摘要:
A process for polymerizing or copolymerizing ethylene, characterized in that ethylene or a mixture of ethylene with other .alpha.-olefin is polymerized in the presence of a catalyst comprising:[I] a solid catalyst component (B) obtained by reacting the following three components:(a) a reaction product (A) of an organomagnesium compound with a hydropolysiloxane or a silicon compound in which organic groups and hydroxyl groups are bonded to silicon atoms,(b) a silicon compound of the formula R.sub.l.sup.1 Si(OR.sup.2).sub.m X.sub.4-(l+m), wherein R.sup.1 is a hydrogen atom or a hydrocarbon group having from 1 to 8 carbon atoms, R.sup.2 is a hydrocarbon group having from 1 to 12 carbon atoms, X is a halogen atom, l is 0, 1 or 2, and m is a number of from 0 to 4, and(c) a titanium compound of the formula Ti(OR.sup.3).sub.n X.sub.4-n, wherein R.sup.3 is a hydrocarbon group having from 1 to 12 carbon atoms, X is a halogen atom, and n is a number of 0 to 4, provided that m and n are not simultaneously 0, and when m is 0, n is 4, and[II] an organoaluminum compound.
摘要翻译:一种聚合或共聚乙烯的方法,其特征在于乙烯或乙烯与其它α-烯烃的混合物在催化剂存在下聚合,所述催化剂包括:[I]通过使以下三种组分反应得到的固体催化剂组分(B) (a)有机镁化合物与有机基团和羟基与硅原子键合的氢化聚硅氧烷或硅化合物的反应产物(A),(b)式R 1 Si(OR 2)m X 4 - (l + m),其中R 1是氢原子或具有1至8个碳原子的烃基,R 2是具有1至12个碳原子的烃基,X是卤素原子,l是0,1或2,以及 m为0〜4的数,(c)式Ti(OR 3)n X 4-n的钛化合物,其中,R 3为碳原子数1〜12的烃基,X为卤素原子,n为 是0〜4的数,条件是m和n不同时为0,当m为0时,n为4,[II]为器官 铝化合物。
摘要:
A solid catalyst for olefin polymerization, obtained by reacting a least one of a hydropolysiloxane compound, having the formula R1aHbSiO(4−a−b)/2, a silane compound of formula R2cSi(OH)4−c, and condensates of the silane, with a compound of formula (MgR32)p.(R3MgX)q to form a reaction product. The reaction product is reacted with an alcohol, having 1 to 4 carbon atoms, to obtain an intermediate product. The intermediate product, is then reacted with water to obtain reaction product. An organoaluminum oxy compound and a metallocene compound are carried on the solid reaction product. The solid catalyst may be used for olefin polymerization. The catalyst requires no deashing treatment and produces a polymer having high bulk density and narrow particle size distribution. Thus the solid catalystenables control of particle size of the polymer in a simple easy manner, and shows no adhesion of polymer onto the inner wall of autoclave.
摘要:
An olefinic copolymer having a cyclic structure is prepared by copolymerizing a) ethylene (M1) and b) dicyclopentadiene or tricyclopentadiene (M2), and, optionally c) a cyclic olefin (M3), in the presence of a catalyst which contains a metallocene compound (A) having formula [1]: H2C(R′mCp)(R″nCp)MX2[1], wherein M is zirconium or hafnium, Cp has a cyclopentadienyl skeleton, each of R′ and R″ is a hydrocarbon group having 1 to 10 carbon atoms, each of two X's which may be the same or different from each other, is a halogen, a hydrogen, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an alkylamino group, an alkoxy group, an aryloxy group of the formula —O—Ar—Yp, a thioalkyl group, or a thioaryl group of the formula —S—Ar—Yp; wherein Ar is an aromatic ring, Y is a halogen, a hydrogen, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an alkoxy group, an alkylamino group, a cyano group or a nitro group, and p is an integer of from 1 to 5, and each of m and n is an integer of from 0 to 4, provided that m and n are not equal, and m+n is an integer of from 3 to 6, and an aluminoxane (B), is used.
摘要:
The present invention relates to a solid catalyst (D) for olefin polymerization comprising a magnesium-containing solid component (A) carrying thereon an organoaluminum-oxy compound (B) and a metallocene compound (C), the magnesium-containing compound (A) being obtained by heat treating a magnesium compound represented by the general formula: MgX2.nH2O where X represents a halogen atom and n is an integer of 1 to 12, and to a method of producing an olefinic polymer using the catalyst. In the case where the above solid catalyst for olefin polymerization is used, catalyst activity, particularly activity per solid catalyst, is high. Therefore, a deashing treatment step such as catalyst removal can be omitted. Further, the olefinic polymer produced has a narrow molecular weight distribution, and in the case of a copolymer, its monomer composition is uniform.
摘要:
A linear motor coil includes a first coil portion, a second coil portion, the first coil portion and the second coil portion being arranged across a partition wall, a first connecting portion provided between the first coil portion and the second coil portion and by means of which the conductive wire crosses to the first coil portion from the second coil portion while a winding direction of the conductive wire is reversed, and a second connecting portion by means of which the conductive wire crosses to the second coil portion from the first coil portion while the winding direction of the conductive wire is reversed. The conductive wire is formed by a single wire and of which a winding start point and a winding end point are provided at an end portion of the first coil portion at a side opposite from a side where the partition wall is provided.
摘要:
A metallocene compound may be used as a catalyst component for the polymerization of olefins. The compound is stable to air and moisture so that it generates no hydrogen halide by hydrolysis and is easily handled, and it has high storage stability and high catalyst activity. Specifically, the catalyst component for the polymerization of olefins comprises a transition metal composition represented by the general formula [1] and [2]: (RaCp)m(R′bCp)M(—X—Ar—Yc)4−(m+n) [1] R″(RdCp)(R′eCp)M(—X—Ar—Yc)2 [2] wherein M is Ti, Zr or Hf; each of (RaCp), (R′b Cp), (Rd Cp) and (R″e Cp) is a radical having the cyclopentadienyl skeleton; R″ is a radical that links (Rd Cp) and (R′e Cp); (—X—Ar—Yc) is a grouping in which the aromatic ring Ar substituted by a specified radical Y bonds to M through an oxygen or sulphur atom X.
摘要:
An electrically operated hydraulic pump having a pump portion and a motor portion includes rotation controlling means controlling rotation of a rotor, first rotor position detecting means detecting rotational position of the rotor on the basis of speed electromotive force induced by exciting coils, second rotor position detecting means detecting the rotational position of the rotor on the basis of magnetic field of a magnet provided at the motor portion, and motor operating condition detecting means detecting operating condition of the motor portion. The rotation controlling means switches a first rotation controlling based on the rotational position of the rotor detected by the first rotor position detecting means, and a second rotation controlling based on the rotational position of the rotor detected by the second rotor position detecting means, on the basis of a result detected by the motor operating condition detecting means.
摘要:
An electromagnetic valve comprises a first yoke member having an approximately cylindrical shape, a second yoke member having an approximately cylindrical shape and being disposed so as to be opposite to the first yoke member, a bobbin being molded by resin so as to surround the first yoke member and the second yoke member and being integral with the first yoke member and the second yoke member, a plunger being fitted into the first yoke member and the second yoke member so as to be movable in the axial direction, a valve member being moved by the plunger, and a plug member disposed between the opposite surfaces of the first and second yoke members.
摘要:
An electrically operated hydraulic pump having a pump portion and a motor portion includes rotation controlling means controlling rotation of a rotor, first rotor position detecting means detecting rotational position of the rotor on the basis of speed electromotive force induced by exciting coils, second rotor position detecting means detecting the rotational position of the rotor on the basis of magnetic field of a magnet provided at the motor portion, and motor operating condition detecting means detecting operating condition of the motor portion. The rotation controlling means switches a first rotation controlling based on the rotational position of the rotor detected by the first rotor position detecting means, and a second rotation controlling based on the rotational position of the rotor detected by the second rotor position detecting means, on the basis of a result detected by the motor operating condition detecting means.
摘要:
A roller dice device includes a pair of rolling rollers respectively including circumferential rolling grooves formed at outer circumferential surfaces thereof, a supporting portion rotatably supporting the pair of rolling rollers respectively around roller axes extending in parallel with each other, a spaced portion configured by a rolling portion, through which a rolling material moves, and formed by the circumferential rolling grooves facing each other, and a restricting portion formed at the outer circumferential surfaces of the pair of the rolling rollers and restricting displacement of the pair of rolling rollers relative to each other in the axial direction of the roller axes.