydroxybenzoic esters, the sterically hindered amines and triazines, and the flame retardant may be an organic phosphorus compound, in particular an organic phosphorus compound soluble in polyethylene terephthalate.

摘要翻译： 本发明涉及由可结晶的热塑性塑料制成并具有5至300μm厚度的透明，低阻燃，耐紫外线的取向膜。 该膜包括至少一种UV稳定剂和至少一种阻燃剂，并且至少阻燃剂，优选UV稳定剂，在制备膜期间直接作为母料进料到可结晶的热塑性塑料。 该膜可以具有一层或多层，UV稳定剂可以选自2-羟基二苯甲酮，2-羟基苯并三唑，有机镍化合物，水杨酸酯，肉桂酸酯衍生物，间苯二酚单苯甲酸酯， 草酰胺，羟基苯甲酸酯，空间位阻胺和三嗪，阻燃剂可以是有机磷化合物，特别是可溶于聚对苯二甲酸乙二醇酯的有机磷化合物。

公开(公告)号：US06902818B2

公开(公告)日：2005-06-07

申请号：US10181514

申请日：2001-01-10

申请人： Ursula Murschall ,  Ulrich Kern ,  Andreas Stopp ,  Guenther Crass

发明人： Ursula Murschall ,  Ulrich Kern ,  Andreas Stopp ,  Guenther Crass

IPC分类号： B29C55/02 ,  B29K101/12 ,  B29K105/32 ,  B29L7/00 ,  B32B27/18 ,  B32B27/36 ,  C08J5/18 ,  C08K5/00 ,  C08K5/3467 ,  C08K5/3475 ,  C08K5/3492 ,  C08L101/00

CPC分类号： B32B27/18 ,  B32B27/08 ,  B32B27/32 ,  B32B27/36 ,  B32B2307/412 ,  B32B2307/518 ,  B32B2307/71 ,  B32B2307/738 ,  B32B2323/04 ,  B32B2367/00 ,  B32B2419/06 ,  B32B2590/00 ,  C08J5/18 ,  C08J2367/02 ,  C08K5/005 ,  C08K5/3475 ,  C08K5/3492 ,  Y10T428/31565 ,  Y10T428/31587 ,  Y10T428/31649 ,  Y10T428/31786 ,  C08L67/02

摘要： The invention relates to a transparent, UV-stabilized, single or multi-layered thermoformable film which contains, as a principal constituent, a crystallizable thermoplastic, preferably polyethylene terephthalate, and at least one UV-stabilizer. The inventive films are characterized by having a good stretchability, thermoformability and good optical and mechanical properties. Said films are suitable for outdoor uses just like shaped bodies made of the same.

摘要翻译： 本发明涉及一种透明的，UV稳定的单层或多层可热成膜，其以可结晶的热塑性材料，优选聚对苯二甲酸乙二醇酯和至少一种UV稳定剂为主要成分。 本发明的膜的特征在于具有良好的拉伸性，热成型性和良好的光学和机械性能。 所述胶片适合户外用途，就像使用同样的成型体一样。

公开(公告)号：US06875803B2

公开(公告)日：2005-04-05

申请号：US10181529

申请日：2001-01-10

申请人： Ursula Murschall ,  Ulrich Kern ,  Andreas Stopp ,  Guenther Crass

发明人： Ursula Murschall ,  Ulrich Kern ,  Andreas Stopp ,  Guenther Crass

IPC分类号： B29C55/02 ,  B29L7/00 ,  B29L9/00 ,  B32B27/18 ,  B32B27/36 ,  C08J5/18 ,  C08K5/00 ,  C08L101/00 ,  C08K5/34 ,  C08K5/09 ,  C08K5/53

CPC分类号： B32B27/18 ,  B32B27/08 ,  B32B27/36 ,  B32B2307/3065 ,  B32B2307/412 ,  B32B2307/71 ,  B32B2307/738 ,  B32B2367/00 ,  B32B2419/06 ,  B32B2451/00 ,  B32B2590/00 ,  C08J5/18 ,  C08J2367/02 ,  Y10T428/31786

摘要： The invention concerns transparent, flame retardant, thermoformable, UV-stabilized, single layered or multilayered films, containing a cristallizable thermoplastic material, preferably polyethyleneterephthalate, at least one flame retarding agent and a UV stabilizer as main components. Said films are characterized by good stretchability, thermoformability and good optical and mechanical properties, which makes them and the shaped bodies made from said films suitable for both inner and outer applications.

摘要翻译： 本发明涉及透明，阻燃，可热成形，UV稳定的单层或多层膜，其含有可重结晶的热塑性材料，优选聚对苯二甲酸乙二醇酯，至少一种阻燃剂和UV稳定剂作为主要成分。 所述膜的特征在于良好的拉伸性，热成型性和良好的光学和机械性能，这使得它们和由所述膜制成的成形体适用于内部和外部应用。

公开(公告)号：US06794432B2

公开(公告)日：2004-09-21

申请号：US10181506

申请日：2002-07-18

申请人： Ursula Murschall ,  Ulrich Kern ,  Andreas Stopp ,  Guenther Crass

发明人： Ursula Murschall ,  Ulrich Kern ,  Andreas Stopp ,  Guenther Crass

IPC分类号： C08K55333

CPC分类号： B32B27/18 ,  B32B27/06 ,  B32B27/08 ,  B32B27/36 ,  B32B2307/3065 ,  B32B2307/412 ,  B32B2307/518 ,  B32B2307/738 ,  B32B2367/00 ,  B32B2419/06 ,  B32B2451/00 ,  B32B2590/00 ,  B32B2605/00 ,  Y10S428/91 ,  Y10T428/31786

摘要： The invention concerns transparent, flame-retardant, single layered or multilayered thermoformable films, containing a crystallizable thermoplastic material, preferably polyethyleneterephthalate, and at least one flame retarding agent as main components. Said films are characterized by good stretchability, thermoformability and good mechanical and optical properties, which makes them and the shaped bodies made from said films suitable for both inner and outer applications.

摘要翻译： 本发明涉及含有可结晶热塑性材料，优选聚对苯二甲酸乙二醇酯和至少一种阻燃剂作为主要成分的透明，阻燃，单层或多层可热成膜。 所述膜的特征在于良好的拉伸性，热成型性和良好的机械和光学性能，这使得它们和由所述膜制成的成形体适用于内部和外部应用。

公开(公告)号：US06797358B2

公开(公告)日：2004-09-28

申请号：US10182294

申请日：2002-07-26

申请人： Ursula Murschall ,  Ulrich Kern ,  Guenther Crass ,  Herbert Peiffer ,  Hans Mahl

发明人： Ursula Murschall ,  Ulrich Kern ,  Guenther Crass ,  Herbert Peiffer ,  Hans Mahl

IPC分类号： B32B2708

CPC分类号： B32B27/36 ,  B29K2995/0072 ,  B32B27/18 ,  Y10S428/91 ,  Y10T428/24355 ,  Y10T428/24942 ,  Y10T428/2817 ,  Y10T428/2826 ,  Y10T428/2852 ,  Y10T428/31786

摘要： The invention concerns a unilaterally mat, sealable, UV-stabilized and flame-resistant, sealable, co-extruded, biaxially oriented polyester film comprising at least one base layer (B) and a sealable top coating (A) applied to both sides of said base layer, in addition to a mat covering (C). The film also contains at least one UV stabilizer as a light stabilizer. The invention further concerns a method for the production of said film and the use thereof.

摘要翻译： 本发明涉及单面毡，可密封的，UV稳定的和阻燃的，可密封的，共挤出的双轴取向聚酯膜，其包含至少一个基层（B）和可密封的顶涂层（A），其施加到所述 基层，除了覆盖（C）之外。 该膜还含有至少一种UV稳定剂作为光稳定剂。 本发明还涉及一种生产所述薄膜的方法及其用途。

公开(公告)号：US06841222B2

公开(公告)日：2005-01-11

申请号：US10182340

申请日：2001-02-07

申请人： Ursula Murschall ,  Klaus Oberlaender ,  Guenther Crass ,  Ulrich Kern ,  Herbert Peiffer

发明人： Ursula Murschall ,  Klaus Oberlaender ,  Guenther Crass ,  Ulrich Kern ,  Herbert Peiffer

IPC分类号： B29C55/12 ,  B29K67/00 ,  B29L7/00 ,  B29L9/00 ,  B32B27/36 ,  B32B27/08 ,  B32B27/18 ,  B32B27/20 ,  B32B31/30

CPC分类号： B32B27/36 ,  Y10S428/91 ,  Y10T428/24355 ,  Y10T428/24942 ,  Y10T428/2495 ,  Y10T428/24959 ,  Y10T428/24967 ,  Y10T428/24975 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/28 ,  Y10T428/2813 ,  Y10T428/2817 ,  Y10T428/2826 ,  Y10T428/31565 ,  Y10T428/31616 ,  Y10T428/3162 ,  Y10T428/31786

摘要： The invention relates to a white, sealable, flame-retardant coextruded, biaxially oriented polyester film composed of at least one base layer B and of outer layers A and B applied to the two sides of this base layer. The film also comprises at least one flame retardant and one white pigment. The invention also includes the use of the film and a process for its production.

摘要翻译： 本发明涉及一种由至少一个基底层B和施加在该基底层两侧的外层A和B组成的白色可密封的阻燃共挤出双轴取向聚酯膜。 该膜还包含至少一种阻燃剂和一种白色颜料。 本发明还包括膜的使用和其生产方法。