摘要:
The invention provides a method for manufacturing a polysiloxane resin with charge transporting property by uniformly dissolving a charge transporting material to a practical concentration in a polysiloxane resin. The charge transporting material that is dissolved in the polysiloxane resin is an aromatically substituted tertiary amine which has been modified by substitution of one or more of the aromatic groups with a hydrocarbon group containing a silyl group with hydrolyzable substituents.
摘要:
An organosilicon-modified charge transporting compound having a structure represented by the following Formula (I): wherein A represents a charge transporting group, Q represents a hydrolytic group or a hydroxyl group, R2 represents a monovalent hydrocarbon group or a halogen-substituted monovalent hydrocarbon group having 1 to 15 carbon atoms, n is 1 to 18, m is 1 to 3, and 1 is 1 to 5; and a curable composition containing the organosilicon-modified charge transporting compound and a cure type resin chiefly composed of an organosilicon high polymer.
摘要:
An electrophotographic photosensitive member is disclosed which has a photosensitive layer and a protection layer. The protection layer contains a particulate colloidal silica and a siloxane resin to have a contact angle of water of not less than 90.degree.. The photosensitive member has a lowered surface energy and excellent mechanical and electrical durability.
摘要:
A process for the preparation of a photosensitive body surface coating material comprises hydrolytically condensing an alkoxysilane in a mixed solvent comprising an alcohol and water in the presence of finely divided silica. A polysiloxane resin is produced by heat curing the silane after its hydrolytic condensation. The polysiloxane resin has the formula: R.sup.1 SiO.sub.3/2, and R.sup.1 comprises fluorohydrocarbon groups. The photosensitive body surface coating material is not detrimental to the functionality required of the electrophotographic photosensitive bodies, has superior optical uniformity, has low surface energy, and has superior surface hardness.
摘要:
The present invention relates to a hydrosilation-curable organopolysiloxane resin composition comprising (A) an organopolysiloxane resin having three or more monovalent unsaturated aliphatic hydrocarbon groups and aromatic hydrocarbon carbon groups, (B) an organosilicon compound having two or more silicon-bonded hydrogen atoms and aromatic hydrocarbon groups, (C) a hydrosilation catalyst, and optionally (D) (d1) a solvent or (d2) a hydrosilation-reactive organosiloxane-based diluent, for optical transmission components, especially for optical transmission components serving as optical communication elements, relates to optical transmission components, represented by optical waveguides, comprisiong a hydrosilation-cured product of the aforementioned organopolysiloxane resin and organosilicon compound, and relates to a process for fabricatiing optical transmission components.
摘要:
A method of manufacturing charge transporting materials which impart a charge transporting property to a polysiloxane resin, and which is soluble in the resin. The charge transporting material is an aromatic substituted tertiary amine with a plurality of aromatic groups, and a silyl group introduced via a hydrocarbon group, into at least one of the aromatic groups. The method is characterized by using an unsaturated aliphatic group bonded to an aromatic group which makes up the silicon-type charge transporting compound, or using a newly bonded unsaturated aliphatic group which is bonded to a silane in which the substituent for silicon is hydrogen or a hydrolyzable group. This is conducted in the presence of a platinum compound as catalyst by means of hydrosilylation. The silicon-type charge transporting material is then brought into contact with an adsorbent for the platinum compound, causing the platinum compound to be adsorbed onto the adsorbent. The platinum compound is removed along with the adsorbent, so that the concentration of residual platinum compound is less than 10 ppm.
摘要:
The present invention provides a nanoparticle dispersed structure featuring a polymer having a crosslinked structure that is chemically inert with respect to the nanoparticles and that is effective in suppressing diffusion, and provides a method for manufacturing this nanoparticle dispersion.
摘要:
The invention is an optically transparent organopolysiloxane resin with a large amount of a uniformly dissolved and dispersed optically-functional organic material. The compatibility of the optically functional material is achieved by modifying it by addition of alkoxysilylalkyl groups to aromatic groups of optically-functional organic compounds such phthalocyanines, porphyrins, tetraphenylbutadienes, axobenzenes, bis(4-dimethylaminodithiobenzyl)nickel and anthracenes. The compositions contain 20 to 200 parts by weight of the modified optically-functional organic compounds per 100 parts by weight of the organopolysiloxane resin. The composition may be formed into a specified shape, solvents evaporated, and cured by heat.
摘要:
An optical silica-containing polysiloxane resin comprises colloidal silica and a polysiloxane resin. The polysiloxane resin has the formula RSiO.sub.3/2, where R is selected from the group consisting of hydrocarbon groups of 1 to 4 carbon atoms and fluorohydrocarbon groups of 3 to 10 carbon atoms. The fluorohydrocarbon groups have the general formula C.sub.n F.sub.(2n+1) C.sub.2 H.sub.4 --, where n is an integer of 1 to 8. The optical silica-containing polysiloxane resin has high light transmissivity and high surface hardness, and can be used for optical elements.
摘要:
A method of manufacturing solvent-soluble charge transporting materials capable of imparting charge-tranporting properties to polysiloxane resins. These materials have the formula A-�R.sup.1 SiR.sup.2.sub.3-n Q.sub.n !.sub.p where A is a tertiary amine and organic group derived from a compound having charge transporting properties with an ionization potential of 4.5-6.2 eV; R.sup.1 is an alkylene group of 1-18 carbon atoms; R.sup.2 is a monovalent hydrocarbon group or a monovalent halogen-substituted hydrocarbon group of 1-15 carbon atoms; Q is a hydrolyzable group such as--OR.sup.3 where R.sup.3 is an alkyl group of 1-6 carbon atoms; n and p are each 1-3. This silicon-type charge transporting material is characterized by aromatic groups, and alkoxysilyl groups bonded via hydrocarbon groups onto the aromatic rings.