公开(公告)号：US20120270107A1

公开(公告)日：2012-10-25

申请号：US13513244

申请日：2010-12-02

申请人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

发明人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

IPC分类号： H01M4/131

CPC分类号： H01M4/505 ,  C01G53/00 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/525 ,  H01M10/052 ,  Y02T10/7011

摘要： An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same.[Solution]A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.

摘要翻译： 本发明的目的是提供具有小粒径和均匀粒度分布的镍钴锰复合氢氧化物颗粒及其制造方法。 [解决方案]提供了通过结晶反应制造镍钴锰复合氢氧化物的方法。 该方法包括：通过将包含镍，钴和锰的金属化合物和铵离子给体的成核水溶液的pH控制在液体温度下测定的pH为12.0〜14.0，进行成核的成核步骤 以25℃为标准; 以及通过将含有在成核步骤中形成的核的颗粒生长用水溶液的pH控制为在液体温度25℃下测定的pH为10.5〜12.0的粒子生长工序。

公开(公告)号：US09954224B2

公开(公告)日：2018-04-24

申请号：US13513244

申请日：2010-12-02

申请人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

发明人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

IPC分类号： H01M4/505 ,  H01M4/525 ,  H01M4/131 ,  C01G53/00 ,  H01M10/052

CPC分类号： H01M4/505 ,  C01G53/00 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/525 ,  H01M10/052 ,  Y02T10/7011

摘要： An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same.[Solution]A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.

公开(公告)号：US10236506B2

公开(公告)日：2019-03-19

申请号：US14123410

申请日：2011-09-02

申请人： Hiroyuki Toya ,  Atsushi Fukui

发明人： Hiroyuki Toya ,  Atsushi Fukui

IPC分类号： H01M4/525 ,  C01G53/00 ,  C01G45/00 ,  C01G51/00 ,  H01M4/505 ,  C01D15/02 ,  H01M4/485 ,  C30B29/22 ,  H01M2/02 ,  H01M2/16 ,  H01M4/131 ,  H01M4/134 ,  H01M4/38 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/0585 ,  H01M4/04 ,  H01M4/1391 ,  H01M4/02

摘要： A tranition metal composite hydroxide can be used as a precursor to allow a lithium transition metal composite oxide having a small and highly uniform particle diameter to be obtained. A method also is provided for producing a transition metal composite hydroxide represented by a general formula (1) MxWsAt(OH)2+α, coated with a compound containing the additive element, and serving as a precursor of a positive electrode active material for nonaqueous electrolyte secondary batteries. The method includes producing a composite hydroxide particle, forming nuclei, growing a formed nucleus; and forming a coating material containing a metal oxide or hydroxide on the surfaces of composite hydroxide particles obtained through the upstream step.

公开(公告)号：US10128501B2

公开(公告)日：2018-11-13

申请号：US14124418

申请日：2012-04-03

申请人： Atsushi Fukui ,  Katsuya Inoue ,  Shuhei Oda ,  Hiroyuki Toya

发明人： Atsushi Fukui ,  Katsuya Inoue ,  Shuhei Oda ,  Hiroyuki Toya

IPC分类号： H01M4/525 ,  C01G53/00 ,  H01M4/505 ,  H01M10/0525 ,  H01M4/02

摘要： Provided are a cathode active material having a suitable particle size and high uniformity, and a nickel composite hydroxide as a precursor of the cathode active material. When obtaining nickel composite hydroxide by a crystallization reaction, nucleation is performed by controlling a nucleation aqueous solution that includes a metal compound, which includes nickel, and an ammonium ion donor so that the pH value at a standard solution temperature of 25° C. becomes 12.0 to 14.0, after which, particles are grown by controlling a particle growth aqueous solution that includes the formed nuclei so that the pH value at a standard solution temperature of 25° C. becomes 10.5 to 12.0, and so that the pH value is lower than the pH value during nucleation. The crystallization reaction is performed in a non-oxidizing atmosphere at least in a range after the processing time exceeds at least 40% of the total time of the particle growth process from the start of the particle growth process where the oxygen concentration is 1 volume % or less, and with controlling an agitation power requirement per unit volume into a range of 0.5 kW/m3 to 4 kW/m3 at least during the nucleation process.

公开(公告)号：US20150364761A1

公开(公告)日：2015-12-17

申请号：US14124418

申请日：2012-04-03

申请人： Atsushi Fukui ,  Katsuya Inoue ,  Shuhei Oda ,  Hiroyuki Toya

发明人： Atsushi Fukui ,  Katsuya Inoue ,  Shuhei Oda ,  Hiroyuki Toya

IPC分类号： H01M4/525 ,  H01M4/505 ,  H01M10/0525 ,  C01G53/00

CPC分类号： H01M4/525 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/34 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/505 ,  H01M10/0525 ,  H01M2004/028

摘要： Provided are a cathode active material having a suitable particle size and high uniformity, and a nickel composite hydroxide as a precursor of the cathode active material. When obtaining nickel composite hydroxide by a crystallization reaction, nucleation is performed by controlling a nucleation aqueous solution that includes a metal compound, which includes nickel, and an ammonium ion donor so that the pH value at a standard solution temperature of 25° C. becomes 12.0 to 14.0, after which, particles are grown by controlling a particle growth aqueous solution that includes the formed nuclei so that the pH value at a standard solution temperature of 25° C. becomes 10.5 to 12.0, and so that the pH value is lower than the pH value during nucleation. The crystallization reaction is performed in a non-oxidizing atmosphere at least in a range after the processing time exceeds at least 40% of the total time of the particle growth process from the start of the particle growth process where the oxygen concentration is 1 volume % or less, and with controlling an agitation power requirement per unit volume into a range of 0.5 kW/m3 to 4 kW/m3 at least during the nucleation process.

摘要翻译： 提供具有合适的粒度和高均匀性的阴极活性材料和作为阴极活性材料的前体的镍复合氢氧化物。 当通过结晶反应获得镍复合氢氧化物时，通过控制包含镍的金属化合物和铵离子供体的成核水溶液进行成核，使得在25℃的标准溶液温度下的pH值变为 12.0〜14.0，然后通过控制包含所形成的核的颗粒生长水溶液生长颗粒，使得在25℃的标准溶液温度下的pH值变为10.5至12.0，并且使得pH值较低 比成核期间的pH值。 至少在处理时间超过从氧浓度为1体积％的粒子生长过程开始的粒子生长过程的总时间的至少40％以上的范围内，在非氧化性气氛中进行结晶反应， 至少在成核过程中，将每单位体积的搅拌功率要求控制在0.5kW / m3至4kW / m3的范围内。

公开(公告)号：US20140106228A1

公开(公告)日：2014-04-17

申请号：US14123410

申请日：2011-09-02

申请人： Hiroyuki Toya ,  Atsushi Fukui

发明人： Hiroyuki Toya ,  Atsushi Fukui

IPC分类号： H01M4/485 ,  C01D15/02

CPC分类号： H01M4/525 ,  C01D15/02 ,  C01G45/006 ,  C01G51/006 ,  C01G53/006 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/01 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/84 ,  C01P2006/12 ,  C01P2006/40 ,  C30B29/22 ,  H01M2/0222 ,  H01M2/1653 ,  H01M4/043 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/134 ,  H01M4/1391 ,  H01M4/382 ,  H01M4/485 ,  H01M4/505 ,  H01M4/623 ,  H01M4/625 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/0585 ,  H01M2004/021 ,  H01M2004/027 ,  H01M2004/028 ,  H01M2220/20 ,  H01M2220/30 ,  Y02P70/54

摘要： A transition metal composite hydroxide can be used as a precursor to allow a lithium transition metal composite oxide having a small and highly uniform particle diameter to be obtained. A method also is provided for producing a transition metal composite hydroxide represented by a general formula (1) MxWsAt(OH)2+α, coated with a compound containing the additive element, and serving as a precursor of a positive electrode active material for nonaqueous electrolyte secondary batteries. The method includes producing a composite hydroxide particle, forming nuclei, growing a formed nucleus; and forming a coating material containing a metal oxide or hydroxide on the surfaces of composite hydroxide particles obtained through the upstream step.

摘要翻译： 可以使用过渡金属复合氢氧化物作为前体，以获得具有小而高度均匀粒径的锂过渡金属复合氧化物。 还提供了一种制备由通式（1）MxWsAt（OH）2 +α表示的过渡金属复合氢氧化物的方法，所述过渡金属复合氢氧化物涂覆有含有添加元素的化合物，并且用作非水性正极活性材料的前体 电解质二次电池。 该方法包括制备复合氢氧化物颗粒，形成核，生长形成的核; 并且在通过上游步骤获得的复合氢氧化物颗粒的表面上形成含有金属氧化物或氢氧化物的涂料。

公开(公告)号：US20080311473A1

公开(公告)日：2008-12-18

申请号：US12034265

申请日：2008-02-20

申请人： Hideo SASAOKA ,  Ryuuichi Kuzuo ,  Atsushi Fukui ,  Mitsukuni Kondou ,  Shin Imaizumi ,  Kensuke Nakura ,  Shuji Tsutsumi

发明人： Hideo SASAOKA ,  Ryuuichi Kuzuo ,  Atsushi Fukui ,  Mitsukuni Kondou ,  Shin Imaizumi ,  Kensuke Nakura ,  Shuji Tsutsumi

IPC分类号： H01M4/00 ,  H01M4/88

CPC分类号： H01M4/525 ,  H01M4/364 ,  H01M4/485 ,  H01M4/505 ,  H01M10/052 ,  H01M2004/028 ,  Y02E60/122 ,  Y02P70/54

摘要： The present invention provides a cathode active material that makes possible a high capacity nonaqueous electrolyte secondary battery that has excellent discharge load characteristics that provide both good cycle characteristics and thermal stability. The cathode active material comprises a lithium nickel composite oxide having the compositional formula LiNi1−aMaO2 (where, M is at least one kind of element that is selected from among a transitional metal other than Ni, a group 2 element, and group 13 element, and 0.01≦a≦0.5) to which fine lithium manganese composite oxide particle adhere to the surface thereof. This lithium nickel composite oxide is obtained by adding manganese salt solution to a lithium nickel composite oxide slurry, causing manganese hydroxide that contains lithium to adhere to the surface of the lithium nickel composite oxide particles, and then baking that lithium nickel composite oxide.

摘要翻译： 本发明提供一种阴极活性材料，其使得具有优异的放电负荷特性的提供良好的循环特性和热稳定性的高容量非水电解质二次电池成为可能。 正极活性物质包含具有组成式LiNi1-aMaO2的锂镍复合氧化物（其中，M为选自Ni之外的过渡金属，第2族元素和13族元素中的至少一种元素， 和0.01 <= a <= 0.5），细小的锂锰复合氧化物颗粒附着在其表面上。 该锂镍复合氧化物是通过向锂镍复合氧化物浆料中添加锰盐溶液而得到的，其中含有锂的氢氧化锰粘附在锂镍复合氧化物粒子的表面上，然后焙烧该锂镍复合氧化物。

公开(公告)号：US09601772B2

公开(公告)日：2017-03-21

申请号：US12034265

申请日：2008-02-20

申请人： Hideo Sasaoka ,  Ryuuichi Kuzuo ,  Atsushi Fukui ,  Mitsukuni Kondou ,  Shin Imaizumi ,  Kensuke Nakura ,  Shuji Tsutsumi

发明人： Hideo Sasaoka ,  Ryuuichi Kuzuo ,  Atsushi Fukui ,  Mitsukuni Kondou ,  Shin Imaizumi ,  Kensuke Nakura ,  Shuji Tsutsumi

IPC分类号： H01M4/131 ,  H01M4/525 ,  H01M4/36 ,  H01M4/485 ,  H01M4/505 ,  H01M10/052 ,  H01M4/02

CPC分类号： H01M4/525 ,  H01M4/364 ,  H01M4/485 ,  H01M4/505 ,  H01M10/052 ,  H01M2004/028 ,  Y02E60/122 ,  Y02P70/54

摘要： The present invention provides a cathode active material that makes possible a high capacity nonaqueous electrolyte secondary battery that has excellent discharge load characteristics that provide both good cycle characteristics and thermal stability. The cathode active material comprises a lithium nickel composite oxide having the compositional formula LiNi1−aMaO2 (where, M is at least one kind of element that is selected from among a transitional metal other than Ni, a group 2 element, and group 13 element, and 0.01≦a≦0.5) to which fine lithium manganese composite oxide particle adhere to the surface thereof. This lithium nickel composite oxide is obtained by adding manganese salt solution to a lithium nickel composite oxide slurry, causing manganese hydroxide that contains lithium to adhere to the surface of the lithium nickel composite oxide particles, and then baking that lithium nickel composite oxide.

公开(公告)号：US09828309B2

公开(公告)日：2017-11-28

申请号：US14119281

申请日：2012-05-24

申请人： Shinichiro Yanagawa ,  Yuichiro Fujiyama ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Yuichiro Fujiyama ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C4/06 ,  C10G35/06 ,  B01D45/12 ,  B01J8/00 ,  C10G35/14 ,  C10G35/04 ,  C10G35/10 ,  B01J29/40 ,  B01J29/70 ,  B01J29/87

CPC分类号： C07C4/06 ,  B01D45/12 ,  B01J8/005 ,  B01J29/40 ,  B01J29/70 ,  B01J29/87 ,  C10G35/04 ,  C10G35/065 ,  C10G35/10 ,  C10G35/14 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/301 ,  C10G2400/30

摘要： Method for producing monocyclic aromatic hydrocarbons includes a cracking and reforming reaction step of obtaining products containing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms and a heavy fraction having 9 or more carbon atoms by bringing the feedstock oil into contact with a catalyst for producing monocyclic aromatic hydrocarbons containing crystalline aluminosilicate to cause a reaction, a catalyst separation step of separating and removing the catalyst for producing monocyclic aromatic hydrocarbons together with tricyclic aromatic hydrocarbons contained in the products from a mixture of the products and a small amount of the catalyst for producing monocyclic aromatic hydrocarbons carried by the products, both of which are derived in the cracking and reforming reaction step, and a purification and recovery step of purifying and recovering the monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms which are separated from the products formed in the cracking and reforming reaction step.

公开(公告)号：US09413010B2

公开(公告)日：2016-08-09

申请号：US13636811

申请日：2011-03-24

申请人： Atsushi Fukui ,  Taizo Sunano ,  Maruo Kamino

发明人： Atsushi Fukui ,  Taizo Sunano ,  Maruo Kamino

IPC分类号： H01M4/62 ,  H01M4/04 ,  H01M4/134 ,  H01M4/1395 ,  H01M10/052 ,  C08L79/08 ,  C08G73/10

CPC分类号： H01M4/622 ,  C08G73/1067 ,  C08G73/1082 ,  C08L79/08 ,  H01M4/04 ,  H01M4/0404 ,  H01M4/134 ,  H01M4/1395 ,  H01M10/052 ,  Y02E60/122 ,  Y02P70/54 ,  Y10T29/49115

摘要： Provided is a lithium secondary battery in which negative-electrode active material particles containing silicon and/or a silicon alloy are used and which prevents the occurrence of breakage of a binder itself and peel-off of the binder at the interfaces with the negative-electrode active material and the negative-electrode current collector and has a high energy density and an excellent cycle characteristic. The lithium secondary battery includes: a negative electrode in which a negative-electrode active material layer including negative-electrode active material particles containing silicon and/or a silicon alloy and a binder is formed on a surface of electrically conductive metal foil serving as a negative-electrode current collector; a positive electrode; and a nonaqueous electrolyte, wherein the binder contains a polyimide resin including a crosslinked structure formed by imidization of a hexavalent or higher-valent carboxylic acid or an anhydride thereof with a diamine.

摘要翻译： 提供一种锂二次电池，其中使用含有硅和/或硅合金的负极活性物质颗粒，并且防止粘合剂本身的破裂发生和粘合剂在与负极的界面处的剥离 活性物质和负极集电体，具有高能量密度和优异的循环特性。 锂二次电池包括：在作为负极的导电性金属箔的表面上形成有负极活性物质层的负极，负极活性物质层包含含有硅和/或硅合金的负极活性物质粒子和粘合剂 电极集电器; 正极; 和非水电解质，其中所述粘合剂含有通过将六价或更高价羧酸或其酸酐与二胺酰亚胺化而形成的交联结构的聚酰亚胺树脂。