NONAQUEOUS ELECTROLYTE SOLUTION AND LITHIUM SECONDARY BATTERY USING SAME
    4.
    发明申请
    NONAQUEOUS ELECTROLYTE SOLUTION AND LITHIUM SECONDARY BATTERY USING SAME 有权
    非电解电解液和锂二次电池使用相同

    公开(公告)号:US20120244426A1

    公开(公告)日:2012-09-27

    申请号:US13489038

    申请日:2012-06-05

    IPC分类号: H01M10/26

    摘要: A non-aqueous electrolyte solution is provided that realizes a large capacity, exhibits high storage characteristics and cycle characteristics, and is capable of inhibiting gas generation.The non-aqueous electrolyte solution comprises a lithium salt and a non-aqueous solvent, and further comprises: a cyclic carbonate compound having an unsaturated bond in a concentration of 0.01 weight % or higher and 8 weight % or lower; and a compound expressed by general formula (Ia) in a concentration of 0.01 weight % or higher and 5 weight % or lower. (in the formula (Ia), R11 and R12 represent, independently of each other, an organic group that is composed of one or more carbon atoms and hydrogen atoms and may optionally contain one or more oxygen atoms but excludes unsaturated bonds, provided that at least either R11 or R12 has an ether linkage. The total number of carbon atoms of R11 and R12 is between 3 and 18, and the total number of oxygen atoms contained in R11 and R12 is between 1 and 6.)

    摘要翻译: 提供了一种实现大容量的非水电解质溶液,具有高储存特性和循环特性,并且能够抑制气体产生。 非水电解质溶液包含锂盐和非水溶剂,并且还包含:具有浓度为0.01重量%以上且8重量%以下的不饱和键的环状碳酸酯化合物; 和由通式(Ia)表示的浓度为0.01重量%以上且5重量%以下的化合物。 (式(Ia)中,R 11和R 12彼此独立地表示由一个或多个碳原子和氢原子组成的有机基团,并且可以任选地含有一个或多个氧原子,但不包括不饱和键,条件是在 R11和R12中的至少一个具有醚键,R11和R12的总碳原子数在3和18之间,R11和R12中所含的氧原子总数在1和6之间)

    NONAQUEOUS ELECTROLYTIC SOLUTIONS AND NONAQUEOUS-ELECTROLYTE BATTERIES
    6.
    发明申请
    NONAQUEOUS ELECTROLYTIC SOLUTIONS AND NONAQUEOUS-ELECTROLYTE BATTERIES 有权
    非电解电解液和非电解电池

    公开(公告)号:US20120115042A1

    公开(公告)日:2012-05-10

    申请号:US13353803

    申请日:2012-01-19

    IPC分类号: H01M10/0569

    摘要: Nonaqueous electrolytes which can produce a battery of high capacity and excellent storability and cycle characteristics are provided, as are batteries produced with the electrolytes. The electrolytes include ones with (i) an aromatic compound having 7-18 carbon atoms in total and a fluorinated cyclic carbonate having two or more fluorine atoms, (ii) diethyl carbonate and a fluorinated cyclic carbonate having two or more fluorine atoms, (iii) at least one of a cyclic sulfonic acid ester compound, disulfonic acid ester compound, nitrile compound, and a compound of formula (1) and a fluorinated cyclic carbonate having two or more fluorine atoms, or (iv) a nonaqueous electrolyte solution for use in a high-voltage battery having a final charge voltage of 4.3 V or higher and having a fluorinated cyclic carbonate with two or more fluorine atoms.

    摘要翻译: 提供了可以生产高容量电池和优异的储存性和循环特性的非水电解质,电解质产生的电池也是如此。 电解质包括(i)总共具有7-18个碳原子的芳族化合物和具有两个或更多个氟原子的氟化环状碳酸酯,(ii)碳酸二乙酯和具有两个或更多个氟原子的氟化环状碳酸酯的(i) )环状磺酸酯化合物,二磺酸酯化合物,腈化合物和式(1)化合物中的至少一种和具有两个或更多个氟原子的氟化环状碳酸酯,或(iv)使用的非水电解质溶液 在具有4.3V或更高的最终充电电压的高压电池中,并具有具有两个或更多个氟原子的氟化环状碳酸酯。

    LITHIUM SECONDARY BATTERIES AND NONAQUEOUS ELECTROLYTE FOR USE IN THE SAME
    9.
    发明申请
    LITHIUM SECONDARY BATTERIES AND NONAQUEOUS ELECTROLYTE FOR USE IN THE SAME 审中-公开
    锂二次电池和非电解电解质用于同一电池

    公开(公告)号:US20170040593A1

    公开(公告)日:2017-02-09

    申请号:US15291314

    申请日:2016-10-12

    摘要: Provided is a lithium secondary battery having a nonaqueous electrolyte which contains at least one compound selected from the group consisting of monofluorophosphoric acid salts; and difluorophosphoric acid salts, in an amount of 10 ppm or more of the whole nonaqueous electrolyte, and a negative electrode selected from [1], [2], [3] and [6]: [1]: a negative electrode containing two or more carbonaceous substances differing in crystallinity; [2]: a negative electrode containing an amorphous carbonaceous substance which, when examined by wide-angle X-ray diffractometry, has an interplanar spacing (d002) for the (002) planes of 0.337 nm or larger and a crystallite size (Lc) of 80 nm or smaller and which, in an examination by argon ion laser Raman spectroscopy, has a Raman. R value of 0.2 or higher defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1; [3]: a negative-electrode active material a titanium-containing metal oxide capable of occluding and releasing lithium; [6]: as a negative-electrode active material, graphitic carbon particles which have a roundness of 0.85 or higher and an interplanar spacing (d002) for the (002) planes of smaller than 0.337 nm as determined by wide-angle X-ray diffractometry and which, in an examination by argon ion laser Raman spectroscopy, have a Raman R value of from 0.12 to 0.8 defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1.

    摘要翻译: 一种锂二次电池,包括:正极和负极,它们各自具有特定的组成和特定性能; 和含有通式(1)表示的环状硅氧烷化合物,通式(2)表示的氟硅烷化合物,通式(3)表示的化合物,分子中具有SF键的化合物,硝酸盐, 亚硝酸盐,单氟磷酸盐,二氟磷酸盐,乙酸盐或丙酸盐,其量为全部非水电解质的10ppm以上。 该锂二次电池具有容量大,寿命长,输出高的特点。 [通式(1)中,R 1和R 2为碳原子数1〜12的有机基团,n为3-10的整数。 通式(2)中,R 3〜R 5为具有1-12个碳原子的有机基团, x是1-3的整数; 并且p,q和r各自为0-3的整数,条件是1‰p + q + r‰3.在通式(3)中,R 6至R 8为具有1-12个碳原子的有机基团 符号A是由H,C,N,O,F,S,Si和/或P构成的基团。