摘要:
The invention relates to isocyanate-terminated polyurethane prepolymers containing a stoichiometric excess of an isocyanate component comprised of one or more aromatic isocyanates containing on average from 2 to 4 isocyanate groups per molecule and a polyol component comprised of an oleochemical polyol prepared by epoxidation of a triglyceride containing olefinic unsaturation and subsequent ring opening with an alcohol. In use, accelerators, flameproofing agents, blowing agents and, optionally, liquefying agents, dyes and/or stabilizers, are included. The oleochemical polyol does not contain any free epoxide groups and is obtained by complete ring opening of epoxidized triglycerides of a fatty acid mixture containing at least partly olefinically unsaturated fatty acids with one or more C.sub.1 -C.sub.12 alcohols and partial conversion by alcoholysis or transesterification of the triglyceride derivatives to alkyl ester polyols containing from 1 to 12 carbon atoms in the alkyl radical. A process for the production of these polyurethane prepolymers and to their use as starting materials for the production of polyurethane foams is included.
摘要:
Process for the production of modified triglycerides which contain epoxide groups, secondary hydroxyl groups and ether groups. The invention particularly relates to the production of reaction products of epoxidized triglycerides, for example epoxidized soy oil, with polyfunctional alcohols, for example glycols. The products so prepared are valuable starting materials, particularly for the production of alkyd resins.
摘要:
Polyurethane prepolymers containing terminal isocyanate groups in which oleochemical polyols are present as the polyol component. The oleochemical polyols are ring opened products or partial ring-opened products of epoxidized fatty acid triglycerides with alcohols. The use of oleochemical polyols having a residual epoxide number of from 1.0 to 4.0% by weight of epoxide oxygen is preferred. The polyurethane prepolymers are particularly suitable for use in one-component or two-component polyurethane foam formulations.
摘要:
The invention relates to two-component polyurethane adhesive preparations in which the resin component is an oleochemical polyol. The oleochemical polyols used are ring-opened products of the reaction of epoxidized fatty alcohols, fatty acid esters (particularly triglycerides) or fatty acid amides with alcohols. The oleochemical polyols may be varied within wide limits in regard to their OH-functionality and so formulated with the hardener polyisocyanate components that the adhesives satisfy the relevant requirements. Reaction products of epoxidized triglycerides with monohydric alcohols are a particularly effective substitute for castor oil.
摘要:
Reactive resin systems suitable for cast-molding polyurethanes comprise reactive isocyanates and chain extenders for the isocyanates comprising polyol addition products of C.sub.1 -C.sub.8 alcohols and epoxidized triglyceride oils: if desired, the polyol addition products used have been alkoxylated with C.sub.2 -C.sub.4 -alkylene oxides.
摘要:
Alkaline earth salts of vicinally hydroxy, alkoxy-substituted C.sub.16 -C.sub.22 fatty acids corresponding to the following general formula ##STR1## in which R represents linear or branched alkyl or alkenyl groups or hydroxyalkyl groups optionally alkylated with a C.sub.16 -C.sub.22 fatty acid, process for their preparation, and their use as catalysts. These salts give a narrow homolog distribution of the polyalkoxylation products in the catalysis of the polyalkoxylation of compounds containing active hydrogen atoms.
摘要:
The invention relates to the use of alkoxyhydroxy fatty acids and the salts thereof having the general formula (I) ##STR1## wherein R.sup.1 represents a straight chain alkyl radical or a straight chain alkenyl radical having from 6 to 8 carbon atoms,R.sup.2 represents a straight chain or branched chain alkyl radical having from 1 to 18 carbon atoms, or a straight chain or branched chain alkenyl radical having from 2 to 18 carbon atoms,M represents hydrogen or an organic ammonium radical having one or more alkyl radicals or hydroxy alkyl radical attached to the nitrogen atom, andm represents an integer having a value of from 3 to 13,in an amount of from 0.01 to 10% by weight, based on the weight of oil, as corrosion inhibitors in oils and oil-containing emulsions.
摘要:
Water-soluble corrosion-inhibiting mixtures containing(a) one or more ammonium salts of fatty acids corresponding to the following general formula ##STR1## in which n=1 or 2 while R.sup.1, R.sup.2, R.sup.3 and R.sup.4 may be the same or different and represent hydrogen, unbranched or branched C.sub.1 -C.sub.6 alkyl groups, C.sub.1 -C.sub.6 hydroxyalkylene groups or C.sub.1 -C.sub.8 aminoalkylene groups and R.sup.5 represents C.sub.6 -C.sub.10 alkyl groups, and(b) one or more polyol fatty acids and/or salts thereof corresponding to the following general formula ##STR2## in which R.sup.6 is a C.sub.1 -C.sub.19 alkyl or alkylene group and R.sup.7 represents an organic residue formed from a dihydroxy or polyhydroxy compound by elimination of a hydroxyl group, M.sup.(+) =H.sup.(+), Na.sup.(+), K.sup.(+) or an ammonium ion [R.sup.1 R.sup.2 R.sup.3 R.sup.4 N].sup.n +, as in formula (I), and m is an integer of from 0 to 18, and to a process for preparing these water-soluble mixtures and to the use of these mixtures for inhibiting corrosion in drilling oils, cutting oils, rolling oils, grinding oils, metal-cleaning solutions, coolants and lubricants.
摘要:
The invention is a process for degreasing animal skins in which the animal skin to be degreased is contacted with a mixture of a predominantly saturated C.sub.12 -C.sub.18 fatty alcohol ethoxylate having an average of not more than 15 EO groups and a predominantly saturated C.sub.6-10 fatty alcohol ethoxylate having an average of not more than 3 EO groups.
摘要:
The invention is cleaning compositions containing Polyethylene-glycol ethers of the formulaR.sub.1 --(CH.sub.2 CH.sub.2 O).sub.n --R.sub.2 (1)in whichR.sub.1 is a straight-chain or branched alkyl- or alkenyl radical having from 20 to 28 carbon atomsR.sub.2 is an alkyl radical having from 4 to 8 carbon atoms and n is an integer from about 6 to about 20as a foam-suppressing additive. The cleaning compositions are stable over a broad temperature range and having low foaming characteristics particularly at about ambient temperatures.