Method of making electrically conductive fibers
    1.
    发明授权
    Method of making electrically conductive fibers 失效
    制造导电纤维的方法

    公开(公告)号:US5248468A

    公开(公告)日:1993-09-28

    申请号:US786170

    申请日:1991-10-31

    IPC分类号: D01D5/34 D01F1/09 D01F8/04

    CPC分类号: D01D5/34 D01F1/09 D01F8/04

    摘要: Electrically conductive conjugate fibers having a diameter less than 50 fm. The fibers include a thermoplastic sheath and a low-melting metal core, with the core occupying 0.2 to 50% of the sectional area of the fiber. The sectional area of the core varies by less than 25% in the longitudinal direction, and the total length of the discontinuous portions of the core is 5 cm or less per meter. The fibers can be produced with a conjugate spinning nozzle. The low-melting metal is provided to the nozzle from a closed fusion tank located at a position below the spinning nozzle. The metal is supplied to the spinning nozzle by means of pressure from inert gas, which is supplied to an upper space of the fusion tank. The level of metal in the fusion tank is maintained substantially constant, and the pressure of the gas is controlled so as to maintain a pressure variation of 0.1 kg/cm.sup.2 or less.

    摘要翻译: 直径小于50微米的导电复合纤维。 纤维包括热塑性护套和低熔点金属芯,其中芯占纤维截面面积的0.2-50%。 芯的截面积沿纵向变化小于25%,芯的不连续部分的总长度为每米5厘米或更小。 纤维可以用复合纺丝喷嘴生产。 将低熔点金属从位于纺丝喷嘴下方位置的封闭的熔化罐提供给喷嘴。 通过来自惰性气体的压力将金属供给到纺丝喷嘴,惰性气体被供应到熔化罐的上部空间。 熔池中的金属含量保持基本恒定,并且控制气体的压力以保持0.1kg / cm 2以下的压力变化。

    Electrically conductive fibers, apparatus and method for the production
thereof
    2.
    发明授权
    Electrically conductive fibers, apparatus and method for the production thereof 失效
    导电纤维,其制造方法及其制造方法

    公开(公告)号:US5173366A

    公开(公告)日:1992-12-22

    申请号:US789539

    申请日:1991-11-08

    IPC分类号: D01D5/34 D01F1/09 D01F8/04

    摘要: Electrically conductive conjugate fibers having a diameter less than 50.mu.m. The fibers include a thermoplastic sheath and a low-melting metal core, with the core occupying 0.2 to 50% of the sectional area of the fiber. The sectional area of the core varies by less than 25% in the longitudinal direction, and the total length of the discontinuous portions of the core is 5 cm or less per meter. The fibers can be produced with a conjugate spinning nozzle. The low-melting metal is provided to the nozzle from the closed fusion tank located at a position below the spinning nozzle. The metal is supplied to the spinning nozzle by means of pressure from inert gas, which is supplied to an upper space of the fusion tank. The level of metal in the fusion tank is maintained substantially constant, and the pressure of the gas is controlled so as to maintain a pressure variation of 0.1 kg/cm.sup.2 or less.

    摘要翻译: 直径小于50微米的导电复合纤维。 纤维包括热塑性护套和低熔点金属芯,其中芯占纤维截面面积的0.2-50%。 芯的截面积沿纵向变化小于25%,芯的不连续部分的总长度为每米5厘米或更小。 纤维可以用复合纺丝喷嘴生产。 低熔点金属从位于纺丝喷嘴下方位置的封闭式熔化罐提供给喷嘴。 通过来自惰性气体的压力将金属供给到纺丝喷嘴,惰性气体被供应到熔化罐的上部空间。 熔池中的金属含量保持基本恒定,并且控制气体的压力以保持0.1kg / cm 2以下的压力变化。

    Polymerizable compound having mildew resistance and polymer thereof
    3.
    发明授权
    Polymerizable compound having mildew resistance and polymer thereof 失效
    具有抗霉菌性的可聚合化合物及其聚合物

    公开(公告)号:US5583230A

    公开(公告)日:1996-12-10

    申请号:US86905

    申请日:1993-07-07

    CPC分类号: C08F12/14 C08L75/04

    摘要: A novel mildew resistant polymerizable compound of the formula: ##STR1## wherein X is --0-- or --S--; and Y is a residue of a known mildew proofing compound, preferably, a residue of a compound selected from the group consisting of phenol substituted with 1 to 5 halogen atoms, p-chloro-m-cresol, o-phenylphenol, p-chloro-m-xylenol, salicylanilide, 8-hydroxyquinoline, 2-(4'-thiazolyl)benzimidazole, 2,5-dibromo-4-methylaniline, 1,2-benzoisothiazolin-3-one and 2-pyridinethiol-1-oxide. A polymer of the compound [I] and polyurethane composition containing the polymer are also disclosed.

    摘要翻译: 一种下式的新型抗霉化聚合性化合物:其中X为-O-或-S-; Y是已知防霉化合物的残基,优选选自被1至5个卤素原子取代的苯酚,对氯间甲苯酚,邻苯基苯酚,对氯 - 间 - 二甲苯酚,水杨酰苯胺,8-羟基喹啉,2-(4'-噻唑基)苯并咪唑,2,5-二溴-4-甲基苯胺,1,2-苯并异噻唑啉-3-酮和2-吡啶硫醇-1-氧化物。 还公开了化合物[I]的聚合物和含有聚合物的聚氨酯组合物。

    Novel polymerizable compound having mildew resistance and polymer thereof
    4.
    发明授权
    Novel polymerizable compound having mildew resistance and polymer thereof 失效
    具有抗霉菌性的新型聚合性化合物及其聚合物

    公开(公告)号:US4956431A

    公开(公告)日:1990-09-11

    申请号:US268956

    申请日:1988-11-09

    IPC分类号: C08F12/14 C08L75/04

    CPC分类号: C08F12/14 C08L75/04

    摘要: A novel mildew resistant polymerizable compound of the formula: ##STR1## wherein X is --O-- or --S--; and Y is a residue of a known mildew proofing compound, preferably, a residue of a compound selected from the group consisting of phenol substituted with 1 to 5 halogen atoms, p-chloro-m-cresol, o-phenylphenol, p-chloro-m-xylenol, salicylanilide, 8-hydroxyquinoline, 2-(4'-thiazolyl)benzimidazole, 2,5-dibromo-4-methylaniline, 1,2-benzoisothiazolin-3-one and 2-pyridinethiol-1-oxide. A polymer of the compound [I] and a polyurethane composition containing the polymer are also disclosed.

    摘要翻译: 一种下式的新型抗霉化可聚合化合物:其中X为-O-或-S-; Y是已知防霉化合物的残基,优选选自被1至5个卤素原子取代的苯酚,对氯间甲苯酚,邻苯基苯酚,对氯 - 间 - 二甲苯酚,水杨酰苯胺,8-羟基喹啉,2-(4'-噻唑基)苯并咪唑,2,5-二溴-4-甲基苯胺,1,2-苯并异噻唑啉-3-酮和2-吡啶硫醇-1-氧化物。 还公开了化合物[I]的聚合物和含有该聚合物的聚氨酯组合物。

    Process for production of polyester polyurethane elastomeric fibers
    7.
    发明授权
    Process for production of polyester polyurethane elastomeric fibers 失效
    生产聚酯聚氨酯弹性体纤维的方法

    公开(公告)号:US4963310A

    公开(公告)日:1990-10-16

    申请号:US267663

    申请日:1988-11-04

    摘要: A process for the production of polyester polyurethane elastomeric fibers having improved humid aging resistance which comprises the steps of reacting a polyester diol with an excess molar amount of an organic diisocyanate to prepare a urethane prepolymer having terminal isocyanate group at both ends thereof; extending the chain of the prepolymer with a bifunctional active hydrogen compound and 0.5 to 10.0 mole % of a diaminosilyl compound based on the total amount of the bifunctional active hydrogen compound during or after preparation of the prepolymer to obtain a polyurethane; spinning the polyurethane into fiber; and crosslinking the polyurethane during or after spinning.

    摘要翻译: 一种制备具有改善的耐潮湿老化性的聚酯聚氨酯弹性体纤维的方法,其包括使聚酯二醇与过量摩尔量的有机二异氰酸酯反应以制备其两端具有末端异氰酸酯基团的氨基甲酸酯预聚物; 基于双功能活性氢化合物的总量,在预聚物制备期间或之后,用双官能活性氢化合物和0.5-10.0摩尔%的二氨基甲硅烷基化合物延伸预聚物链,得到聚氨酯; 将聚氨酯纺成纤维; 并在纺丝期间或之后使聚氨酯交联。

    Urethane polymers containing a tertiary nitrogen atom, and their
production
    9.
    发明授权
    Urethane polymers containing a tertiary nitrogen atom, and their production 失效
    含有叔氮原子的聚氨酯聚合物及其生产

    公开(公告)号:US4562239A

    公开(公告)日:1985-12-31

    申请号:US638007

    申请日:1984-08-06

    摘要: A tertiary nitrogen atom-containing urethane polymer which comprises units of the following formulas (I) and (II) as the essential components and units of the following formulas (III), (IV) and (V) as the optional components, the content of the unit of the formula (I) being not less than 10 milliequivalents in terms of the tertiary nitrogen atom per kilogram of the urethane polymer, and has a molecular weight of not less than 500: ##STR1## wherein R.sub.1 and R.sub.2 are each a C.sub.1 -C.sub.4 alkyl group and, when taken together with the adjacent nitrogen atom to which they are attached, represent a nitrogen-containing heterocyclic group, R.sub.3 is a C.sub.1 -C.sub.4 alkyl group, R.sub.4 is an optionally branched C.sub.1 -C.sub.8 alkylene group, m is a positive integer and n is zero or a positive integer but m+n is a number which can provide the unit of the formula (I) with a molecular weight of 131 to 6998 and the bondings in the unit of the formula (I) may be in random and/or block, R.sub.5 is a residue of an organic diisocyanate, R.sub.6 is an optionally branched C.sub.1 -C.sub.8 alkylene group, an aromatic group optionally substituted with one or more C.sub.1 -C.sub.4 alkyl groups and/or one or more halogen atoms or a residue of a polyetherdiol thereof, R.sub.7 is a residue of a dicarboxylic acid and R.sub.8 is a residue of a diamine or a residue of a hydrazine, which is effective in improvement of resistance to color change due to gas.

    摘要翻译: 含有以下式(I)和(II)的单元作为主要组分的叔氮原子的氨基甲酸酯聚合物和作为任选组分的下式(III),(IV)和(V)的单元,含量 式(I)的单元按每千克氨基甲酸酯聚合物的叔氮原子计不少于10毫当量,分子量不小于500:(I)[CONHR5NHCO]( II)[OR 6 O](III)[COR 7 CO](IV)[NHR 8 NH](V)其中R 1和R 2各自是C 1 -C 4烷基,并且与它们所连接的相邻氮原子一起表示 含氮杂环基,R3为C1-C4烷基,R4为任意支链的C1-C8亚烷基,m为正整数,n为0或正整数,但m + n为可提供 式(I)单元,其分子量为131至6998,并且式(I)单元中的键可以是任意的,并且 /或嵌段,R5是有机二异氰酸酯的残基,R6是任选支链的C 1 -C 8亚烷基,任选被一个或多个C 1 -C 4烷基和/或一个或多个卤素原子取代的芳基,或者 其为聚醚二醇,R 7为二羧酸的残基,R 8为二胺或残基的残基,可有效提高由气体引起的颜色变化。

    Polyurethane composition improved in dyeing property
    10.
    发明授权
    Polyurethane composition improved in dyeing property 失效
    聚氨酯组合物改善了染色性能

    公开(公告)号:US4499221A

    公开(公告)日:1985-02-12

    申请号:US615647

    申请日:1984-05-31

    IPC分类号: C08L75/04 C08L75/00

    CPC分类号: C08L75/04

    摘要: A polyurethane composition improved in dyeing property which comprises (A) a polyurethane and (B) a tertiary nitrogen atom-containing polymer incorporated therein in an amount sufficient to stabilize the polyurethane (A), said polymer (B) being the reaction product between (C) a tertiary nitrogen atom-containing diol and an excessive amount of (D) an organic diisocyanate, the terminal isocyanate group in said reaction product being blocked with a monoamine and/or a dialkylhydrazine.

    摘要翻译: 一种改进了染色性能的聚氨酯组合物,其包含(A)聚氨酯和(B)含有足以稳定聚氨酯(A)的量的含叔叔氮原子的聚合物,所述聚合物(B)是( C)含有叔氮原子的二醇和过量的(D)有机二异氰酸酯,所述反应产物中的末端异氰酸酯基团被单胺和/或二烷基肼封闭。