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    Method For Producing Amide Compound
    3.
    发明申请
    Method For Producing Amide Compound 审中-公开
    生产酰胺化合物的方法

    公开(公告)号：US20090171051A1

    公开(公告)日：2009-07-02

    申请号：US12089511

    申请日：2006-10-06

    申请人： Hiroko Shibamoto ,  Toshikazu Aikawa ,  Teruo Arii ,  Masanori Muramoto ,  Takeshi Fukuda ,  Kiyoshi Ito ,  Takeya Abe ,  Souichi Hazama

    发明人： Hiroko Shibamoto ,  Toshikazu Aikawa ,  Teruo Arii ,  Masanori Muramoto ,  Takeshi Fukuda ,  Kiyoshi Ito ,  Takeya Abe ,  Souichi Hazama

    IPC分类号： C08F22/38 ,  C12P13/02

    CPC分类号： C12P13/00 ,  C07C231/06 ,  C08F220/56 ,  C12P13/02 ,  C07C233/09

    摘要： [Problems] The present invention provides a method for efficiently producing a corresponding amide compound from a nitrile compound by a reaction using a nitrile hydratase and a method for producing an amide-based polymer excellent in quality from the amide compound. In addition, the present invention provides a method for more efficiently producing an acrylamide with higher quality by a microbial catalyst containing a nitrile hydratase and the like and a method for producing an acrylamide-based polymer, which is excellent in hue, has a good balance between the water solubility and the high molecular weight and is also excellent in quality, by using the acrylamide.[Means for Solving the Problems] The method for producing an amide compound of the present invention is characterized in that in a method for producing an amide compound from a nitrile compound in an aqueous medium in the presence of a catalyst having a nitrile hydratase activity, the concentration of benzene in the aqueous medium is 4.0 ppm or less. In addition, the method for producing an amide-based polymer of the present invention is characterized by homopolymerizing the amide compound or by copolymerizing the amide compound and at least unsaturated monomer copolymerizable with the amide compound. Further, the method for producing acrylamide of the present invention is characterized by hydrating acrylonitrile having a concentration of acrolein of 1 ppm or less by a microbial cell containing a nitrile hydratase or a processed product of the microbial cell in an aqueous medium. Furthermore, the method for producing an acrylamide-based polymer of the present invention is characterized by homopolymerizing the acrylamide or by copolymerizing the acrylamide and at least one unsaturated monomer copolymerizable with the acrylamide.

    摘要翻译： 本发明提供一种通过使用腈水合酶的反应从腈化合物有效地制备相应的酰胺化合物的方法和由酰胺化合物质量优异的酰胺类聚合物的制备方法。 此外，本发明提供了一种通过含有腈水合酶等的微生物催化剂更有效地制备丙烯酰胺的方法以及色调优异的丙烯酰胺类聚合物的制造方法，其平衡性良好 在水溶性和高分子量之间，并且通过使用丙烯酰胺也具有优异的质量。 解决问题的手段本发明的酰胺化合物的制造方法的特征在于，在具有腈水合酶活性的催化剂存在下，在含水介质中由腈化合物制备酰胺化合物的方法中， 水介质中苯的浓度为4.0ppm以下。 此外，本发明的酰胺系聚合物的制造方法的特征在于，使酰胺化合物均聚，或者使酰胺化合物与至少与酰胺化合物可共聚的不饱和单体共聚。 此外，本发明的丙烯酰胺的制造方法的特征在于，通过含有腈水合酶的微生物细胞或微生物细胞的加工产物在水性介质中使丙烯醛浓度为1ppm以下的丙烯腈水合。 此外，本发明的丙烯酰胺类聚合物的制造方法的特征在于使丙烯酰胺均聚或通过共聚丙烯酰胺和至少一种与丙烯酰胺共聚的不饱和单体。

    PROCESS FOR PRODUCING (METH) ACRYLAMIDE
    4.
    发明申请
    PROCESS FOR PRODUCING (METH) ACRYLAMIDE 有权
    生产（甲基）丙烯酰胺的方法

    公开(公告)号：US20090311759A1

    公开(公告)日：2009-12-17

    申请号：US12301138

    申请日：2007-04-03

    申请人： Takeya Abe ,  Takeshi Fukuda

    发明人： Takeya Abe ,  Takeshi Fukuda

    IPC分类号： C12P13/02

    CPC分类号： C07C231/24 ,  C12P13/02 ,  C07C233/09

    摘要： [Problem] To provide a process for producing (meth)acrylamide using a microbial catalyst, wherein production steps can be simplified and production cost can be reduced.[Means for solving problem] The process for producing (meth)acrylamide of the present invention is a process comprising (a) a step of allowing (meth)acrylonitrile to undergo hydration reaction by the use of a microbial catalyst containing nitrile hydratase in an aqueous medium to obtain a (meth)acrylamide reaction solution (I) and (b) a step of removing impurities from the reaction solution (I) to obtain a (meth)acrylamide aqueous solution (II), wherein the concentration of (meth)acrylamide in the reaction solution (I) obtained in the step (a) is higher than the concentration of (meth)acrylamide in the aqueous solution (II) obtained in the step (b) by 2 to 20% by weight.

    摘要翻译： [问题]提供使用微生物催化剂制备（甲基）丙烯酰胺的方法，其中可以简化生产步骤并降低生产成本。 [解决问题的方法]本发明的（甲基）丙烯酰胺的制造方法是一种方法，其包括（a）使（甲基）丙烯腈进行水合反应的工序，其中使用含腈水合酶的微生物催化剂 培养以得到（甲基）丙烯酰胺反应溶液（I）和（b）从反应溶液（I）中除去杂质以获得（甲基）丙烯酰胺水溶液（II）的步骤，其中（甲基）丙烯酰胺 在步骤（a）中获得的反应溶液（I）中，比步骤（b）中获得的水溶液（II）中的（甲基）丙烯酰胺的浓度高2至20重量％。

    Process for producing (meth)acrylamide
    5.
    发明授权
    Process for producing (meth)acrylamide 有权
    （甲基）丙烯酰胺的制造方法

    公开(公告)号：US08143033B2

    公开(公告)日：2012-03-27

    申请号：US12301138

    申请日：2007-04-03

    申请人： Takeya Abe ,  Takeshi Fukuda

    发明人： Takeya Abe ,  Takeshi Fukuda

    IPC分类号： C12P13/02

    CPC分类号： C07C231/24 ,  C12P13/02 ,  C07C233/09

    摘要： A process for producing (meth)acrylamide using a microbial catalyst, wherein production steps can be simplified and production cost can be reduced. The process for producing (meth)acrylamide of the present involves (a) a step of allowing (meth)acrylonitrile to undergo hydration reaction by the use of a microbial catalyst containing nitrile hydratase in an aqueous medium to obtain a (meth)acrylamide reaction solution (I) and (b) a step of removing impurities from the reaction solution (I) to obtain a (meth)acrylamide aqueous solution (II), wherein the concentration of (meth)acrylamide in the reaction solution (I) obtained in the step (a) is higher than the concentration of (meth)acrylamide in the aqueous solution (II) obtained in the step (b) by 2 to 20% by weight.

    摘要翻译： 使用微生物催化剂制造（甲基）丙烯酰胺的方法，其中可以简化生产步骤并降低生产成本。 本发明的（甲基）丙烯酰胺的制造方法包括：（a）使含有腈水合酶的微生物催化剂在水性介质中进行水合反应的步骤，得到（甲基）丙烯酰胺反应液 （I）和（b）从反应溶液（I）中除去杂质以获得（甲基）丙烯酰胺水溶液（II）的步骤，其中在（I）中获得的反应溶液（I）中的（甲基）丙烯酰胺的浓度 步骤（a）比步骤（b）中得到的水溶液（II）中的（甲基）丙烯酰胺的浓度高2〜20重量％。

    Catalyst for living radical polymerization and polymerization method
    6.
    发明授权
    Catalyst for living radical polymerization and polymerization method 有权
    催化剂用于活性自由基聚合和聚合方法

    公开(公告)号：US09546226B2

    公开(公告)日：2017-01-17

    申请号：US13388811

    申请日：2010-05-10

    申请人： Atsushi Goto ,  Yoshinobu Tsujii ,  Takeshi Fukuda

    发明人： Atsushi Goto ,  Yoshinobu Tsujii ,  Takeshi Fukuda

    IPC分类号： C08F20/14 ,  C08F4/40 ,  C08F293/00 ,  C08F12/08 ,  C08F120/14

    CPC分类号： C08F4/40 ,  C08F12/08 ,  C08F120/14 ,  C08F293/005 ,  C08F2438/00

    摘要： Provided is a low-cost, highly active, environmentally friendly living radical polymerization catalyst which does not require a radical initiator. An organic compound having an oxidation-reduction capability is used as a catalyst. Even if a radical initiator is not used, a monomer can be subjected to a radical polymerization to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced. It is made possible to prevent adverse effects of using a radical initiator. The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages of the catalyst such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor (which do not require a post-treatment for a molded article), etc.

    摘要翻译： 提供了不需要自由基引发剂的低成本，高活性，环保的活性自由基聚合催化剂。 使用具有氧化还原能力的有机化合物作为催化剂。 即使不使用自由基引发剂，也可以对单体进行自由基聚合，得到分子量分布窄的聚合物。 活性自由基聚合的成本可以显着降低。 可以防止使用自由基引发剂的不利影响。 由于催化剂的优点，催化剂的低毒性，必需的催化剂量低，催化剂的溶解度高，反应条件温和，反应条件好，因此本发明的环保性和经济性优于常规的活性自由基聚合方法。 无着色/无异味（不需要后处理成型品）等

    Method for producing tolylene diisocyanate
    8.
    发明授权
    Method for producing tolylene diisocyanate 有权
    甲苯二异氰酸酯的制备方法

    公开(公告)号：US08748654B2

    公开(公告)日：2014-06-10

    申请号：US14115852

    申请日：2012-04-06

    申请人： Koji Takamatsu ,  Kazuhiro Kosumi ,  Takeshi Fukuda ,  Masaaki Sasaki

    发明人： Koji Takamatsu ,  Kazuhiro Kosumi ,  Takeshi Fukuda ,  Masaaki Sasaki

    IPC分类号： C07C263/00 ,  C07C263/04 ,  C07C263/06 ,  C07C263/20

    CPC分类号： C07C263/00 ,  C07C263/04 ,  C07C263/06 ,  C07C263/20 ,  C07C269/04 ,  C07C265/14 ,  C07C271/28

    摘要： A method for producing tolylene diisocyanate includes: mixing a first diaminotoluene containing 2,4-diaminotoluene and 2,6-diaminotoluene at a first isomer ratio and a second diaminotoluene containing 2,4-diaminotoluene and/or 2,6-diaminotoluene at a second isomer ratio that is different from the first isomer ratio so as to prepare mixed diaminotoluene; producing tolylene dicarbamate by reaction of the mixed diaminotoluene, urea and/or N-unsubstituted carbamic acid ester and alcohol; and thermally decomposing the tolylene dicarbamate.

    摘要翻译： 一种制备甲苯二异氰酸酯的方法包括：以第一异构体比例混合含有2,4-二氨基甲苯和2,6-二氨基甲苯的第一二氨基甲苯和第二异构体含有2,4-二氨基甲苯和/或2,6-二氨基甲苯的第二二氨基甲苯 异构体比例与第一异构体比例不同，以制备混合的二氨基甲苯; 通过混合的二氨基甲苯，脲和/或N-未取代的氨基甲酸酯和醇的反应制备甲苯二甲氨基甲酸酯; 并分解甲苯二氨基甲酸酯。

    Catalyst for living radical polymerization
    10.
    发明授权
    Catalyst for living radical polymerization 有权
    活性自由基聚合催化剂

    公开(公告)号：US08575285B2

    公开(公告)日：2013-11-05

    申请号：US13062688

    申请日：2009-09-08

    申请人： Atsushi Goto ,  Yoshinobu Tsujii ,  Takeshi Fukuda

    发明人： Atsushi Goto ,  Yoshinobu Tsujii ,  Takeshi Fukuda

    IPC分类号： C08F4/00 ,  C08F12/02 ,  C07C19/16 ,  C07C255/50 ,  C07C19/07 ,  C07C25/02 ,  C07C43/247 ,  B01J31/00 ,  B01J27/06 ,  B01J27/135

    CPC分类号： C08F4/00 ,  C08F293/005 ,  C08F2438/00

    摘要： Provided is a catalyst used for a living radical polymerization method, which contains a central element consisting of carbon and at least one halogen atom binding to the central element. Further, a hydrocarbon compound can be used as a catalyst precursor. A monomer having a radical-reactive unsaturated bond is subjected to a radical polymerization reaction in the presence of the catalyst, consequently a polymer having narrow molecular weight distribution can be obtained, and thus the cost of the living radical polymerization can be remarkably reduced. The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst used, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor (no need of any post-treatments for a molded article), and the like.

    摘要翻译： 提供了用于活性自由基聚合法的催化剂，其包含由碳和与中心元素结合的至少一个卤素原子组成的中心元素。 此外，可以使用烃化合物作为催化剂前体。 具有自由基反应性不饱和键的单体在催化剂的存在下进行自由基聚合反应，因此可以获得具有窄分子量分布的聚合物，从而可显着降低活性自由基聚合的成本。 本发明由于催化剂的毒性低，催化剂用量少，催化剂溶解性高，反应条件温和，无着色/无色性等优点，比现有的活性自由基聚合法更具环保性和经济性， 无异味（不需要对成形品进行后处理）等。