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公开(公告)号：US06476278B1
公开(公告)日：2002-11-05
申请号：US09868169
申请日：2001-10-25
申请人： Hideyuki Ikehira , Kunihiko Murata , Eiji Katayama , Masami Kozawa , Toru Yokozawa , Takeshi Ohkuma , Takao Ikariya , Ryoji Noyori
发明人： Hideyuki Ikehira , Kunihiko Murata , Eiji Katayama , Masami Kozawa , Toru Yokozawa , Takeshi Ohkuma , Takao Ikariya , Ryoji Noyori
IPC分类号： C07C2700
CPC分类号： C07C29/145 , C07B2200/09 , C07C45/62 , C07C2601/14 , C07C33/22 , C07C35/08 , C07C33/20
摘要： Alcohols are produced in a practical and advantageous method, by the hydrogenation of a carbonyl compound under mild conditions, by reacting the carbonyl compounds with hydrogen in the presence of a bipyridyl derivative, a group VIII transition metal complex, and a base, or by reducing a carbonyl compound in the presence of a bipyridyl derivative, a group VIII transition metal complex, a base, and an alcoholic solvent.
摘要翻译： 通过在温和条件下氢化羰基化合物，通过在联吡啶衍生物，VIII族过渡金属络合物和碱的存在下使羰基化合物与氢反应，或通过还原 在联吡啶衍生物，VIII族过渡金属络合物，碱和醇溶剂存在下的羰基化合物。
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2.发明授权公开(公告)号：US07601667B2
公开(公告)日：2009-10-13
申请号：US11922409
申请日：2006-03-10
申请人： Noriyuki Utsumi , Kunihiko Murata , Kunihiko Tsutsumi , Takeaki Katayama , Masahito Watanabe , Takeshi Ohkuma , Ryoji Noyori
发明人： Noriyuki Utsumi , Kunihiko Murata , Kunihiko Tsutsumi , Takeaki Katayama , Masahito Watanabe , Takeshi Ohkuma , Ryoji Noyori
IPC分类号： B01J31/18 , B01J31/12 , C07C29/145
CPC分类号： C07C311/18 , B01J31/1805 , B01J31/2204 , B01J31/2295 , B01J2231/643 , B01J2531/821 , B01J2531/822 , B01J2531/827 , C07B2200/07 , C07C29/145 , C07C2602/08 , C07D311/22 , C07C33/26 , C07C33/46 , C07C35/32
摘要： A sulfonate catalyst represented by the formula below and a ketone compound are placed in a solvent, and the ketone compound is hydrogenated by mixing in the presence of hydrogen to produce an optically active alcohol.
摘要翻译： 将由下式表示的磺酸盐催化剂和酮化合物置于溶剂中，并且通过在氢气存在下混合来使酮化合物氢化以产生光学活性的醇。
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公开(公告)号：US20080234525A1
公开(公告)日：2008-09-25
申请号：US11922409
申请日：2006-03-10
申请人： Noriyuki Utsumi , Kunihiko Murata , Kunihiko Tsutsumi , Takeaki Katayama , Masahiro Watanabe , Takeshi Ohkuma , Ryoji Noyori
发明人： Noriyuki Utsumi , Kunihiko Murata , Kunihiko Tsutsumi , Takeaki Katayama , Masahiro Watanabe , Takeshi Ohkuma , Ryoji Noyori
IPC分类号： C07C29/143 , C07F11/00
CPC分类号： C07C311/18 , B01J31/1805 , B01J31/2204 , B01J31/2295 , B01J2231/643 , B01J2531/821 , B01J2531/822 , B01J2531/827 , C07B2200/07 , C07C29/145 , C07C2602/08 , C07D311/22 , C07C33/26 , C07C33/46 , C07C35/32
摘要： A sulfonate catalyst represented by the formula below and a ketone compound are placed in a solvent, and the ketone compound is hydrogenated by mixing in the presence of hydrogen to produce an optically active alcohol.
摘要翻译： 将由下式表示的磺酸盐催化剂和酮化合物置于溶剂中，并且通过在氢气存在下混合来使酮化合物氢化以产生光学活性的醇。
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4.发明申请Hydrogenation Promoter, Hydrogenation Catalyst, and Process for Producing Alkene Compound 失效氢化促进剂，氢化催化剂和生产烯烃化合物的方法公开(公告)号：US20080033221A1
公开(公告)日：2008-02-07
申请号：US11547002
申请日：2005-03-30
申请人： Junichi Hori , Kunihiko Murata , Nobuhito Kurono , Takeshi Ohkuma , Ryoji Noyori
发明人： Junichi Hori , Kunihiko Murata , Nobuhito Kurono , Takeshi Ohkuma , Ryoji Noyori
CPC分类号： B01J31/2291 , B01J23/44 , B01J31/2286 , B01J35/0013 , B01J35/006 , B01J2231/645 , B01J2531/824 , B82Y30/00 , C07C5/09 , C07C17/354 , C07C29/17 , C07C2531/22 , C07F15/006 , C07F15/0066 , C07C11/02 , C07C21/04 , C07C33/046 , C07C33/044 , C07C33/042 , C07C33/025
摘要： A hydrogenation promoter of the present invention is produced by reacting an alkyne compound or an alkene compound, a palladium compound represented by a general formula Pd(II)XjLk (where L represents a monodentate ligand or a polydendate ligand other than a phosphorus-containing ligand (when two or more Ls are present in the compound, the Ls may be the same or different), X represents an anionic group, j represents a value determined according to the valence of X so that Xj has a valence of −2 as a whole, and k represents an integer in the range of 0 to 4), and a base in an organic solvent. Specifically, The hydrogenation promoter of the invention includes palladium nanoparticles containing the alkyne compound or the alkene compound as an agglomeration-preventing agent.
摘要翻译： 本发明的氢化助催化剂是通过使炔化合物或烯烃化合物，通式Pd（II）所示的钯化合物（N） 其中L表示除含磷配体以外的单齿配体或多齿配体（当化合物中存在两个或更多个L时，L可以相同或不同），X表示阴离子基团，j表示确定的值 根据X的化合价，使X X整体上的化合价为-2，k表示0〜4的整数）和有机溶剂中的碱。 具体地说，本发明的氢化促进剂包括含有炔化合物或烯化合物作为防结块剂的钯纳米颗粒。
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5.发明授权Hydrogenation promoter, hydrogenation catalyst, and process for producing alkene compound 失效氢化促进剂，氢化催化剂和烯烃化合物的制备方法公开(公告)号：US07619125B2
公开(公告)日：2009-11-17
申请号：US11547002
申请日：2005-03-30
申请人： Junichi Hori , Kunihiko Murata , Nobuhito Kurono , Takeshi Ohkuma , Ryoji Noyori
发明人： Junichi Hori , Kunihiko Murata , Nobuhito Kurono , Takeshi Ohkuma , Ryoji Noyori
IPC分类号： B01J31/00
CPC分类号： B01J31/2291 , B01J23/44 , B01J31/2286 , B01J35/0013 , B01J35/006 , B01J2231/645 , B01J2531/824 , B82Y30/00 , C07C5/09 , C07C17/354 , C07C29/17 , C07C2531/22 , C07F15/006 , C07F15/0066 , C07C11/02 , C07C21/04 , C07C33/046 , C07C33/044 , C07C33/042 , C07C33/025
摘要： A hydrogenation promoter of the present invention is produced by reacting an alkyne compound or an alkene compound, a palladium compound represented by a general formula Pd(II)XjLk (where L represents a monodentate ligand or a polydendate ligand other than a phosphorus-containing ligand (when two or more Ls are present in the compound, the Ls may be the same or different), X represents an anionic group, j represents a value determined according to the valence of X so that Xj has a valence of −2 as a whole, and k represents an integer in the range of 0 to 4), and a base in an organic solvent. Specifically, The hydrogenation promoter of the invention includes palladium nanoparticles containing the alkyne compound or the alkene compound as an agglomeration-preventing agent.
摘要翻译： 本发明的氢化促进剂是通过使炔烃化合物或烯烃化合物，通式Pd（II）XjLk（其中L代表单配体或除了含磷配体之外的多齿配位体）表示的钯化合物 （当化合物中存在两个或更多个L时，L可以相同或不同），X表示阴离子基团，j表示根据X的化合价确定的值，使得Xj的化合价为-2，为 整数，k表示0〜4的整数）和有机溶剂中的碱。 具体地说，本发明的氢化促进剂包括含有炔化合物或烯化合物作为防结块剂的钯纳米颗粒。
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公开(公告)号：US20070225528A1
公开(公告)日：2007-09-27
申请号：US10594327
申请日：2004-03-29
IPC分类号： C07C29/00
CPC分类号： B01J31/182 , B01J31/2452 , B01J2231/643 , B01J2531/821 , C07B2200/07 , C07C29/145 , C07C311/18 , C07C2602/08 , C07C2602/10 , C07C2602/12 , C07D311/22 , C07C31/20 , C07C31/205 , C07C31/207 , C07C31/36 , C07C31/38 , C07C33/042 , C07C33/26 , C07C33/28 , C07C33/46 , C07C35/23 , C07C35/32 , C07C35/36 , C07C35/52
摘要： A ruthenium complex RuCl[(S,S)-Tsdpen](p-cymene) represented by a formula below and a ketone compound are placed in a polar solvent, and the resulting mixture is mixed under pressurized hydrogen to hydrogenate the ketone compound and to thereby produce an optically active alcohol:
摘要翻译： 将由下式表示的钌络合物RuCl [（S，S）-Tsdpen]（对甲基异丙基苯）和酮化合物置于极性溶剂中，将所得混合物在加压氢气下混合以氢化酮化合物，并 从而产生光学活性的醇：
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公开(公告)号：US20090216019A1
公开(公告)日：2009-08-27
申请号：US11887340
申请日：2005-03-30
申请人： Ryoji Noyori , Takeshi Okuma , Kunihiko Tsutsumi , Nariyuki Utsumi , Kunihiko Murata , Takeaki Katayama
发明人： Ryoji Noyori , Takeshi Okuma , Kunihiko Tsutsumi , Nariyuki Utsumi , Kunihiko Murata , Takeaki Katayama
IPC分类号： C07F15/00 , C07D453/02
CPC分类号： C07F9/5027 , B01J31/1815 , B01J31/182 , B01J31/24 , B01J2231/643 , B01J2531/821 , C07B53/00 , C07D453/02 , C07F15/0046 , C07F15/0053
摘要： A novel ruthenium complex which is a highly efficient catalyst useful for the production of optically active 3-quinuclidinols, and a process for production of optically active 3-quinuclidinols using the ruthenium complex as a catalyst, where the optically active 3-quinuclidinols are useful as an optically active, physiologically active compound utilized in medicines and agrichemicals or as a synthetic intermediate such as a liquid crystal material.
摘要翻译： 一种新型的钌络合物，其是用于制备光学活性3-奎宁环的高效催化剂，以及使用钌络合物作为催化剂生产光学活性3-奎宁环的方法，其中光学活性3-奎宁环醇可用作 用于药物和农药的光学活性的生理活性化合物或作为液晶材料的合成中间体。
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8.发明授权公开(公告)号：US07332622B2
公开(公告)日：2008-02-19
申请号：US10934338
申请日：2004-09-03
IPC分类号： C07C255/00 , C07C69/76
CPC分类号： B01J31/1805 , B01J31/2295 , B01J2231/348 , B01J2531/821 , B01J2540/34 , C07C253/30 , C07C255/22
摘要： A process for preparing optically active nitro compounds and cyano compounds using a metal complex, which is obtained by reaction of an optically active nitrogen-containing compound and a periodic table group VIII metal complex, in the asymmetric Michael reaction.
摘要翻译： 在非对称迈克尔反应中使用通过光学活性含氮化合物和周期表VIII族金属络合物的反应获得的金属络合物制备旋光性硝基化合物和氰基化合物的方法。
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9.发明申请公开(公告)号：US20050101787A1
公开(公告)日：2005-05-12
申请号：US10934338
申请日：2004-09-03
IPC分类号： C07D317/60 , C07B53/00 , C07B61/00 , C07C201/12 , C07C205/45 , C07C205/53 , C07C253/30 , C07C255/41 , C07D307/54 , C07D333/24 , C07D29/12 , C07D27/333
CPC分类号： B01J31/1805 , B01J31/2295 , B01J2231/348 , B01J2531/821 , B01J2540/34 , C07C253/30 , C07C255/22
摘要： A process for preparing optically active nitro compounds and cyano compounds represented by the chemical formula (C) using a metal complex, which is obtained by reaction of an optically active nitrogen-containing compound and a periodic table group VIII metal complex, in the asymmetric Michael reaction of a compound represented by the chemical formula (A) and a compound represented by the chemical formula (B) according to the claim 1.
摘要翻译： 使用通过光学活性含氮化合物和周期表VIII族金属络合物的反应获得的金属络合物来制备由式（C）表示的光学活性硝基化合物和氰基化合物的方法， 由化学式（A）表示的化合物与根据权利要求1的化学式（B）表示的化合物的反应。
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公开(公告)号：US08212037B2
公开(公告)日：2012-07-03
申请号：US11887340
申请日：2005-03-30
申请人： Ryoji Noyori , Takeshi Okuma , Kunihiko Tsutsumi , Noriyuki Utsumi , Kunihiko Murata , Takeaki Katayama
发明人： Ryoji Noyori , Takeshi Okuma , Kunihiko Tsutsumi , Noriyuki Utsumi , Kunihiko Murata , Takeaki Katayama
IPC分类号： C07F15/00 , C07D453/02
CPC分类号： C07F9/5027 , B01J31/1815 , B01J31/182 , B01J31/24 , B01J2231/643 , B01J2531/821 , C07B53/00 , C07D453/02 , C07F15/0046 , C07F15/0053
摘要： A novel ruthenium complex which is a highly efficient catalyst useful for the production of optically active 3-quinuclidinols, and a process for production of optically active 3-quinuclidinols using the ruthenium complex as a catalyst, where the optically active 3-quinuclidinols are useful as an optically active, physiologically active compound utilized in medicines and agrichemicals or as a synthetic intermediate such as a liquid crystal material.
摘要翻译： 一种新型的钌络合物，其是用于制备光学活性3-奎宁环的高效催化剂，以及使用钌络合物作为催化剂生产光学活性3-奎宁环的方法，其中光学活性3-奎宁环醇可用作 用于药物和农药的光学活性的生理活性化合物或作为液晶材料的合成中间体。
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