End carboxyl bearing reactive vinyl monomers and preparation thereof
    1.
    发明授权
    End carboxyl bearing reactive vinyl monomers and preparation thereof 失效
    端羧基反应性乙烯基单体及其制备

    公开(公告)号:US4883899A

    公开(公告)日:1989-11-28

    申请号:US345005

    申请日:1989-04-28

    IPC分类号: C07C67/08 C07C67/29 C07C69/54

    CPC分类号: C07C67/08 C07C69/54

    摘要: An end carboxyl bearing reactive vinyl monomer represented by the formula: ##STR1## wherein R.sub.1 is hydrogen or methyl group; R.sub.2 is a bivalent aliphatic hydrocarbon having 2 to 10 carbon atoms, a bivalent alicyclic hydrocarbon having 6 to 7 carbon atoms, phenylene substituted with halogen, sulfo or carboxyl group; A is a repeating unit of the formula: ##STR2## R.sub.3 is ethylene or propylene; R.sub.4 is an alkylene having 2 to 7 carbon atoms; R.sub.5 is an alkylene having 2 to 5 carbon atoms; m is an integer of 1 to 10 and n is an integer of 2 to 50. The present reactive vinyl monomer is very useful as a constituting unit of vinyl resin.

    摘要翻译: 由下式表示的端羧基反应性乙烯基单体:其中R 1是氢或甲基; R2是碳原子数为2〜10的二价脂肪族烃,碳原子数为6〜7的二价脂环烃,被卤素,磺基或羧基取代的亚苯基。 A是下式的重复单元:< IMAGE> R3是乙烯或丙烯; R4是具有2-7个碳原子的亚烷基; R5是具有2-5个碳原子的亚烷基; m为1〜10的整数,n为2〜50的整数。本反应性乙烯基单体作为乙烯基树脂的构成单元非常有用。

    Resinous composition comprising an acrylic resin having end carboxyl
bearing long pendant groups and preparation thereof
    2.
    发明授权
    Resinous composition comprising an acrylic resin having end carboxyl bearing long pendant groups and preparation thereof 失效
    树脂组合物包含具有端羧基长链侧基的丙烯酸树脂及其制备

    公开(公告)号:US4812549A

    公开(公告)日:1989-03-14

    申请号:US1010

    申请日:1987-01-07

    CPC分类号: C08F246/00 C08F220/28

    摘要: A resinous composition comprising an acrylic resin having end carboxyl bearing long pendant groups of the formula: ##STR1## wherein R.sub.2 is a substituted or unsubstituted aliphatic hydrocarbon having 2 to 10 carbon atoms, alicyclic hydrocarbon having 6 to 7 carbon atoms or aromatic hydrocarbon having 6 carbon atoms; A is a repeating unit of ##STR2## R.sub.3 is ethylene or propylene; R.sub.4 is a substituted or unsubstituted alkylene having 2 to 7 carbon atoms; R.sub.5 is a substituted or unsubstituted alkylene having 2 to 5 carbon atoms; m is an integer of 1 to 10; and n is an integer of 2 to 50. The invention also concerns a process for preparing said resinous composition characterizing by polymerizing a monomer mixture containing end carboxyl bearing reactive acryl monomer of the formula: ##STR3##

    摘要翻译: 一种树脂组合物,其包含具有末端羧基的具有下式的长侧基的丙烯酸树脂:其中R 2是具有2至10个碳原子的取代或未取代的脂族烃,具有6至7个碳原子的脂环族烃或具有6个 碳原子 A是重复单元,其中R3是乙烯或丙烯; R4是取代或未取代的碳原子数为2〜7的亚烷基; R5是取代或未取代的碳原子数2〜5的亚烷基。 m为1〜10的整数。 本发明还涉及一种制备所述树脂组合物的方法,其特征在于通过聚合含有末端羧基的反应性丙烯酸单体的单体混合物,其结构如下:< IMAGE>

    Aqueous vinyl resin emulsion
    3.
    发明授权
    Aqueous vinyl resin emulsion 失效
    水性乙烯基树脂乳液

    公开(公告)号:US5017646A

    公开(公告)日:1991-05-21

    申请号:US001009

    申请日:1987-01-07

    IPC分类号: C08F220/28 C08F246/00

    CPC分类号: C08F246/00 C08F220/28

    摘要: (A) 1 to 50% by weight of at least one end carboxyl bearing reactive vinyl monomer of the formula: ##STR1## in which R.sub.1 is hydrogen or methyl group; R.sub.2 is a substituted or unsubstituted aliphatic hydrocarbon having 2 to 10 carbon atoms, alicyclic hydrocarbon having 6 to 7 carbon atoms or aromatic hydrocarbon having 6 carbon atoms; A is a repeating unit of ##STR2## R.sub.3 is ethylene or propylene; R.sub.4 is a substituted or unsubstituted alkylene having 2 to 7 carbon atoms; R.sub.5 is a substituted or unsubstituted alkylene having 2 to 5 carbon atoms; m is an integer of 1 to 10; n is an integer of 2 to 50; X is an inorganic or organic base, and when .alpha., .beta.-ethylenically unsaturated compound(s) (B) hereinunder referred to includes a basic relative monomer, it may be hydrogen atom, and(B) 99 to 50% by weight of at least one other .alpha., .beta.-ethylenically unsaturated compounds, in an aqueous medium through an emulsion polymerization and removing the said medium therefrom.The invention also concerns an aqueous emulsion containing said microparticles in a considerable quantity, which is specifically useful in an aqueous paint.

    摘要翻译: (A)1至50重量%的下式的至少一种含羧基的反应性乙烯基单体:其中R 1是氢或甲基; R2是取代或未取代的碳原子数2〜10的脂肪族烃,碳原子数6〜7的脂肪族烃或碳原子数为6的芳香族烃。 A是重复单元,其中R3是乙烯或丙烯; R4是取代或未取代的碳原子数为2〜7的亚烷基; R5是取代或未取代的碳原子数2〜5的亚烷基。 m为1〜10的整数。 n为2〜50的整数, X是无机或有机碱,当α,β-烯属不饱和化合物(B)在下文中被称为包括碱性相对单体时,其可以是氢原子,和(B)99至50重量% 至少一种其它α,β-烯属不饱和化合物,通过乳液聚合在水性介质中,并从中除去所述介质。 本发明还涉及含有相当数量的所述微粒的含水乳液,其特别用于水性涂料。

    Photosensitive resin composition
    4.
    发明授权
    Photosensitive resin composition 失效
    感光树脂组合物

    公开(公告)号:US5204221A

    公开(公告)日:1993-04-20

    申请号:US648881

    申请日:1991-01-31

    IPC分类号: G03F7/033 G03F7/027 H05K3/00

    CPC分类号: G03F7/027 H05K3/0076

    摘要: Disclosed is a photosensitive resin composition which has improved water developability and storage stability. The composition comprises(I) crosslinked resin particles prepared by a post-emulsion method from(a) a base resin having a glass transition temperature (Tg) of 0.degree. C. or less and a polymerizable double bond,(b) a monomer which, when polymerized, provides a resin in which Tg is 20.degree. C. higher than that of the base resin, or a resin in which Tg is 20.degree. C. higher than that of the base resin,(c) a polyvinyl compound, and(d) a polymerization initiator(II) a photopolymerizable unsaturated monomer, and(III) a photopolymerization initiator.

    Amphiphatic polymerizable vinyl monomers, vinyl resin particles derived
from said monomers and preparation thereof
    9.
    发明授权
    Amphiphatic polymerizable vinyl monomers, vinyl resin particles derived from said monomers and preparation thereof 失效
    双键可聚合乙烯基单体,衍生自所述单体的乙烯基树脂颗粒及其制备

    公开(公告)号:US4908468A

    公开(公告)日:1990-03-13

    申请号:US126965

    申请日:1987-11-30

    IPC分类号: C08F12/22 C08F20/26 C08F20/38

    CPC分类号: C08F20/38 C08F12/22 C08F20/26

    摘要: A novel amphiphatic polymerizable vinyl monomer of the formula: ##STR1## having surface active function and crosslinking catalytic function, as well as increased amphiphatic nature. The invention also provides a preparation method of said amphiphatic polymerizable vinyl monomer, resin particles obtained by using said vinyl monomer, aqueous and organic solvent dispersion of said resin particles which are specifically useful in coating compositions.

    摘要翻译: 具有下式的新颖的两亲性可聚合乙烯基单体:具有表面活性功能和交联催化功能,以及增加的双亲性质。 本发明还提供了所述两亲性可聚合乙烯基单体的制备方法,通过使用所述乙烯基单体获得的树脂颗粒,所述树脂颗粒的水性和有机溶剂分散体特别可用于涂料组合物。