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公开(公告)号：US4844724A
公开(公告)日：1989-07-04
申请号：US129287
申请日：1987-12-07
CPC分类号： C03C23/00 , C03B32/00 , C03C21/005 , G02B6/1345
摘要： The refractive index distribution in refractive index distribution lenses may be adjusted to better approach an ideal by heating the refractive index distribution lens. When the refractive index distribution lens was created by diffusion of refractive index changing ions into a body, further heating in an environment in which no additional ions can diffuse into the body causes further migration of ions within the body so that its refractive index distribution approaches an ideal.
摘要翻译： 可以通过加热折射率分布透镜来调节折射率分布透镜中的折射率分布以更好地接近理想。 当折射率分布透镜由折射率变化的离子扩散到体内而产生时，在没有其他离子可以扩散到体内的环境中的进一步加热导致体内离子的进一步迁移使其折射率分布接近 理想。
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公开(公告)号：US4902330A
公开(公告)日：1990-02-20
申请号：US228780
申请日：1988-08-04
CPC分类号： C03C21/001 , C03C21/005 , Y10S359/90
摘要： A method of producing a gradient-index lens includes a first step in which a glass body is immersed into a molten salt containing ions which are able to provide a refractive index higher than that of ions constituting the glass body, in order to perform ion diffusion into the glass body. Thereafter, in a second step the glass body obtained from the first step is immersed into a molten salt containing ions which provide a refractive index lower than that of the ions of the molten salt used in the first step. In this way there is formed a predetermined refractive index distribution in the glass body.
摘要翻译： 制造梯度折射率透镜的方法包括：第一步骤，其中将玻璃体浸入含能够提供折射率高于构成玻璃体的离子的离子的熔盐中，以进行离子扩散 进入玻璃体。 此后，在第二步骤中，将从第一步骤获得的玻璃体浸入含有离子的熔盐中，所述离子的折射率低于第一步骤中使用的熔融盐的离子的折射率。 以这种方式，在玻璃体中形成预定的折射率分布。
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3.发明授权Gradient refractive index type anamorphic planar microlens and method of producing the same 失效梯度折射率型变形平面微透镜及其制造方法
公开(公告)号：US4805997A
公开(公告)日：1989-02-21
申请号：US868696
申请日：1986-05-30
CPC分类号： G02B13/08 , G02B3/0087 , G02B6/4206
摘要： The present invention provides a gradient refractive index type anamorphic planar microlens which can be utilized for collimating an elliptical beam radiated from a semiconductor laser, or the like, and a method of producing such a lens. To collimate light rays, in which astigmatism exists, it is necessary to use a lens in which the respective focal distances in the directions perpendicular to an optical axis are different from each other. It includes a semiellipsoidal refractive index distribution region formed in a transparent substrate so as to have a major axis and a minor axis on a surface of the transparent substrate.
摘要翻译： 本发明提供了可用于校准从半导体激光器辐射的椭圆形光束等的梯度折射率型变形平面微透镜，以及制造这种透镜的方法。 为了准直存在散光的光线，需要使用其中在与光轴垂直的方向上的各个焦距彼此不同的透镜。 它包括半透明折射率分布区域，形成在透明基板中，以在透明基板的表面上具有长轴和短轴。
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4.发明授权Process for producing transparent glass product having refractive index gradient 失效具有折射率梯度的透明玻璃制品的制造方法
公开(公告)号：US4767435A
公开(公告)日：1988-08-30
申请号：US937468
申请日：1986-12-02
申请人： Shigeaki Omi , Yoshiyuki Asahara , Seiichi Shingaki , Shin Nakayama , Kenji Nakagawa , Tetsuro Izumitani , Hiroyuki Sakai
发明人： Shigeaki Omi , Yoshiyuki Asahara , Seiichi Shingaki , Shin Nakayama , Kenji Nakagawa , Tetsuro Izumitani , Hiroyuki Sakai
IPC分类号： C03B8/00 , C03B20/00 , C03B37/014 , C03C3/06 , C03C21/00 , C03C23/00 , G02B6/00 , C03C15/00 , C03C17/00 , C03C25/00
CPC分类号： C03C23/0095 , Y10S65/90
摘要： A process for producing a transparent glass product having a refractive index gradient by the molecular stuffing method is described. A thallium compound is used as a dopant and, after a concentration gradient of the thallium dopant is formed, the porous glass product is heated up to the temperature region of 350.degree. to 550.degree. C. at a temperature-rising rate of 25.degree. to 150.degree. C./hour in a reducing gas atmosphere and then heat treated above 550.degree. C. in an inert gas atmosphere to collapse micropores in the porous glass product, thereby obtaining a glass product having a refractive index gradient which is transparent and free of light-scattering and coloration. The glass product is suitable as materials (preforms) for optical fibers or materials for rod-shaped lenses, particularly rod-shaped microlenses for microlens arrays and microlenses for coupling an optical fiber and a light source.
摘要翻译： 描述了通过分子填充方法制造具有折射率梯度的透明玻璃制品的方法。 使用铊化合物作为掺杂剂，并且在形成铊掺杂剂的浓度梯度之后，将多孔玻璃产物以25℃至25℃的升温速率加热到350℃至550℃的温度区域 150℃/小时，然后在惰性气体气氛中在550℃以上进行热处理，使多孔玻璃制品中的微孔塌陷，得到折射率梯度为透明且无 光散射和着色。 玻璃制品适用于用于光纤的材料（预型件）或用于棒状透镜的材料，特别是用于微透镜阵列的棒状微透镜和用于耦合光纤和光源的微透镜。
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5.发明授权Lenses having plural contiguous refractive index distribution substrates and method of manufacture 失效具有多个相邻的折射率分布基板的透镜及其制造方法
公开(公告)号：US4844589A
公开(公告)日：1989-07-04
申请号：US166812
申请日：1988-02-29
CPC分类号： G02B3/005 , G02B3/0056 , G02B3/0087 , G02B6/1245 , G02B6/4206 , G02B2006/1218 , G02B2006/12188
摘要： Refractive index distribution lenses may be made by forming refractive index distribution patterns in surfaces of two substrates. The patterns in the two substrates are made to be matching. Then, these surfaces of the two substrates are placed together with the patterns in the substrates coinciding. If the refractive index distribution patterns in the surfaces form semicylindrical lenses with parallel axes, the substrates may be put together so that the axes of the lenses in one substrate coincide with corresponding axes of semicylindrical lenses in the other substrate to form a rod lens array. If the refractive index distribution patterns in the two substrates are constant in directions parallel to the surfaces of these substrates but vary in the direction perpendicular to the surfaces, the surfaces of these substrates may be put together to form a slab lens.
摘要翻译： 折射率分布透镜可以通过在两个基板的表面中形成折射率分布图案来制造。 使两个基板中的图案相匹配。 然后，将这两个基板的这些表面放置在一起，使基板中的图案重合。 如果表面中的折射率分布图形成具有平行轴的半圆柱形透镜，则可以将基板放置在一起，使得一个基板中的透镜的轴线与另一个基板中的半圆柱形透镜的相应轴线重合以形成棒状透镜阵列。 如果两个基板中的折射率分布图案在平行于这些基板的表面的方向上是恒定的，但是在垂直于表面的方向上变化，则这些基板的表面可以放在一起以形成平板透镜。
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公开(公告)号：US5122178A
公开(公告)日：1992-06-16
申请号：US557745
申请日：1990-07-26
申请人： Shigeaki Omi , Yoshiyuki Asahara , Shuji Yoshida
发明人： Shigeaki Omi , Yoshiyuki Asahara , Shuji Yoshida
CPC分类号： C03C14/006 , G02B1/02 , G02B13/14 , C03C2214/16 , G02F1/3555
摘要： The present invention relates to a process for producing a glass doped with dispersed microcrystallites, which glass is used as a material for sharp cut filter, a material for infrared-transmitting filter, a nonlinear optical material, etc. In the process, high-melting semiconductor microcrystallites are precipitated at a temperature T.sub.1 which is lower than the sag point of a glass to be produced but not lower than the transition temperature of the glass, and then low-melting semiconductor microcrystallites are precipitated at a temperature T.sub.2 which is not higher than the flow point of the glass but not lower than the sag point of the glass to obtain a glass comprising a matrix and microcrystallites of semiconductor solid solution of multilayer structure dispersed in said matrix. This glass has solved, owing to the multilayer structure of the microcrystallites of semiconductor solid solution, the problem of conventional glasses doped with dispersed microcrystallites that the emission from the band edge of microcrystallites of semiconductor solid solution is hidden by the emission from the surface trap level.
摘要翻译： 本发明涉及一种掺杂有分散微晶的玻璃的制造方法，该玻璃用作锋利切割过滤器的材料，红外线透过滤材料，非线性光学材料等。在该方法中，高熔点 半导体微晶在比要制造的玻璃的下垂点低但不低于玻璃的转变温度的温度T1下沉淀，然后低温半导体微晶在不高于 玻璃的流动点，但不低于玻璃的下垂点，以获得包含基体的玻璃和分散在所述基体中的多层结构的半导体固溶体的微晶。 由于半导体固溶体的微晶的多层结构，由于半导体固溶体的微晶的边缘的发射被表面捕获水平的发射所掩盖，因此，由于半导体固溶体的微晶的多层结构，掺杂有分散微晶的问题 。
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公开(公告)号：US5043003A
公开(公告)日：1991-08-27
申请号：US489108
申请日：1990-03-06
申请人： Shigeaki Omi , Shuji Yoshida , Yoshiyuki Asahara
发明人： Shigeaki Omi , Shuji Yoshida , Yoshiyuki Asahara
CPC分类号： C03C14/006 , C03C2214/16 , Y10S65/15
摘要： The present invention relates to a process for producing a glass doped with dispersed microcrystallites, said process comprises:a first step of cooling a glas melt comprising a component to become a glass matrix and a component to become microcrystallites dispersed in said matrix, to a temperature T which is not higher than the flow point of the glass but not lower than the sag point of the glass, anda second step of maintaining the cooled glass at the temperature T to precipitate microcrytallites in the matrix.The glass doped with dispersed microcrystallites produced is used as a material for sharp cut filter, a material for infrared-transmitting filter, a nonlinear optical material, etc.
摘要翻译： 本发明涉及一种掺杂有分散的微晶的玻璃的制造方法，所述方法包括：将包含组分的玻璃熔体的玻璃熔体和分散在所述基质中的微晶的组分冷却至温度的第一步骤 T不高于玻璃的流动点但不低于玻璃的下垂点，以及将冷却的玻璃保持在温度T的第二步骤，以沉淀基质中的微辉石。 掺杂有分散的微晶的玻璃被用作锋利切割过滤器，红外透射滤光器材料，非线性光学材料等的材料。
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8.发明授权Method of making multi-component glass doped with cadmium chalcogenide microparticles 失效制造掺杂硫酸镉微粒的多组分玻璃的方法
公开(公告)号：US5098460A
公开(公告)日：1992-03-24
申请号：US574754
申请日：1990-08-30
申请人： Shigeaki Omi , Shuji Yoshida
发明人： Shigeaki Omi , Shuji Yoshida
CPC分类号： C03C14/006 , G02F1/3555 , C03C2214/16 , C03C2214/30 , Y10S65/15
摘要： A multi-component glass doped with microparticles of CdS.sub.x Se.sub.y Te.sub.z, which can be used as a material for sharp cut filter, a material for infrared-transmitting filter or a nonlinear optical material. This glass has solved the problems of conventional glasses doped with microparticles, of (a) being low in microparticles concentration and accordingly having a low spectral characteristic when made into a thin filter and (b) being low in microparticles concentration and accordingly having low third-order nonlinearity, by containing microparticles at a high concentration, i.e. 5-50% by weight. The present invention relates to a process for producing the above multi-component glass doped with CdS.sub.x Se.sub.y Te.sub.z microparticles. This has solved the conventional problems that the chalcogen element(s) to constitute the microparticles is (are) vaporized at the step for obtaining a glass melt, by specifying (a) the material to become a glass matrix and (b) the atmosphere used for obtaining a glass melt.
摘要翻译： 掺杂有CdSx SeyTez的微粒的多组分玻璃，其可以用作锋利切割过滤器的材料，用于红外透射过滤器的材料或非线性光学材料。 该玻璃已经解决了掺杂有微粒的常规玻璃的问题，（a）微细颗粒浓度低，并且因此在制成薄过滤器时具有低光谱特性，和（b）微粒浓度低，因此具有低的第三 - 通过含有高浓度的微粒，即5-50重量％的微粒来订购非线性。 本发明涉及一种制备掺杂有CdSx Sey Tez微粒的上述多组分玻璃的方法。 这解决了通过规定（a）成为玻璃基质的材料和（b）所使用的气氛，在获得玻璃熔体的步骤中，构成微粒的硫属元素被蒸发的常规问题 用于获得玻璃熔体。
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公开(公告)号：US5162054A
公开(公告)日：1992-11-10
申请号：US814608
申请日：1991-12-30
申请人： Shigeaki Omi
发明人： Shigeaki Omi
CPC分类号： C03C14/006 , G02F1/3555 , C03C2214/16 , C03C2214/30 , Y10S65/15
摘要： The method involves producing a multi-component glass doped with CdS.sub.x Se.sub.y Te.sub.z microparticles. The process has solved the conventional problems that the chalcogen element(s) to constitute the microparticles is (are) vaporized at the step for obtaining a glass melt, by specifying (a) the material to become a glass matrix and (b) the atmosphere used for obtaining a glass melt. The method involves using a mixture of elemental Cd and at least one of the elements S, Se and Te.
摘要翻译： 该方法涉及制备掺杂有CdSx Sey Tez微粒的多组分玻璃。 该方法解决了通过规定（a）成为玻璃基体的材料和（b）大气的常规问题，构成微粒的硫属元素在用于获得玻璃熔体的步骤中被汽化 用于获得玻璃熔体。 该方法包括使用元素Cd和元素S，Se和Te中的至少一种的混合物。
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10.发明授权
公开(公告)号：US5134095A
公开(公告)日：1992-07-28
申请号：US714173
申请日：1991-06-14
申请人： Shigeaki Omi , Katsuaki Uchida
发明人： Shigeaki Omi , Katsuaki Uchida
CPC分类号： C03C14/006 , C03C2214/16
摘要： The present invention relates to a matrix glass composition for glass doped with dispersed CdS.sub.x Se.sub.y Te.sub.z (x+y+z=1) microcrystallites, which contains P.sub.2 O.sub.5 and/or B.sub.2 O.sub.3, and ZnO and/or CdO as essential constituent components, in which the total amount of P.sub.2 O.sub.5 and B.sub.2 O.sub.3 is in a range of from 35 to 65 mol %, and the total amount of ZnO and CdO is in a range of from 65 to 25 mol %. The present invention relates also to glass doped with dispersed microcrystallites which comprises a matrix glass composition as defined above as matrix glass, and CdS.sub.x Se.sub.y Te.sub.z (x+y+z=1) microcrystallites precipitated in the matrix glass.
摘要翻译： 本发明涉及掺杂有分散的CdSxSeyTez（x + y + z = 1）微晶的玻璃的玻璃基体玻璃组合物，其包含P 2 O 5和/或B 2 O 3，以及ZnO和/或CdO作为必需组分，其中总量 的P 2 O 5和B 2 O 3在35〜65摩尔％的范围内，ZnO和CdO的总量在65〜25摩尔％的范围内。 本发明还涉及掺杂有分散的微晶的玻璃，其包含如上面定义为基质玻璃的基质玻璃组合物，以及沉淀在基体玻璃中的CdSxSeyTez（x + y + z = 1）微晶。
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