公开(公告)号：US20120270107A1

公开(公告)日：2012-10-25

申请号：US13513244

申请日：2010-12-02

申请人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

发明人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

IPC分类号： H01M4/131

CPC分类号： H01M4/505 ,  C01G53/00 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/525 ,  H01M10/052 ,  Y02T10/7011

摘要： An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same.[Solution]A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.

摘要翻译： 本发明的目的是提供具有小粒径和均匀粒度分布的镍钴锰复合氢氧化物颗粒及其制造方法。 [解决方案]提供了通过结晶反应制造镍钴锰复合氢氧化物的方法。 该方法包括：通过将包含镍，钴和锰的金属化合物和铵离子给体的成核水溶液的pH控制在液体温度下测定的pH为12.0〜14.0，进行成核的成核步骤 以25℃为标准; 以及通过将含有在成核步骤中形成的核的颗粒生长用水溶液的pH控制为在液体温度25℃下测定的pH为10.5〜12.0的粒子生长工序。

公开(公告)号：US09954224B2

公开(公告)日：2018-04-24

申请号：US13513244

申请日：2010-12-02

申请人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

发明人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

IPC分类号： H01M4/505 ,  H01M4/525 ,  H01M4/131 ,  C01G53/00 ,  H01M10/052

CPC分类号： H01M4/505 ,  C01G53/00 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/525 ,  H01M10/052 ,  Y02T10/7011

摘要： An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same.[Solution]A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.

公开(公告)号：US08486564B2

公开(公告)日：2013-07-16

申请号：US13618526

申请日：2012-09-14

申请人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

发明人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

IPC分类号： H01M4/13

CPC分类号： H01M4/366 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/16 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/021 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： Active material particles are provided that exhibit performance suitable for increasing the output of a lithium secondary battery and little deterioration due to charge-discharge cycling. The active material particles provided by the present invention have a hollow structure having secondary particles including an aggregate of a plurality of primary particles of a lithium transition metal oxide, and a hollow portion formed inside the secondary particles, and through holes that penetrates to the hollow portion from the outside are formed in the secondary particles. BET specific surface area of the active material particles is 0.5 to 1.9 m2/g.

摘要翻译： 提供活性物质颗粒，其表现出适合于增加锂二次电池的输出并且由于充放电循环而导致的劣化。 由本发明提供的活性物质颗粒具有中空结构，其具有二次粒子，其具有多个锂过渡金属氧化物的一次粒子的聚集体和形成在二次粒子内部的中空部分，以及穿透到中空部的通孔 从二次颗粒形成从外部的部分。 活性物质粒子的BET比表面积为0.5〜1.9m 2 / g。

公开(公告)号：US20130302687A1

公开(公告)日：2013-11-14

申请号：US13941253

申请日：2013-07-12

申请人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

发明人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

IPC分类号： H01M4/36 ,  H01M4/525

CPC分类号： H01M4/366 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/16 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/021 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： Active material particles are provided that exhibit performance suitable for increasing the output of a lithium secondary battery and little deterioration due to charge-discharge cycling. The active material particles provided by the present invention have a hollow structure having secondary particles including an aggregate of a plurality of primary particles of a lithium transition metal oxide, and a hollow portion formed inside the secondary particles, and through holes that penetrates to the hollow portion from the outside are formed in the secondary particles. BET specific surface area of the active material particles is 0.5 to 1.9 m2/g.

公开(公告)号：US20120282525A1

公开(公告)日：2012-11-08

申请号：US13513209

申请日：2010-10-07

申请人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

发明人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

IPC分类号： H01M4/525

CPC分类号： H01M4/366 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/16 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/021 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： Active material particles are provided that exhibit performance suitable for increasing the output of a lithium secondary battery and little deterioration due to charge-discharge cycling. The active material particles provided by the present invention have a hollow structure having secondary particles including an aggregate of a plurality of primary particles of a lithium transition metal oxide, and a hollow portion formed inside the secondary particles, and through holes that penetrates to the hollow portion from the outside are formed in the secondary particles. BET specific surface area of the active material particles is 0.5 to 1.9 m2/g.

摘要翻译： 提供活性物质颗粒，其表现出适合于增加锂二次电池的输出并且由于充放电循环而导致的劣化。 由本发明提供的活性物质颗粒具有中空结构，其具有二次粒子，其具有多个锂过渡金属氧化物的一次粒子的聚集体和形成在二次粒子内部的中空部分，以及穿透到中空部的通孔 从二次颗粒形成从外部的部分。 活性物质粒子的BET比表面积为0.5〜1.9m 2 / g。

公开(公告)号：US20140011090A1

公开(公告)日：2014-01-09

申请号：US13820110

申请日：2011-03-28

申请人： Hiroyuki Toya ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako

发明人： Hiroyuki Toya ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako

IPC分类号： C30B7/14 ,  H01M10/0525 ,  H01M4/525 ,  H01M4/04 ,  H01M4/36 ,  H01M4/505

CPC分类号： C30B7/14 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/34 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/40 ,  H01M4/0471 ,  H01M4/0497 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  Y10T428/2982

摘要： Provided are nickel manganese composite hydroxide particles having a small and uniform particle size and having a double structure which enables to obtain a cathode active material having a hollow structure, and a manufacturing method thereof. When obtaining the nickel manganese composite hydroxide by a reaction crystallization, using an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel, a metallic compound that contains manganese and an ammonium ion donor and controlling the pH value that is measured at a standard solution temperature of 25° C. is 10.5 to 12.0, nucleation is performed in an oxidizing atmosphere in which the oxygen concentration is greater than 1% by volume, and then nuclei are grown by switching the atmosphere from the oxidizing atmosphere to a mixed atmosphere of oxygen and inert gas in which the oxygen concentration is 1% by volume or less.

摘要翻译： 提供具有小而均匀的粒度的镍锰复合氢氧化物颗粒及其制造方法，其具有能够获得具有中空结构的正极活性物质的双重结构。 当通过反应结晶获得镍锰复合氢氧化物时，使用包含至少含有镍的金属化合物的成核水溶液，含有锰和铵离子供体的金属化合物，并控制在 25℃的标准溶液温度为10.5〜12.0，在氧浓度大于1体积％的氧化气氛中进行成核，然后通过将氧化气氛的气氛转换为混合 氧浓度为1体积％以下的氧气和惰性气体。

公开(公告)号：US10017875B2

公开(公告)日：2018-07-10

申请号：US13820110

申请日：2011-03-28

申请人： Hiroyuki Toya ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako

发明人： Hiroyuki Toya ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako

IPC分类号： H01M10/0525 ,  C30B7/14 ,  H01M4/505 ,  H01M4/525 ,  C01G53/00 ,  H01M4/04 ,  H01M4/36

CPC分类号： C30B7/14 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/34 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/40 ,  H01M4/0471 ,  H01M4/0497 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  Y10T428/2982

摘要： Provided are nickel manganese composite hydroxide particles having a small and uniform particle size and having a double structure which enables to obtain a cathode active material having a hollow structure, and a manufacturing method thereof. When obtaining the nickel manganese composite hydroxide by a reaction crystallization, using an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel, a metallic compound that contains manganese and an ammonium ion donor and controlling the pH value that is measured at a standard solution temperature of 25° C. is 10.5 to 12.0, nucleation is performed in an oxidizing atmosphere in which the oxygen concentration is greater than 1% by volume, and then nuclei are grown by switching the atmosphere from the oxidizing atmosphere to a mixed atmosphere of oxygen and inert gas in which the oxygen concentration is 1% by volume or less.

公开(公告)号：US20130189581A1

公开(公告)日：2013-07-25

申请号：US13811465

申请日：2011-04-01

申请人： Shin Imaizumi ,  Rei Kokado ,  Kensaku Mori

发明人： Shin Imaizumi ,  Rei Kokado ,  Kensaku Mori

IPC分类号： H01M4/131

CPC分类号： H01M4/131 ,  C01G23/002 ,  C01G51/42 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/54 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/40 ,  H01M4/525 ,  H01M10/052

摘要： The present invention provides a cathode active material for a nonaqueous electrolyte secondary battery with a high capacity, high stability and excellent output characteristics and a method for producing the same, and a nonaqueous electrolyte secondary battery using the cathode active material.The cathode active material for a nonaqueous electrolyte secondary battery is represented by a general formula: LitNi1.x.y.zCoxAlyTizO2 wherein 0.98≦t≦1.10, 0

摘要翻译： 本发明提供一种具有高容量，高稳定性和优异的输出特性的非水电解质二次电池用正极活性物质及其制造方法以及使用该正极活性物质的非水电解质二次电池。 用于非水电解质二次电池的阴极活性材料由以下通式表示：LitNi1.x.y.zCoxAlyTizO2其中0.98 @ t @ 1.10,0

公开(公告)号：US09559351B2

公开(公告)日：2017-01-31

申请号：US14001722

申请日：2011-03-31

申请人： Kensaku Mori ,  Rei Kokado ,  Shin Imaizumi

发明人： Kensaku Mori ,  Rei Kokado ,  Shin Imaizumi

IPC分类号： H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  C01G53/00 ,  H01M4/04

CPC分类号： H01M4/131 ,  C01G53/006 ,  C01G53/42 ,  C01P2004/03 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/84 ,  C01P2006/12 ,  H01M4/0471 ,  H01M4/0497 ,  H01M4/505 ,  H01M4/525 ,  Y02E60/122 ,  Y02P70/54

摘要： A method for producing nickel composite hydroxide particles may include: a first step of producing nuclei including primary particles by controlling the pH of an aqueous solution for nucleation, the aqueous solution for nucleation containing a metal compound having an atomic ratio of metals corresponding to an atomic ratio of metals in the nickel composite hydroxide particles and substantially not containing a metal complex ion-forming agent; and a second step of forming, on an outer surface of each of the nuclei, an outer shell portion including platy primary particles larger than primary particles of the nuclei by controlling the pH of an aqueous solution for particle growth containing the nuclei obtained in the nucleation step.

摘要翻译： 制造镍复合氢氧化物颗粒的方法可以包括：通过控制成核水溶液的pH来产生包括一次颗粒的核的第一步骤，含有与原子相对应的金属原子比的金属化合物的成核水溶液 镍复合氢氧化物颗粒中的金属比例基本上不含金属络合物离子形成剂; 以及第二步骤，通过控制包含在成核中获得的核的颗粒生长用水溶液的pH，在每个核的外表面上形成包含比原核粒子大的初级粒子的外壳部分 步。

公开(公告)号：US20120276454A1

公开(公告)日：2012-11-01

申请号：US13513240

申请日：2010-12-02

申请人： Kensaku Mori ,  Shin Imaizumi ,  Rei Kokado

发明人： Kensaku Mori ,  Shin Imaizumi ,  Rei Kokado

IPC分类号： H01M4/525 ,  C09K3/00

CPC分类号： H01M4/525 ,  C01G53/00 ,  C01G53/006 ,  C01G53/42 ,  C01G53/50 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/45 ,  C01P2004/51 ,  C01P2004/61 ,  H01M4/485 ,  H01M4/505 ,  Y10T428/2982

摘要： Disclosed are: nickel complex hydroxide particles that have small and uniform particle diameters; and a method by which the nickel complex hydroxide particles can be produced. Specifically disclosed is a method for producing a nickel complex hydroxide by a crystallization reaction, which comprises: a nucleation step in which nucleation is carried out, while controlling an aqueous solution for nucleation containing an ammonium ion supplying material and a metal compound that contains nickel to have a pH of 12.0-13.4 at a liquid temperature of 25° C.; and a particle growth step in which nuclei are grown, while controlling an aqueous solution for particle growth containing the nuclei, which have been formed in the nucleation step, to have a pH of 10.5-12.0 at a liquid temperature of 25° C. In this connection, the pH in the particle growth step is controlled to be less than the pH in the nucleation step.

摘要翻译： 公开了：具有小而均匀粒径的镍复合氢氧化物颗粒; 以及可以制造镍复合氢氧化物颗粒的方法。 具体公开的是通过结晶反应制造镍复合氢氧化物的方法，其包括：成核步骤，其中进行成核，同时控制含有铵离子供给材料的成核水溶液和含有镍的金属化合物 在液温25℃时pH为12.0-13.4。 以及粒子生长步骤，其中在液态温度为25℃的同时控制在成核步骤中形成的包含核的颗粒生长用水溶液的pH为10.5-12.0的细胞核生长。 在这种连接中，将颗粒生长步骤中的pH控制为小于成核步骤中的pH。