摘要:
A nonaqueous electrolyte battery of the present invention includes a positive electrode having a positive active material capable of intercalating and deintercalating a lithium ion, a negative electrode having a negative active material capable of intercalating and deintercalating a lithium ion, a separator interposed between the positive electrode and the negative electrode, and a nonaqueous electrolyte. The heat generation starting temperature of the positive electrode is 180° C. or higher. The separator includes heat-resistant fine particles and a thermoplastic resin. The proportion of particles with a particle size of 0.2 μm or less in the heat-resistant fine particles is 10 vol % or less and the proportion of particles with a particle size of 2 μm or more in the heat-resistant fine particles is 10 vol % or less. The separator effects a shutdown in the range of 100° C. to 150° C.
摘要:
A nonaqueous electrolyte battery of the present invention includes a positive electrode having a positive active material capable of intercalating and deintercalating a lithium ion, a negative electrode having a negative active material capable of intercalating and deintercalating a lithium ion, a separator interposed between the positive electrode and the negative electrode, and a nonaqueous electrolyte. The heat generation starting temperature of the positive electrode is 180° C. or higher. The separator includes heat-resistant fine particles and a thermoplastic resin. The proportion of particles with a particle size of 0.2 μm or less in the heat-resistant fine particles is 10 vol % or less and the proportion of particles with a particle size of 2 μm or more in the heat-resistant fine particles is 10 vol % or less. The separator effects a shutdown in the range of 100° C. to 150° C.
摘要:
The non-aqueous secondary battery of the present invention includes a positive electrode, a negative electrode, a non-aqueous electrolyte and a separator. The positive electrode includes a positive electrode mixture layer containing a positive electrode active material, a conductive polymer, an organic silane compound, a conductive assistant and a binder, the conductive polymer is polythiophene or a derivative thereof, and the content of the conductive polymer is 0.05 to 0.5 mass % with respect to the total mass of the positive electrode mixture layer.
摘要:
The electrode for a lithium ion secondary battery of the present invention has an electrode mixture layer containing carbon nanotubes as a conductive auxiliary agent and deoxyribonucleic acid as a dispersant for the carbon nanotubes, and the content of the carbon nanotubes in the electrode mixture layer is 0.001 to 5 parts by mass with respect to 100 parts by mass of active material particles. The lithium ion secondary battery of the present invention has the electrode of the invention as its positive electrode and/or negative electrode. The electrode of the invention can be produced by a producing method of the invention of forming the electrode mixture layer from an electrode mixture-containing composition prepared using a dispersion including carbon nanotubes and deoxyribonucleic acid.
摘要:
A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, a non-aqueous electrolyte, and a separator, wherein the positive electrode includes a positive electrode current collector and a positive electrode material mixture layer formed on one or both sides of the positive electrode current collector, the positive electrode material mixture layer has a thickness greater than 80 μm per side of the positive electrode current collector, the positive electrode material mixture layer includes a positive electrode active material, the positive electrode active material is composed of secondary particles formed by aggregation of primary particles, the secondary particles have an average particle size of 6 μm or less, and, when diffraction-line integrated intensities of the (003) plane and the (104) plane in an X-ray diffraction chart of the positive electrode material mixture layer are I003 and I104, respectively, the ratio I003/I104 of the integrated intensities is 1.1 or more.
摘要:
A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, a non-aqueous electrolyte, and a separator, wherein the positive electrode includes a positive electrode current collector and a positive electrode material mixture layer formed on one or both sides of the positive electrode current collector, the positive electrode material mixture layer has a thickness greater than 80 μm per side of the positive electrode current collector, the positive electrode material mixture layer includes a positive electrode active material, the positive electrode active material is composed of secondary particles formed by aggregation of primary particles, the secondary particles have an average particle size of 6 μm or less, and, when diffraction-line integrated intensities of the (003) plane and the (104) plane in an X-ray diffraction chart of the positive electrode material mixture layer are I003 and I104, respectively, the ratio I003/I104 of the integrated intensities is 1.1 or more.
摘要:
A lithium ion secondary battery containing a negative electrode active material containing Si and O as constituent elements and exhibiting excellent charge-discharge cycle characteristics. The lithium ion secondary battery has a positive electrode having a positive electrode material mixture layer, a negative electrode, a separator and a nonaqueous electrolyte containing at least an electrolyte salt and an organic solvent, where the negative electrode has a negative electrode material mixture layer containing a negative electrode active material containing Si and O as constituent elements (the atomic ratio x of O to Si is 0.5≦x≦1.5). The nonaqueous electrolyte contains the electrolyte salt at a concentration exceeding a concentration at which conductivity in the nonaqueous electrolyte containing the electrolyte salt and the organic solvent is maximized, and the conductivity at 25° C. is 6.5 to 16 mS/cm.
摘要:
It is an object of the present invention to provide a nonaqueous electrolyte battery in which a winding body is uniformly expanded, to thereby prevent undulation. A nonaqueous electrolyte battery (1) comprises a winding body (30) having a flattened shape, in which a positive electrode (31) and a negative electrode (32) are wound with separators (33, 34) interposed therebetween, and a negative electrode tab (36) joined to the negative electrode (32), extending in a winding axis direction of the winding body (30). The positive electrode (31) includes a positive electrode current collector (310) having a strip-like shape, a first positive electrode mixture layer (311) formed on one surface of the positive electrode current collector (310), and a second positive electrode mixture layer (312) formed on the other surface of the positive electrode current collector (310), and a winding trailing end portion (311b) of the first positive electrode mixture layer (311) is positioned on an inner side of the winding body (30) with respect to the negative electrode tab (36) in the width direction (x direction) and a winding trailing end portion (312b) of the second positive electrode mixture layer (312) is positioned on an outer side of the winding body (30) with respect to the negative electrode tab (36) in the width direction (x direction).
摘要:
An electrode active material includes particles of a lithium-containing composite oxide represented by the general compositional formula: Li1+xMO2, where −0.15≦x≦0.15, and M represents an element group of three or more elements including at least Ni, Co and Mn, wherein the ratios of Ni, Co and Mn to the total elements constituting M satisfy 45≦a≦90, 5≦b≦30, 5≦c≦30 and 10≦b+c≦55, where the ratios of Ni, Co and Mn are represented by a, b and c, respectively, in units of mol %, the average valence A of Ni in the whole particles is 2.2 to 3.2, the valence B of Ni on the surface of the particles has the relationship: B