摘要:
An object is to provide a nonaqueous electrolyte and a nonaqueous-electrolyte secondary battery which have excellent discharge load characteristics and are excellent in high-temperature storability, cycle characteristics, high capacity, continuous-charge characteristics, storability, gas evolution inhibition during continuous charge, high-current-density charge/discharge characteristics, discharge load characteristics, etc. The object has been accomplished with a nonaqueous electrolyte which comprises: a monofluorophosphate and/or a difluorophosphate; and further a compound having a specific chemical structure or specific properties.
摘要:
An object is to provide a nonaqueous electrolyte and a nonaqueous-electrolyte secondary battery which have excellent discharge load characteristics and are excellent in high-temperature storability, cycle characteristics, high capacity, continuous-charge characteristics, storability, gas evolution inhibition during continuous charge, high-current-density charge/discharge characteristics, discharge load characteristics, etc. The object has been accomplished with a nonaqueous electrolyte which comprises: a monofluorophosphate and/or a difluorophosphate; and further a compound having a specific chemical structure or specific properties.
摘要:
A nonaqueous electrolyte containing a monofluorophosphate and/or a difluorophosphate and a compound having a specific chemical structure or specific properties. The nonaqueous electrolyte can contain at least one of a saturated chain hydrocarbon, a saturated cyclic hydrocarbon, an aromatic compound having a halogen atom and an ether having a fluorine atom.
摘要:
A non-aqueous electrolyte solution is provided that realizes a large capacity, exhibits high storage characteristics and cycle characteristics, and is capable of inhibiting gas generation.The non-aqueous electrolyte solution comprises a lithium salt and a non-aqueous solvent, and further comprises: a cyclic carbonate compound having an unsaturated bond in a concentration of 0.01 weight % or higher and 8 weight % or lower; and a compound expressed by general formula (Ia) in a concentration of 0.01 weight % or higher and 5 weight % or lower. (in the formula (Ia), R11 and R12 represent, independently of each other, an organic group that is composed of one or more carbon atoms and hydrogen atoms and may optionally contain one or more oxygen atoms but excludes unsaturated bonds, provided that at least either R11 or R12 has an ether linkage. The total number of carbon atoms of R11 and R12 is between 3 and 18, and the total number of oxygen atoms contained in R11 and R12 is between 1 and 6.)
摘要:
A non-aqueous electrolyte solution is provided that realizes a large capacity, exhibits high storage characteristics and cycle characteristics, and is capable of inhibiting gas generation.The non-aqueous electrolyte solution comprises a lithium salt and a non-aqueous solvent, and further comprises: a cyclic carbonate compound having an unsaturated bond in a concentration of 0.01 weight % or higher and 8 weight % or lower; and a compound expressed by general formula (Ia) in a concentration of 0.01 weight % or higher and 5 weight % or lower. (in the formula (Ia), R11 and R12 represent, independently of each other, an organic group that is composed of one or more carbon atoms and hydrogen atoms and may optionally contain one or more oxygen atoms but excludes unsaturated bonds, provided that at least either R11 or R12 has an ether linkage. The total number of carbon atoms of R11 and R12 is between 3 and 18, and the total number of oxygen atoms contained in R11 and R12 is between 1 and 6.)
摘要:
Nonaqueous electrolytes which can produce a battery of high capacity and excellent storability and cycle characteristics are provided, as are batteries produced with the electrolytes. The electrolytes include ones with (i) an aromatic compound having 7-18 carbon atoms in total and a fluorinated cyclic carbonate having two or more fluorine atoms, (ii) diethyl carbonate and a fluorinated cyclic carbonate having two or more fluorine atoms, (iii) at least one of a cyclic sulfonic acid ester compound, disulfonic acid ester compound, nitrile compound, and a compound of formula (1) and a fluorinated cyclic carbonate having two or more fluorine atoms, or (iv) a nonaqueous electrolyte solution for use in a high-voltage battery having a final charge voltage of 4.3 V or higher and having a fluorinated cyclic carbonate with two or more fluorine atoms.
摘要:
Disclosed is a nonaqueous electrolytic solution which enables formation of a nonaqueous-electrolyte battery having high capacity and excellent storage characteristics at high temperatures, while sufficiently enhancing safety at the time of overcharge. A nonaqueous-electrolyte battery produced by using the nonaqueous electrolytic solution is also disclosed. The nonaqueous electrolytic solution comprises an electrolyte and a nonaqueous solvent, and includes any of specific nonaqueous electrolytic solutions (A) to (D).
摘要:
Provided is a lithium secondary battery having a nonaqueous electrolyte which contains at least one compound selected from the group consisting of monofluorophosphoric acid salts, and difluorophosphoric acid salts, in an amount of 10 ppm or more of the whole nonaqueous electrolyte, and a negative electrode selected from [1], [2], [3] and [6]: [1]: a negative electrode containing two or more carbonaceous substances differing in crystallinity; [2]: a negative electrode containing an amorphous carbonaceous substance which, when examined by wide-angle X-ray diffractometry, has an interplanar spacing (d002) for the (002) planes of 0.337 nm or larger and a crystallite size (Lc) of 80 nm or smaller and which, in an examination by argon ion laser Raman spectroscopy, has a Raman. R value of 0.2 or higher defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1; [3]: a negative-electrode active material a titanium-containing metal oxide capable of occluding and releasing lithium; [6]: as a negative-electrode active material, graphitic carbon particles which have a roundness of 0.85 or higher and an interplanar spacing (d002) for the (002) planes of smaller than 0.337 nm as determined by wide-angle X-ray diffractometry and which, in an examination by argon ion laser Raman spectroscopy, have a Raman R value of from 0.12 to 0.8 defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1.
摘要:
Provided is a lithium secondary battery having a nonaqueous electrolyte which contains at least one compound selected from the group consisting of monofluorophosphoric acid salts; and difluorophosphoric acid salts, in an amount of 10 ppm or more of the whole nonaqueous electrolyte, and a negative electrode selected from [1], [2], [3] and [6]: [1]: a negative electrode containing two or more carbonaceous substances differing in crystallinity; [2]: a negative electrode containing an amorphous carbonaceous substance which, when examined by wide-angle X-ray diffractometry, has an interplanar spacing (d002) for the (002) planes of 0.337 nm or larger and a crystallite size (Lc) of 80 nm or smaller and which, in an examination by argon ion laser Raman spectroscopy, has a Raman. R value of 0.2 or higher defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1; [3]: a negative-electrode active material a titanium-containing metal oxide capable of occluding and releasing lithium; [6]: as a negative-electrode active material, graphitic carbon particles which have a roundness of 0.85 or higher and an interplanar spacing (d002) for the (002) planes of smaller than 0.337 nm as determined by wide-angle X-ray diffractometry and which, in an examination by argon ion laser Raman spectroscopy, have a Raman R value of from 0.12 to 0.8 defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1.
摘要:
A lithium secondary battery comprising a battery case and an electrode group is provided. The electrode group comprises a positive electrode, a negative electrode, a microporous film separator and a nonaqueous electrolyte comprising a lithium salt. The electrode group and the nonaqueous electrolyte are held in the battery case and the electrodes each comprise a current collector and an active-material layer containing an active material capable of occluding/releasing a lithium ion. The nonaqueous electrolyte comprises a difluorophosphoric acid salt in an amount of 10 ppm or more of the whole nonaqueous electrolyte. The battery case comprises a casing material in which at least part of the battery inner side comprises a sheet formed from a thermoplastic resin and with which the electrode group can be enclosed by placing the electrode group in the casing material and heat sealing layers of the thermoplastic resin to each other.