公开(公告)号：US5594081A

公开(公告)日：1997-01-14

申请号：US504825

申请日：1995-07-20

申请人： Hideshi Uchino ,  June Endo ,  Toshihiko Sugano ,  Tomohiko Takahama ,  Taku Kato ,  Eiji Taniyama ,  Naoshi Iwama

发明人： Hideshi Uchino ,  June Endo ,  Toshihiko Sugano ,  Tomohiko Takahama ,  Taku Kato ,  Eiji Taniyama ,  Naoshi Iwama

IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F4/642

CPC分类号： C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/943

摘要： The present invention provides a catalyst for polymerizing an .alpha.-olefin which is capable of producing an .alpha.-olefin polymer having a high molecular weight in a high yield under the polymerization conditions including at high temperature, and a process for preparing an .alpha.-olefin polymer, which catalyst comprises a Component (A) which comprises a coordination compound having a skeleton of a metallocene compound comprising an indenyl ring or a hydroindenyl ring which is an indenyl having a six-membered portion hydrogenated as a ligand and having Ti, Zr or Hf as a metal component in combination with a Component (B) which is, for example, an alumoxane. The coordination compound is crosslinked at the six-membered rings characterized by the fact that two of the indenyl or hydroindenyl groups are crosslinked at the six-membered ring of the indenyl or hydroindenyl group.

摘要翻译： 本发明提供了一种用于聚合α-烯烃的催化剂，其能够在包括高温的聚合条件下以高产率生产具有高分子量的α-烯烃聚合物，以及制备α-烯烃聚合物的方法 ，该催化剂包含组分（A），其包含具有包含茚基环的茂金属化合物的骨架的配位化合物或作为配体氢化的六元部分的具有Ti，Zr或Hf的茚基的茚环 作为与例如铝氧烷的组分（B）组合的金属组分。 配位化合物在六元环交联，其特征在于茚基或茚基中的两个在茚基或氢茚基的六元环上交联。

公开(公告)号：US6084043A

公开(公告)日：2000-07-04

申请号：US975277

申请日：1997-11-20

申请人： Toshihiko Sugano ,  Hideshi Uchino ,  Kaori Imaeda ,  Eiji Taniyama ,  Naoshi Iwama

发明人： Toshihiko Sugano ,  Hideshi Uchino ,  Kaori Imaeda ,  Eiji Taniyama ,  Naoshi Iwama

IPC分类号： C08F4/642 ,  C08F4/44 ,  C08F4/60 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/646 ,  C08F4/6592 ,  C08F10/00

CPC分类号： C08F10/00 ,  C08F4/61908 ,  C08F4/61912 ,  C08F4/61927 ,  Y10S526/943

摘要： A catalyst component for the polymerization of alpha-olefins, represented by the following formula [I]: ##STR1## wherein R.sup.1 -R.sup.3 =H, a halogen, a C.sub.1-10 hydrocarbon radical, a Si-containing C.sub.1-18 hydrocarbon radical, or a halogen-containing C.sub.1-10, hydrocarbon radical (provided that R.sup.1 and R.sup.2 cannot be hydrogen at the same time); n=2 to 7; Q=a C.sub.1-20 hydrocarbon radical, a silylene or oligosilylene group having or not having a C.sub.1-20 hydrocarbon radical, a germylene group having or not having a C.sub.1-20 hydrocarbon radical; X and Y=H, a halogen, a C.sub.1-20 hydrocarbon radical, or an O- or N-containing C.sub.1-20 hydrocarbon radical; and M=a transition metal selected from the groups IVB-VIB; a catalyst for the polymerization of alpha-olefins, comprising the catalyst component; and a process for producing alpha-olefin polymers, where use is made of the catalyst. Use of the catalyst will produce alpha-olefin polymers having a high melting point and a high molecular weight in a high yield.

摘要翻译： 由下式[I]表示的用于α-烯烃聚合的催化剂组分：其中R1-R3 = H，卤素，C1-10烃基，含Si的C1-18烃基或卤素 含有C 1-10的烃基（条件是R1和R2不能同时为氢）; n = 2〜7; Q = C 1-20烃基，具有或不具有C 1-20烃基的亚甲硅烷基或低聚亚芳基，具有或不具有C 1-20烃基的亚乙烯基; X和Y = H，卤素，C 1-20烃基或含O-或N的C 1-20烃基; M =选自IVB-VIB族的过渡金属; 包含催化剂组分的α-烯烃聚合催化剂; 和使用催化剂的α-烯烃聚合物的制备方法。 催化剂的使用将以高产率生产具有高熔点和高分子量的α-烯烃聚合物。

公开(公告)号：US08461365B2

公开(公告)日：2013-06-11

申请号：US13131301

申请日：2009-12-14

申请人： Masato Nakano ,  Hideshi Uchino ,  Naoshi Iwama ,  Masami Kashimoto ,  Tomohiro Kato

发明人： Masato Nakano ,  Hideshi Uchino ,  Naoshi Iwama ,  Masami Kashimoto ,  Tomohiro Kato

IPC分类号： C08F299/00 ,  C08F4/76 ,  C07F7/08 ,  B01J31/14 ,  B01J21/16

CPC分类号： C07F17/00 ,  C08F4/65912 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65927 ,  C08F4/65916 ,  C08F2/001 ,  C08F2500/01 ,  C08F210/16 ,  C08F210/08

摘要： A metallocene complex by which high uptake efficiency of ethylene and/or α-olefin can be obtained compared with the conventional metallocene catalyst, and robber component having high molecular weight can be polymerized, and polymerization method of olefin. Metallocene complex (metallocene complex having furyl or thienyl group in which substituent exists at 5-position of indenyl ring, and substituent may exist at 2-position of indenyl ring, and the like) represented by the general formula [II], the catalyst for olefin polymerization characterized by comprising said metallocene complex, and polymerization method of olefin characterized that polymerization or copolymerization of olefin is carried out using said polymerization catalyst for olefin, and the like.

摘要翻译： 与常规茂金属催化剂相比，可以获得乙烯和/或α-烯烃的高吸收效率的茂金属络合物，并且可以聚合具有高分子量的强力组分，以及烯烃的聚合方法。 茂金属络合物（具有呋喃基或噻吩基的茂金属络合物，其中在茚基环的5-位上存在取代基，并且取代基可以存在于由通式[II]表示的茚基环的2-位，等等），催化剂 烯烃聚合的特征在于包含所述茂金属络合物和烯烃的聚合方法，其特征在于使用所述烯烃聚合催化剂等进行烯烃的聚合或共聚。

公开(公告)号：US20110230622A1

公开(公告)日：2011-09-22

申请号：US13131301

申请日：2009-12-14

申请人： Masato Nakano ,  Hideshi Uchino ,  Naoshi Iwama ,  Masami Kashimoto ,  Tomohiro Kato

发明人： Masato Nakano ,  Hideshi Uchino ,  Naoshi Iwama ,  Masami Kashimoto ,  Tomohiro Kato

IPC分类号： C08F299/00 ,  C08F4/76 ,  C07F7/08 ,  B01J31/14 ,  B01J21/16

CPC分类号： C07F17/00 ,  C08F4/65912 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65927 ,  C08F4/65916 ,  C08F2/001 ,  C08F2500/01 ,  C08F210/16 ,  C08F210/08

摘要： A metallocene complex by which high uptake efficiency of ethylene and/or α-olefin can be obtained compared with the conventional metallocene catalyst, and rubber component having high molecular weight can be polymerized, and polymerization method of olefin.Metallocene complex (metallocene complex having furyl or thienyl group in which substituent exists at 5-position of indenyl ring, and substituent may exist at 2-position of indenyl ring, and the like) represented by the general formula [I], the catalyst for olefin polymerization characterized by comprising said metallocene complex, and polymerization method of olefin characterized in that polymerization or copolymerization of olefin is carried out using said polymerization catalyst for olefin, and the like.

摘要翻译： 与常规茂金属催化剂相比，可以获得乙烯和/或α-烯烃的高吸收效率的茂金属络合物，可以聚合具有高分子量的橡胶组分，以及烯烃的聚合方法。 茂金属络合物（具有呋喃基或噻吩基的茂金属络合物，其中在茚基环的5-位存在取代基，并且取代基可以存在于通式[I]表示的茚基环的2-位，等等），催化剂 其特征在于包含所述茂金属络合物和烯烃聚合方法，其特征在于使用所述烯烃聚合催化剂等进行烯烃的聚合或共聚。

公开(公告)号：US5252677A

公开(公告)日：1993-10-12

申请号：US553

申请日：1993-01-04

申请人： Masayuki Tomita ,  Hiroshi Nakano ,  Hideshi Uchino ,  Toshihiko Sugano ,  Mitsutoshi Aritomi

发明人： Masayuki Tomita ,  Hiroshi Nakano ,  Hideshi Uchino ,  Toshihiko Sugano ,  Mitsutoshi Aritomi

IPC分类号： C08F8/00 ,  C08F8/08 ,  C08F8/34 ,  C08F10/06 ,  C08F110/06

CPC分类号： C08F8/00 ,  C08F2800/10 ,  C08F2810/40

摘要： A functionalized polymer having excellent adhesion, printability, and compatibility in polymer blends or the like which are obtained by introducing an epoxy group, a hydroxyl group or a sulfonic group into a syndiotactic .alpha.-olefin polymer having an olefinic unsaturated bond at its terminus is disclosed. The terminal unsaturated syndiotactic .alpha.-olefin polymer is obtained by polymerizing an .alpha.-olefin with a catalyst comprising the combination of a metallocene compound and an alumoxane, and the functional groups are obtained by the oxidation, sulfonation or the like of the terminal unsaturated group, by the addition of a compound containing the corresponding functional group to the unsaturated bond, or by the conversion of a precursor polymer containing a precursor of the functional group into a polymer containing the functional group desired.

摘要翻译： 公开了通过在其末端将具有烯属不饱和键的间同立构的α-烯烃聚合物引入环氧基，羟基或磺酸基而获得的聚合物共混物等中具有优异的粘合性，可印刷性和相容性的官能化聚合物， 。 末端不饱和间规α-烯烃聚合物是通过使含有茂金属化合物和铝氧烷的组合的催化剂聚合α-烯烃得到的，该官能团是通过末端不饱和基团的氧化，磺化等获得的， 通过向不饱和键中加入含有相应的官能团的化合物，或通过将含有官能团前体的前体聚合物转化成所需官能团的聚合物。

公开(公告)号：US5331054A

公开(公告)日：1994-07-19

申请号：US962837

申请日：1992-10-19

申请人： Takashi Fujita ,  Toshihiko Sugano ,  Hajime Mizuno ,  Hideshi Uchino

发明人： Takashi Fujita ,  Toshihiko Sugano ,  Hajime Mizuno ,  Hideshi Uchino

IPC分类号： C08J5/18 ,  C08L23/10 ,  C08L23/14 ,  C08L23/18

CPC分类号： C08J5/18 ,  C08L23/10 ,  C08L23/142 ,  C08J2323/10 ,  C08L2205/02 ,  Y10S526/943 ,  Y10T428/31913

摘要： A propylene copolymer composition enabling the production of a film having excellent low-temperature heat sealing ability and blocking resistance, is obtained by blending 1 to 70 wt % of a component A and 30 to 99 wt % of a component B. The component A comprises either a propylene homopolymer or a copolymer of propylene with not more than 10 mol % of ethylene or an a-olefin having a carbon number of 4 to 20, and has a molecular weight distribution (Mw/Mn) of not more than 3, a mean elution temperature of 40.degree. to 100.degree. C., and an elution dispersion degree (.sigma. value) of not more than 10. The component B comprises a copolymer of propylene with ethylene and/or an .alpha.-olefin having a carbon number of 4 to 20, and has a molecular weight distribution (Mw/Mn) of 3.5 to 10.

摘要翻译： 通过混合1〜70重量％的组分A和30〜99重量％的组分B，可以得到能够制备具有优异的低温热封性和耐粘连性的膜的丙烯共聚物组合物。组分A包含 丙烯均聚物或丙烯与不超过10摩尔％的乙烯或碳数为4-20的α-烯烃的共聚物，分子量分布（Mw / Mn）不大于3，a 平均洗脱温度为40℃至100℃，洗脱分散度（σ值）不大于10.组分B包括丙烯与乙烯和/或碳数为4的α-烯烃的共聚物 至20，分子量分布（Mw / Mn）为3.5〜10。

公开(公告)号：US5225501A

公开(公告)日：1993-07-06

申请号：US877106

申请日：1992-05-01

申请人： Takashi Fujita ,  Toshihiko Sugano ,  Hideshi Uchino

发明人： Takashi Fujita ,  Toshihiko Sugano ,  Hideshi Uchino

IPC分类号： C08F4/642 ,  C08F4/60 ,  C08F4/659 ,  C08F4/6592 ,  C08F210/00 ,  C08F210/06

CPC分类号： C08F210/06 ,  C08F4/65912 ,  C08F4/65922 ,  Y10S526/943

摘要： A process for producing a propylene random copolymer comprising the repeating units (I)-(III) in quantities of 70-99.9 molar % of (I), 0-15 molar % and 0.1-30 molar %, respectively, which comprises contacting monomers which afford the following repeating units: ##STR1## m denotes 0 or an integer of 2-10, R.sub..alpha., R.sub..beta. and R.sub..gamma. independently represent a hydrogen atom or a hydrocarbyl group having 1-5 carbon atoms, at least one of R.sub..beta. and R.sub..gamma. being the hydrocarbyl group, and n denotes an integer of 1-5, with a polymerization catalyst to copolymerize, the polymerization catalyst comprising:component (A) which is a transition metal compound represented by the formula:Q.sub.a (C.sub.5 H.sub.5-a-b R.sup.1.sub.b)(C.sub.5 H.sub.5-a-c R.sup.2.sub.c)MeXYwherein R.sup.1 and R.sup.2, respectively, represent a hydrocarbyl group having 1-20 carbon atoms, a halogen atom, an alkoxy group, a silicon-containing hydrocarbyl group, a phosphorus-containing hydrocarbyl group, a nitrogen-containing hydrocarbyl group or a boron-containing hydrocarbyl group, Q represents a bonding group crosslinking the two conjugated five-membered ring ligands, Me represents a transition metal of groups IVB-VIB in the Periodic Table, X and Y, represent hydrogen, a halogen atom, a hydrocarbyl group, an alkoxy group, an amino group, phosphorus-containing hydrocarbyl group or a silicon-containing hydrocarbyl group, respectively, a denotes 0 or 1, b denotes an integer in the range of 0.ltoreq.b.ltoreq.4 and c denotes an integer in the range of 0.ltoreq.c.ltoreq.4; and component (B) which is an alumoxane.

公开(公告)号：US6143911A

公开(公告)日：2000-11-07

申请号：US678686

申请日：1996-07-11

申请人： Takashi Fujita ,  Toshihiko Sugano ,  Hideshi Uchino

发明人： Takashi Fujita ,  Toshihiko Sugano ,  Hideshi Uchino

IPC分类号： C07F17/00 ,  C08F4/60 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/76 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  C07F7/00

CPC分类号： C08F10/00 ,  C07F17/00 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/943

摘要： A catalyst useful for the polymerization of olefins, comprising the following components (A) and (B):Component (A): A transition metallic compound having the following formula [I]: ##STR1## wherein M: a transition metal selected from Ti, Zr and Hf; R.sup.1 : a monovalent C.sub.1-6 hydrocarbyl group, or a monovalent C.sub.1-6 hydrocarbyl group containing Si;R.sup.2 : a divalent C.sub.4-20 hydrocarbyl group, or a divalent C.sub.4-20 hydrocarbyl group containing Si;R.sup.3 : a divalent C.sub.1-30 hydrocarbyl group, or a divalent C.sub.1-30 hydrocarbyl group containing Si or Ge; andX and Y: H, halogen, a monovalent C.sub.1-20 hydrocarbyl group, or a monovalent C.sub.1-20 hydrocarbyl group containing N, O or Si.Component (B): Alumoxane having the following formula [II] or [III]: ##STR2## wherein m: 4 to 30; and R.sup.4 : a monovalent hydrocarbyl group. A highly stereoregular polyolefin having a high molecular weight can be obtained by the above catalyst.

摘要翻译： 用于烯烃聚合的催化剂，其包含以下组分（A）和（B）：组分（A）：具有下式[I]的过渡金属化合物：其中M：选自Ti，Zr和 Hf; R1：一价C 1-6烃基或含有Si的一价C 1-6烃基; R2：二价C 4-20烃基，或含有Si的二价C 4-20烃基; R3：二价C1-30烃基，或含有Si或Ge的二价C1-30烃基; 和X和Y：H，卤素，一价C 1-20烃基或含有N，O或Si的一价C 1-20烃基。 组分（B）：具有下式[II]或[III]的Alumoxane：其中m：4-30; 和R4：一价烃基。 通过上述催化剂可以获得具有高分子量的高立体规则聚烯烃。

公开(公告)号：US5444125A

公开(公告)日：1995-08-22

申请号：US876037

申请日：1992-04-30

申请人： Masayuki Tomita ,  Hideshi Uchino ,  Toshihiko Sugano ,  Takashi Fujita ,  Mitsutoshi Aritomi

发明人： Masayuki Tomita ,  Hideshi Uchino ,  Toshihiko Sugano ,  Takashi Fujita ,  Mitsutoshi Aritomi

IPC分类号： C08F8/30 ,  C08F8/32 ,  C08F10/00

CPC分类号： C08F8/32

摘要： An aminated polymer having excellent adhesion, printability, and compatibility in polymer blends or the like which are obtained by introducing an amino group, into an isotactic .alpha.-olefin polymer having an olefinic unsaturated bond at its terminus is disclosed. The terminal unsaturated isotactic or syndiotactic .alpha.-olefin polymer is obtained by polymerizing an .alpha.-olefin with a catalyst comprising the combination of a metallocene compound and an alumoxane, and the amino group is obtained by the amination of the terminal unsaturated group, by the addition of a compound containing the corresponding functional group to the unsaturated bond, or by the conversion of a precursor polymer containing a precursor of the functional group into a polymer containing the functional group desired.

摘要翻译： 公开了一种在通过将氨基引入到其末端具有烯属不饱和键的全同立构α-烯烃聚合物中而获得的聚合物共混物等中具有优异的粘附性，可印刷性和相容性的胺化聚合物。 末端不饱和全同立构或间同立构的α-烯烃聚合物是通过用包含茂金属化合物和铝氧烷的组合的催化剂聚合α-烯烃而获得的，该氨基通过末端不饱和基团的胺化获得， 含有与不饱和键相应的官能团的化合物，或通过将含有官能团前体的前体聚合物转化成含有所需官能团的聚合物。

公开(公告)号：US06677411B2

公开(公告)日：2004-01-13

申请号：US10111408

申请日：2002-05-06

申请人： Hideshi Uchino ,  Hiroshi Nakano ,  Shuuichi Toriu ,  Takao Tayano ,  Hirotugu Niwa ,  Yoshiyuki Ishihama ,  Toshihiko Sugano

发明人： Hideshi Uchino ,  Hiroshi Nakano ,  Shuuichi Toriu ,  Takao Tayano ,  Hirotugu Niwa ,  Yoshiyuki Ishihama ,  Toshihiko Sugano

IPC分类号： C08F402

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65922 ,  C08F210/06 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/02 ,  C08F4/65916 ,  C08F4/025 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F210/08 ,  C08F210/14

摘要： A catalyst component for olefin polymerization, which comprises an ion-exchange layered silicate having the following features 1 and 2: feature 1: in a pore size distribution curve calculated from desorption isotherm by nitrogen adsorption-desorption method, a pore diameter Dm showing a maximum peak intensity DVM is from 60 to 200 Å; and feature 2: in a pore size distribution curve calculated from desorption isotherm by nitrogen adsorption-desorption method, a pore diameter Dm1/2 (Å) on the smaller pore size side corresponding to a ½ peak intensity of the maximum peak intensity DVM has a relation of Dm1/2/Dm of at least 0.65 and less than 1, provided that the largest value is employed when there are a plurality of Dm1/2 values.

摘要翻译： 用于烯烃聚合的催化剂组分，其包含具有以下特征1和2的离子交换层状硅酸盐：特征1：通过氮吸附 - 解吸法由解吸等温线计算的孔径分布曲线中，孔径Dm表示最大值 峰值强度DVM为60〜200; 特征2：在通过氮吸附 - 解吸法从解吸等温线计算的孔径分布曲线中，在与最大峰值强度DVM的1/2峰强度对应的较小孔径侧的孔径Dm1 / 2（）具有关系 的Dm1 / 2 / Dm为0.65以上且小于1，条件是当存在多个Dm1 / 2值时采用最大值。