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公开(公告)号：US5252677A
公开(公告)日：1993-10-12
申请号：US553
申请日：1993-01-04
IPC分类号： C08F8/00 , C08F8/08 , C08F8/34 , C08F10/06 , C08F110/06
CPC分类号： C08F8/00 , C08F2800/10 , C08F2810/40
摘要： A functionalized polymer having excellent adhesion, printability, and compatibility in polymer blends or the like which are obtained by introducing an epoxy group, a hydroxyl group or a sulfonic group into a syndiotactic .alpha.-olefin polymer having an olefinic unsaturated bond at its terminus is disclosed. The terminal unsaturated syndiotactic .alpha.-olefin polymer is obtained by polymerizing an .alpha.-olefin with a catalyst comprising the combination of a metallocene compound and an alumoxane, and the functional groups are obtained by the oxidation, sulfonation or the like of the terminal unsaturated group, by the addition of a compound containing the corresponding functional group to the unsaturated bond, or by the conversion of a precursor polymer containing a precursor of the functional group into a polymer containing the functional group desired.
摘要翻译： 公开了通过在其末端将具有烯属不饱和键的间同立构的α-烯烃聚合物引入环氧基，羟基或磺酸基而获得的聚合物共混物等中具有优异的粘合性，可印刷性和相容性的官能化聚合物， 。 末端不饱和间规α-烯烃聚合物是通过使含有茂金属化合物和铝氧烷的组合的催化剂聚合α-烯烃得到的，该官能团是通过末端不饱和基团的氧化，磺化等获得的， 通过向不饱和键中加入含有相应的官能团的化合物，或通过将含有官能团前体的前体聚合物转化成所需官能团的聚合物。
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公开(公告)号：US5444125A
公开(公告)日：1995-08-22
申请号：US876037
申请日：1992-04-30
CPC分类号： C08F8/32
摘要： An aminated polymer having excellent adhesion, printability, and compatibility in polymer blends or the like which are obtained by introducing an amino group, into an isotactic .alpha.-olefin polymer having an olefinic unsaturated bond at its terminus is disclosed. The terminal unsaturated isotactic or syndiotactic .alpha.-olefin polymer is obtained by polymerizing an .alpha.-olefin with a catalyst comprising the combination of a metallocene compound and an alumoxane, and the amino group is obtained by the amination of the terminal unsaturated group, by the addition of a compound containing the corresponding functional group to the unsaturated bond, or by the conversion of a precursor polymer containing a precursor of the functional group into a polymer containing the functional group desired.
摘要翻译： 公开了一种在通过将氨基引入到其末端具有烯属不饱和键的全同立构α-烯烃聚合物中而获得的聚合物共混物等中具有优异的粘附性，可印刷性和相容性的胺化聚合物。 末端不饱和全同立构或间同立构的α-烯烃聚合物是通过用包含茂金属化合物和铝氧烷的组合的催化剂聚合α-烯烃而获得的，该氨基通过末端不饱和基团的胺化获得， 含有与不饱和键相应的官能团的化合物，或通过将含有官能团前体的前体聚合物转化成含有所需官能团的聚合物。
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公开(公告)号：US5191030A
公开(公告)日：1993-03-02
申请号：US762112
申请日：1991-09-19
CPC分类号： C08G65/485 , C08L71/126 , C08L63/00 , C08L67/00 , C08L77/00 , Y10S525/905
摘要： A process for producing an amino group terminated polyphenylene ether represented by the following general formula (I) ##STR1## wherein Q.sup.1 s each represents a halogen atom, a primary or secondary alkyl group, a phenyl group, an aminoalkyl group, a hydrocarbon oxy group or a halohydrocarbon oxy group; Q.sup.2 s each represents a hydrogen atom, a halogen atom, a primary or secondary alkyl group, a phenyl group, a haloalkyl group, a hydrocarbon oxy group or halohydrocarbon oxy group; R represents an aliphatic hydrocarbon group having 1 to 32 carbon atoms, an aromatic hydrocarbon group or an araliphatic hydrocarbon group; and n is a number of 10 to 500, which process comprises reacting a polyphenylene ether represented by the following general formula (II) ##STR2## wherein Q.sub.1, Q.sub.2 and n are as define above, with a primary amine halide represented by the following general formula (III)X--R--NH.sub.2 (III)wherein R is as defined above, and X represents a halogen atom.
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4.发明授权Process for producing silane-modified polyphenylene ether and thermoplastic resin composition containing the same 失效生产硅烷改性聚苯乙烯醚的方法和含有其的热塑性树脂组合物
公开(公告)号：US5177156A
公开(公告)日：1993-01-05
申请号：US701910
申请日：1991-05-17
申请人： Mitsutoshi Aritomi , Haruo Ohmura , Hiroshi Nakano , Michiharu Kihira , Yusuke Arashiro , Fumiyoshi Yamada , Shinako Mori , Fumiyo Ikehata
发明人： Mitsutoshi Aritomi , Haruo Ohmura , Hiroshi Nakano , Michiharu Kihira , Yusuke Arashiro , Fumiyoshi Yamada , Shinako Mori , Fumiyo Ikehata
CPC分类号： C08G65/485 , C08L71/126 , C08L67/00 , C08L77/00
摘要： A process for producing a terminal-modified polyphenylene ether represented by formula (III): ##STR1## wherein Q.sup.1 represents a halogen atom, a primary of secondary alkyl group, a phenyl group, an aminoalkyl group, a hydrocarbon oxy group, or a halo-hydrocarbon oxy group; Q.sup.2 represents a hydrogen atom, a halogen atom, a primary or secondary alkyl group, a phenyl group, a haloalkyl group, a hydrocarbon oxy group, or a halo-hydrocarbon oxy group; n represents an integer of at least 10; X represents an oxygen atom or a nitrogen atom;R.sup.1 represents an alkylene group having from 1 to 12 carbon atoms; R.sup.2 and R.sup.3 each represents a hydrocarbon group having from 1 to 6 carbon atoms; s represents 1 when X is an oxygen atom, or 2 when X is a nitrogen atom; and t represents an integer of from from 1 to 3,which comprises reacting a polyphenylene ether represented by formula (I): ##STR2## wherein Q.sup.1, Q.sup.2, and n are as defined above, with a compound represented by formula (II): ##STR3## wherein X, R.sup.1, R.sup.2, R.sup.3, s, and t are as defined above; a process for producing an alkoxysilylated polyphenylene ether represented by formula (V): ##STR4## wherein Q.sup.1, Q.sup.2, and n are as defined above; R.sup.11 represents a bond or an alkylene group having from 1 to 12 carbon atoms; R.sup.12 and R.sup.13 each represents a hydrocarbon group having from 1 to 6 carbon atoms; and m represents an integer of from 1 to 3, which comprises reacting a polyphenylene ether represented by formula (I) shown above with a compound represented by formula (IV): ##STR5## wherein R.sup.11, R.sup.12, R.sup.13, and m are as defined above; and Y represents a halogen atom;and a thermoplastic resin composition comprising the modified polyphenylene ether of formula (III) or (IV) with a saturated polyester, a polyamide, or a modified olefin resin.
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5.发明授权Thermoplastic resin composition and process for preparing modified polyolefin type resin 失效热塑性树脂组合物和改性聚烯烃类树脂的制备方法
公开(公告)号：US5424359A
公开(公告)日：1995-06-13
申请号：US201008
申请日：1994-02-24
IPC分类号： C08F255/00 , C08L51/06 , C08L67/02
CPC分类号： C08L51/06 , C08F255/00 , C08L67/02
摘要： Disclosed is a thermoplastic resin composition comprising(A) 90 to 10% by weight of a modified polyolefin type resin obtained by subjecting 100 parts by weight of a polyolefin type resin to graft polymerization with 0.01 to 20 parts by weight of an .alpha.,.beta.-unsaturated carboxylate having a hydroxyl group and 0.01 to 50 parts by weight of an aromatic vinyl compound; and(B) 10 to 90% by weight of a saturated polyester.
摘要翻译： 公开了一种热塑性树脂组合物，其包含（A）90至10重量％的改性聚烯烃类树脂，其通过使100重量份的聚烯烃类树脂与0.01至20重量份的α，β- 具有羟基的不饱和羧酸酯和0.01〜50重量份的芳族乙烯基化合物; 和（B）10〜90重量％的饱和聚酯。
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公开(公告)号：US5332801A
公开(公告)日：1994-07-26
申请号：US16090
申请日：1993-02-10
申请人： Toru Tsukahara , Mitsutoshi Aritomi
发明人： Toru Tsukahara , Mitsutoshi Aritomi
CPC分类号： C08G65/485 , Y10S525/905
摘要： Disclosed are processes for preparing a process for preparing a modified polyphenylene ether which comprises reacting any one of a borane compound having at least one boronhydrogen bond, an .alpha.,.beta.-unsaturated carbonyl compound or a mercaptane having a carbonyl group, a hydroxyl group or an alkoxysilyl group with a polyphenylene ether having a carbon-carbon unsaturated bond in a substituent, and optionally oxidizing the resulting borane-modified PPE under alkaline conditions.
摘要翻译： 公开了制备改性聚苯醚的方法的方法，其包括使具有至少一个硼氢键的硼烷化合物，α，β-不饱和羰基化合物或具有羰基的硫醇中的任何一种，羟基或 在取代基中具有碳 - 碳不饱和键的聚亚苯基的烷氧基甲硅烷基，并且任选在碱性条件下氧化所得的硼烷改性PPE。
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公开(公告)号：US6160048A
公开(公告)日：2000-12-12
申请号：US133963
申请日：1998-08-14
IPC分类号： C08F8/00 , C08F255/02 , C08L51/06 , C08J3/02
CPC分类号： C08F255/02 , C08F8/00 , C08F2800/20 , C08L51/06 , C08L2666/02 , C08F210/02
摘要： There is provided a modified ethylene resin produced by subjecting (a) an ethylene resin to modification with (b) an .alpha.,.beta.-unsaturated carboxylic ester having a hydrocarbon-terminated polyalkylene oxide chain, and with (c) an aromatic vinyl compound and/or (d) an ester of an .alpha.,.beta.-unsaturated carboxylic acid with an aliphatic alcohol.There is also provided an ethylene resin composition comprising: (A) 80 to 99.9% by weight of a modified ethylene resin produced by subjecting (a) an ethylene resin to modification at least with (b) an .alpha.,.beta.-unsaturated carboxylic ester having a polyalkylene oxide chain; and (B) 20 to 0.1% by weight of a surfactant.
摘要翻译： 提供一种改性乙烯树脂，其通过（a）乙烯树脂与（b）具有烃封端的聚环氧烷链的α，β-不饱和羧酸酯和（c）芳族乙烯基化合物和/ 或（d）α，β-不饱和羧酸与脂族醇的酯。 还提供了一种乙烯树脂组合物，其包含：（A）80至99.9重量％的改性乙烯树脂，其通过（a）乙烯树脂至少用（b）α，β-不饱和羧酸酯 聚环氧烷链; 和（B）20至0.1重量％的表面活性剂。
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公开(公告)号：US5939181A
公开(公告)日：1999-08-17
申请号：US927225
申请日：1997-09-10
申请人： Yuuta Kumano , Mitsutoshi Aritomi , Kenji Takasaki , Osamu Nishizawa , Nobuhiro Shibuya , Hisao Ochiai , Kenji Nakajima
发明人： Yuuta Kumano , Mitsutoshi Aritomi , Kenji Takasaki , Osamu Nishizawa , Nobuhiro Shibuya , Hisao Ochiai , Kenji Nakajima
CPC分类号： C08J5/18 , C08J2323/10 , C08J2323/20 , Y10S428/91 , Y10T428/249953 , Y10T428/249978
摘要： A porous molded article having microvoids therein which comprises a stretched product of a resin molded material made up of, as the base material, an olefinic resin composition containing from 95 to 50% by weight of a crystalline olefinic resin component (A) and from 5 to 50% by weight of a polymer of a cyclic olefin having a weight average molecular weight of not less than 1,000 and less than 10,000 and a glass transition point of from 180 to 400.degree. C. component (B).
摘要翻译： 一种其中具有微孔的多孔模制品，其包括由作为基材的树脂模制材料的拉伸产物，所述树脂模制材料含有95至50重量％的结晶烯烃树脂组分（A）和5至5重量％的烯属树脂组合物 至50重量％的重均分子量不小于1,000且小于10,000的环烯烃的聚合物和玻璃化转变温度为180-400℃的组分（B）。
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公开(公告)号：US4923942A
公开(公告)日：1990-05-08
申请号：US251999
申请日：1988-09-30
申请人： Tadao Takeyama , Mitsutoshi Aritomi
发明人： Tadao Takeyama , Mitsutoshi Aritomi
IPC分类号： C08F220/20 , C08F20/10 , C08F220/10 , C08F220/18 , C08F220/30 , G02B1/04
CPC分类号： C08F220/30
摘要： An optical resin consisting essentially of a radical polymerization polymer of an ethylenically unsaturated monomer, characterized in that at least a major part of the ethlenically unsaturated monomer is an ester of 1 mole of tricyclo[5,2,1,0.sup.2,6 ]decanedimethanol with 2 moles of a mixture of acrylic acid and metharcylic acid. Because the resin is a polymer obtained from the restricted monomer as specified above, the resin possesses high thermal resistance and high heat stability as well as low hygroscopic property. Dimethanol compounds from higher Diels-Alder adducts of cyclopentadine are also used in place of the tricyclo [5,2,1,0.sup.2,6 ]decanedimthanol which is a Diels-Alder adduct of two moles of cyclopentadiene.
摘要翻译： 一种基本上由烯属不饱和单体的自由基聚合聚合物组成的光学树脂，其特征在于至少大部分的所述不饱和单体是1摩尔三环[5,2,1,02,6]癸烷二甲醇与 2摩尔丙烯酸和甲基马来酸的混合物。 由于树脂是由上述受限单体获得的聚合物，所以树脂具有高耐热性和高热稳定性以及低吸湿性。 也可以使用来自较高级Diels-Alder加合物的二甲醇化合物代替三环[5,2,1,02,6]癸二醇，其是两摩尔环戊二烯的Diels-Alder加合物。
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10.发明授权Process for production of highly rigid shaped product of polymer containing therein diacetylene group 失效用于生产含有二乙炔基团的聚合物的高刚性成型产品的方法
公开(公告)号：US4654178A
公开(公告)日：1987-03-31
申请号：US818744
申请日：1986-01-14
CPC分类号： C08G18/679 , B29C43/003 , B29C43/56 , C08G63/52 , B29K2105/251
摘要： A method for producing polyurethane or polyester containing therein the diacetylene group having high rigidity and useful in manufacturing precision mechanical parts, which comprises molding a polymer material containing therein the diacetylene group having a unit structure to be represented by the following general formula and a molecular weight in a range from 5.times.10.sup.2 to 1.times.10.sup.5 under a high pressure and at a temperature below the melting point of the polymer: ##STR1## wherein R is a divalent organic group; and x is an integer of 0 or 1.
摘要翻译： 一种含有其中具有高刚性并且可用于制造精密机械部件的二乙炔基团的聚氨酯或聚酯的方法，其包括在其中含有具有由下列通式表示的单元结构的二乙炔基的聚合物材料和分子量 在高压下和低于聚合物熔点的温度下在5×102至1×10 5的范围内：其中R是二价有机基团; x为0或1的整数。
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