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公开(公告)号：US20070172737A1
公开(公告)日：2007-07-26
申请号：US10589043
申请日：2004-12-24
申请人： Hideki Oki , Yuri Nakayama , Kazuhiro Noda
发明人： Hideki Oki , Yuri Nakayama , Kazuhiro Noda
CPC分类号： H01M2/105 , H01M2/1061 , H01M10/425 , H01M10/44
摘要： An electrochemical device having battery characteristics and an electrode used therefor. The electrochemical device has a first pole, a second pole, and an electrolyte, said first pole containing an active material having at least one element selected from the group consisting of 1B Group, 2B Group, 6A Group, 7A Group, and 8 Group of the short-form periodic table, and said electrolyte containing an element belonging to 2A Group and/or 3B Group of the periodic table. Interactions between the electrolyte and the active material cause the occlusion and release of said ions.
摘要翻译： 具有电池特性的电化学装置和用于其的电极。 所述电化学装置具有第一极，第二极和电解质，所述第一极含有活性物质，所述活性物质具有选自1B族，2B族，6A族，7A族和8族的至少一种元素 短周期表，所述电解质含有属于周期表的2A族和/或3B族的元素。 电解质与活性物质之间的相互作用导致所述离子的闭塞和释放。
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公开(公告)号：US20110171536A1
公开(公告)日：2011-07-14
申请号：US12085723
申请日：2006-11-14
申请人： Hideki Oki , Yuri Nakayama , Kazuhiro Noda
发明人： Hideki Oki , Yuri Nakayama , Kazuhiro Noda
IPC分类号： H01M10/056 , H01M4/58 , H01M4/38 , H01M4/62
CPC分类号： H01M10/054 , H01M4/38 , H01M4/381 , H01M4/466 , H01M4/582 , H01M4/622 , H01M4/623 , H01M10/0568 , H01M10/0569 , H01M2004/028
摘要： A cathode (1) is formed by compression bonding a mixture to a cathode current collecting net (5). The mixture includes a cathode active material and an electroconductive material such as graphite powder. The cathode active material is a halide of at least one metal element selected from the group consisting of Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn. An anode (2) is composed typically of a metallic magnesium plate. A separator (3) composed typically of polyethylene glycol is arranged between the cathode (1) and the anode (2) to avoid direct contact between them. A battery chamber (8) is filled with an electrolytic solution (4) and is hermetically sealed with a gasket (9). The electrolytic solution (4) may be a solution of a suitable metal ion-containing salt in an aprotic organic solvent, such as a solution of Mg(ACl2EtBu)2 in tetrahydrofuran (THF). This configuration can provide an electrochemical device that can satisfactorily bring out excellent properties, as an anode active material, such as a large energy capacity, possessed by a polyvalent metal such as metallic magnesium.
摘要翻译： 阴极（1）通过将混合物压接到阴极集电网（5）而形成。 混合物包括阴极活性材料和诸如石墨粉末的导电材料。 阴极活性物质是选自Sc，Ti，V，Cr，Mn，Fe，Co，Ni，Cu和Zn中的至少一种金属元素的卤化物。 阳极（2）通常由金属镁板构成。 通常由聚乙二醇组成的分离器（3）布置在阴极（1）和阳极（2）之间，以避免它们之间的直接接触。 电池室（8）填充有电解液（4），并用垫圈（9）气密密封。 电解液（4）可以是合适的含金属离子的盐在非质子有机溶剂如Mg（AClEtBu）2的四氢呋喃（THF）溶液中的溶液。 这种结构可以提供能够令人满意地产生优异性能的电化学装置，作为金属镁等多价金属所具有的能量容量大的负极活性物质。
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3.发明申请公开(公告)号：US20100136438A1
公开(公告)日：2010-06-03
申请号：US12452503
申请日：2008-06-05
申请人： Yuri Nakayama , Kenta Yamamoto , Yoshirio Kudo , Hideki Oki
发明人： Yuri Nakayama , Kenta Yamamoto , Yoshirio Kudo , Hideki Oki
CPC分类号： H01M10/054 , H01M4/466 , H01M10/0568 , H01M10/0569 , H01M2300/0025
摘要： A magnesium battery (10) is constituted of a negative electrode (1), a positive electrode (2) and an electrolyte (3). The negative electrode (1) is formed of metallic magnesium and can also be formed of an alloy. The positive electrode (2) is composed of a positive electrode active material, for example, a metal oxide, graphite fluoride ((CF)n) or the like, etc. The electrolytic solution (3) is, for example, a magnesium ion-containing nonaqueous electrolytic solution prepared by dissolving magnesium(II) chloride (MgCl2) and dimethylaluminum chloride ((CH3)2AlCl) in tetrahydrofuran (THF). In the case of dissolving and depositing magnesium by using this electrolytic solution, the following reaction proceeds in the normal direction or reverse direction. According to this, there are provided a magnesium ion-containing nonaqueous electrolytic solution having a high oxidation potential and capable of sufficiently bringing out excellent characteristics of metallic magnesium as a negative electrode active material and a method for manufacturing the same, and an electrochemical device with high performances using this electrolytic solution.
摘要翻译： 镁电池（10）由负极（1），正极（2）和电解质（3）构成。 负极（1）由金属镁形成，也可以由合金形成。 正极（2）由正极活性物质，例如金属氧化物，氟化石墨（（CF）n）等构成。电解液（3）例如为镁离子 （II）氯化物（MgCl 2）和二甲基氯化铝（（CH 3）2 AlCl 3）在四氢呋喃（THF）中制备的非水电解液。 在通过使用该电解液溶解并沉积镁的情况下，在正常方向或反向进行下列反应。 据此，提供了具有高氧化电位并能够充分发挥作为负极活性物质的金属镁的优异特性的含镁离子的非水电解液及其制造方法，以及具有 使用这种电解液的高性能。
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4.发明授权公开(公告)号：US08993178B2
公开(公告)日：2015-03-31
申请号：US12452503
申请日：2008-06-05
申请人： Yuri Nakayama , Kenta Yamamoto , Yoshihiro Kudo , Hideki Oki
发明人： Yuri Nakayama , Kenta Yamamoto , Yoshihiro Kudo , Hideki Oki
IPC分类号： H01M6/16 , H01M2/16 , H01M6/04 , H01M6/00 , H01M10/00 , H01M10/054 , H01M10/0568 , H01M10/0569 , H01M4/46
CPC分类号： H01M10/054 , H01M4/466 , H01M10/0568 , H01M10/0569 , H01M2300/0025
摘要： A magnesium battery (10) is constituted of a negative electrode (1), a positive electrode (2) and an electrolyte (3). The negative electrode (1) is formed of metallic magnesium and can also be formed of an alloy. The positive electrode (2) is composed of a positive electrode active material, for example, a metal oxide, graphite fluoride ((CF)n) or the like, etc. The electrolytic solution (3) is, for example, a magnesium ion-containing nonaqueous electrolytic solution prepared by dissolving magnesium(II) chloride (MgCl2) and dimethylaluminum chloride ((CH3)2AlCl) in tetrahydrofuran (THF). In the case of dissolving and depositing magnesium by using this electrolytic solution, the following reaction proceeds in the normal direction or reverse direction. According to this, there are provided a magnesium ion-containing nonaqueous electrolytic solution having a high oxidation potential and capable of sufficiently bringing out excellent characteristics of metallic magnesium as a negative electrode active material and a method for manufacturing the same, and an electrochemical device with high performances using this electrolytic solution.
摘要翻译： 镁电池（10）由负极（1），正极（2）和电解质（3）构成。 负极（1）由金属镁形成，也可以由合金形成。 正极（2）由正极活性物质，例如金属氧化物，氟化石墨（（CF）n）等构成。电解液（3）例如为镁离子 （II）氯化物（MgCl 2）和二甲基氯化铝（（CH 3）2 AlCl 3）在四氢呋喃（THF）中制备的非水电解液。 在通过使用该电解液溶解并沉积镁的情况下，在正常方向或反向进行下列反应。 据此，提供了具有高氧化电位并能够充分发挥作为负极活性物质的金属镁的优异特性的含镁离子的非水电解液及其制造方法，以及具有 使用这种电解液的高性能。
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公开(公告)号：US20060003229A1
公开(公告)日：2006-01-05
申请号：US10532947
申请日：2003-10-28
CPC分类号： H01M4/485 , B82Y30/00 , H01M4/131 , H01M4/46 , H01M4/5815 , H01M10/054 , H01M10/0566 , H01M10/54 , Y02W30/84
摘要： An electrochemical cell is provided, including an anode, a cathode, and an electrolyte therebetween. The anode contains magnesium in a reduced state, and the cathode includes a rutile structure. The rutile structure is capable of intercalating magnesium ions received from the anode to produce a low voltage. The electrochemical cell is rechargeable. Additionally, the electrochemical cell is cheaper, more environmentally friendly and has a higher volume density than related art electrochemical cells. A method of manufacture is also provided.
摘要翻译： 提供了一种电化学电池，包括阳极，阴极和它们之间的电解质。 阳极含有还原态的镁，阴极包括金红石结构。 金红石结构能够插入从阳极接收的镁离子以产生低电压。 电化学电池是可充电的。 此外，电化学电池比现有技术的电化学电池更便宜，更环保且具有更高的体积密度。 还提供了一种制造方法。
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公开(公告)号：US09819052B2
公开(公告)日：2017-11-14
申请号：US13264641
申请日：2010-04-09
申请人： Yui Senda , Kenta Yamamoto , Yuri Nakayama , Reina Ito
发明人： Yui Senda , Kenta Yamamoto , Yuri Nakayama , Reina Ito
IPC分类号： H01M10/054 , H01B1/12 , H01M10/0568 , H01M10/0569 , H01M4/38 , H01M4/46
CPC分类号： H01M10/054 , H01B1/122 , H01M4/38 , H01M4/463 , H01M10/0568 , H01M10/0569 , H01M2300/0037
摘要： A secondary battery capable of safely improving a battery performance is provided. An electrolyte with which a separator 13 is impregnated contains an alkyl sulfone and a low-polar solvent (a solvent having a relative permittivity of 20 or less) together with an aluminum salt. The alkyl sulfone facilitates the redox reaction of aluminum, and further reduces the reactivity of the electrolyte. Additionally, the low-polar solvent suppresses the block of the redox reaction of aluminum. In charge and discharge, it becomes easy to electrochemically efficiently precipitate and dissolve aluminum, and further to inhibit the corrosion of a metallic exterior package member or the like.
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7.发明授权公开(公告)号：US09413005B2
公开(公告)日：2016-08-09
申请号：US12733363
申请日：2008-09-02
申请人： Kenta Yamamoto , Yuri Nakayama
发明人： Kenta Yamamoto , Yuri Nakayama
CPC分类号： H01M4/502 , C01G45/02 , C01P2002/72 , H01M4/38 , H01M4/505 , H01M4/623 , H01M4/625 , H01M10/054 , H01M2004/028 , Y02E60/122 , Y02P70/54
摘要： The invention provides a high-capacity positive electrode active material capable of sufficiently exploiting the excellent characteristics of magnesium metal or the like as a negative electrode active material, such as high energy capacity; a method for producing the same; and an electrochemical device using the positive electrode active material. A positive electrode 11 includes a positive electrode can 1, a positive pole pellet 2 having a positive electrode active material and the like, and a metal mesh support 3. A negative electrode 12 includes a negative electrode cap 4 and a negative electrode active material 5 such as magnesium metal. The positive electrode pellet 2 and the negative electrode active material 5 are disposed so as to sandwich a separator 6, and an electrolyte 7 is injected into the separator 6. The positive electrode active material, which provides the feature of the invention, is synthesized by a step of reacting a permanganate, such as potassium permanganate, with hydrochloric acid preferably having a concentration of 3 to 4 mol/l to produce a precipitate, and a step of filtering the precipitate, thoroughly washing the filtered precipitate with water, and then subjecting the washed precipitate to heat treatment preferably at a temperature of 300 to 400° C. for not less than 2 hours, thereby giving a manganese oxide.
摘要翻译： 本发明提供能够充分利用镁金属等优异特性的高容量正极活性物质作为负极活性物质，如高能量容量; 其制造方法; 以及使用正极活性物质的电化学装置。 正极11包括正极罐1，具有正极活性物质等的正极团粒2和金属网状支撑体3.负极12包括负极帽4和负极活性物质5 如镁金属。 将正极片2和负极活性物质5配置成夹着隔膜6，将电解质7注入隔膜6.提供本发明特征的正极活性物质由 将高锰酸盐如高锰酸钾与优选浓度为3至4mol / l的盐酸反应以产生沉淀物的步骤，以及过滤沉淀物的步骤，用水充分洗涤过滤的沉淀物，然后 洗涤的沉淀物优选在300-400℃的温度下加热处理不少于2小时，由此得到氧化锰。
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8.发明申请公开(公告)号：US20100196762A1
公开(公告)日：2010-08-05
申请号：US12733363
申请日：2008-09-02
申请人： Kenta Yamamoto , Yuri Nakayama
发明人： Kenta Yamamoto , Yuri Nakayama
CPC分类号： H01M4/502 , C01G45/02 , C01P2002/72 , H01M4/38 , H01M4/505 , H01M4/623 , H01M4/625 , H01M10/054 , H01M2004/028 , Y02E60/122 , Y02P70/54
摘要： The invention provides a high-capacity positive electrode active material capable of sufficiently exploiting the excellent characteristics of magnesium metal or the like as a negative electrode active material, such as high energy capacity; a method for producing the same; and an electrochemical device using the positive electrode active material. A positive electrode 11 includes a positive electrode can 1, a positive pole pellet 2 having a positive electrode active material and the like, and a metal mesh support 3. A negative electrode 12 includes a negative electrode cap 4 and a negative electrode active material 5 such as magnesium metal. The positive electrode pellet 2 and the negative electrode active material 5 are disposed so as to sandwich a separator 6, and an electrolyte 7 is injected into the separator 6. The positive electrode active material, which provides the feature of the invention, is synthesized by a step of reacting a permanganate, such as potassium permanganate, with hydrochloric acid preferably having a concentration of 3 to 4 mol/l to produce a precipitate, and a step of filtering the precipitate, thoroughly washing the filtered precipitate with water, and then subjecting the washed precipitate to heat treatment preferably at a temperature of 300 to 400° C. for not less than 2 hours, thereby giving a manganese oxide.
摘要翻译： 本发明提供能够充分利用镁金属等优异特性的高容量正极活性物质作为负极活性物质，如高能量容量; 其制造方法; 以及使用正极活性物质的电化学装置。 正极11包括正极罐1，具有正极活性物质等的正极团粒2和金属网状支撑体3.负极12包括负极帽4和负极活性物质5 如镁金属。 将正极片2和负极活性物质5配置成夹着隔膜6，将电解质7注入隔膜6.提供本发明特征的正极活性物质由 将高锰酸盐如高锰酸钾与优选浓度为3至4mol / l的盐酸反应以产生沉淀物的步骤，以及过滤沉淀物的步骤，用水充分洗涤过滤的沉淀物，然后 洗涤的沉淀物优选在300-400℃的温度下加热处理不少于2小时，由此得到氧化锰。
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9.发明授权公开(公告)号：US08691434B2
公开(公告)日：2014-04-08
申请号：US12231557
申请日：2008-09-04
申请人： Kenta Yamamoto , Yuri Nakayama
发明人： Kenta Yamamoto , Yuri Nakayama
IPC分类号： H01M10/05 , H01M10/056 , H01M10/054
CPC分类号： H01M10/056 , H01M10/054 , H01M10/0568 , H01M10/0569
摘要： A magnesium ion containing non-aqueous electrolyte in which magnesium ions and aluminum ions are dissolved in an organic etheric solvent, and which is formed by: adding metal magnesium, a halogenated hydrocarbon RX, an aluminum halide AlY3, and a quaternary ammonium salt R1R2R3R4N+Z− to an organic etheric solvent; and applying a heating treatment while stirring them (in the general formula RX representing the halogenated hydrocarbon, R is an alkyl group or an aryl group, X is chlorine, bromine, or iodine, in the general formula AlY3 representing the aluminum halide, Y is chlorine, bromine, or iodine, in the general formula R1R2R3R4N+Z− representing the quaternary ammonium salt, R1, R2, R3, and R4 represent each an alkyl group or an aryl group, and Z− represents chloride ion, bromide ion, iodide ion, acetate ion, perchlorate ion, tetrafluoro borate ion, hexafluoro phosphate ion, hexafluoro arsenate ion, perfluoroalkyl sulfonate ion, or perfluoroalkyl sulfonylimide ion.
摘要翻译： 通过添加金属镁，卤代烃RX，卤化铝AlY3和季铵盐R1R2R3R4N +，形成含有镁离子和铝离子的镁离子，其中镁离子和铝离子溶解在有机醚溶剂中， Z-至有机醚溶剂; 在表示卤化物的通式RX中，R表示烷基或芳基，X表示氯，溴或碘，表示卤化铝的通式为AlY 3中，Y为 氯，溴或碘，通式为R1R2R3R4N + Z-代表季铵盐，R1，R2，R3和R4分别表示烷基或芳基，Z-表示氯离子，溴离子，碘化物 离子，乙酸根离子，高氯酸根离子，四氟硼酸根离子，六氟磷酸根离子，六氟砷酸根离子，全氟烷基磺酸根离子或全氟烷基磺酰亚胺离子。
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公开(公告)号：US20130202972A1
公开(公告)日：2013-08-08
申请号：US13879584
申请日：2011-09-27
申请人： Yuri Nakayama , Kazumasa Takeshi , Yui Senda , Hiroyuki Morioka
发明人： Yuri Nakayama , Kazumasa Takeshi , Yui Senda , Hiroyuki Morioka
IPC分类号： H01M10/0567
CPC分类号： H01M10/0567 , H01B1/122 , H01B1/22 , H01M10/054 , H01M10/0568 , H01M10/0569 , H01M2300/0025 , H01M2300/0028 , H01M2300/0037
摘要： A secondary battery capable of decreasing progression temperature of a precipitation-dissolution reaction of aluminum is provided. A cathode 11 and an anode 12 are separated from each other by a separator 13. An electrolyte with which the separator 13 is impregnated contains an alkyl sulfone (R1—S(═O)2—R2: each of R1 and R2 represents an alkyl group) and a solvent (having a specific dielectric constant of 20 or less) together with an aluminum salt. A content of the solvent is equal to or larger than 30 mol % and is less than 88 mol %, and a mol ratio (a content of the aluminum salt/a content of the alkyl sulfone) is equal to or larger than 4/5 and is less than 7/3.
摘要翻译： 提供能够降低铝的沉淀 - 溶解反应的进行温度的二次电池。 阴极11和阳极12通过隔板13彼此分离。浸渍隔板13的电解液含有烷基砜（R1-S（= O）2-R2：R 1和R 2各自表示烷基 基团）和溶剂（比介电常数为20以下）与铝盐一起使用。 溶剂的含量等于或大于30摩尔％且小于88摩尔％，摩尔比（铝盐的含量/烷基砜的含量）等于或大于4/5 小于7/3。
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