Amphiphatic polymerizable vinyl monomers, vinyl resin particles derived
from said monomers and preparation thereof
    1.
    发明授权
    Amphiphatic polymerizable vinyl monomers, vinyl resin particles derived from said monomers and preparation thereof 失效
    双键可聚合乙烯基单体,衍生自所述单体的乙烯基树脂颗粒及其制备

    公开(公告)号:US4908468A

    公开(公告)日:1990-03-13

    申请号:US126965

    申请日:1987-11-30

    IPC分类号: C08F12/22 C08F20/26 C08F20/38

    CPC分类号: C08F20/38 C08F12/22 C08F20/26

    摘要: A novel amphiphatic polymerizable vinyl monomer of the formula: ##STR1## having surface active function and crosslinking catalytic function, as well as increased amphiphatic nature. The invention also provides a preparation method of said amphiphatic polymerizable vinyl monomer, resin particles obtained by using said vinyl monomer, aqueous and organic solvent dispersion of said resin particles which are specifically useful in coating compositions.

    摘要翻译: 具有下式的新颖的两亲性可聚合乙烯基单体:具有表面活性功能和交联催化功能,以及增加的双亲性质。 本发明还提供了所述两亲性可聚合乙烯基单体的制备方法,通过使用所述乙烯基单体获得的树脂颗粒,所述树脂颗粒的水性和有机溶剂分散体特别可用于涂料组合物。

    Electrodeposition coating composition
    2.
    发明授权
    Electrodeposition coating composition 失效
    电沉积涂料组合物

    公开(公告)号:US4869796A

    公开(公告)日:1989-09-26

    申请号:US81782

    申请日:1987-08-05

    IPC分类号: C09D5/44

    CPC分类号: C09D5/448 Y10S524/901

    摘要: An electrodeposition coating composition comprising (a) a water-dispersible, electrically depositable binder resin and (b) water-insoluble, internally crosslinked polymer microparticles having a particle size from 0.01 to 2 microns, said polymer microparticles bearing on their surfaces physically adhered or covalently bound thereto an amphoionic group of the formula: ##STR1## wherein R represents an unsubstituted or substituted C.sub.1 -C.sub.6 alkylene or phenylene, A is --COOH or --SO.sub.3 H.

    摘要翻译: 一种电沉积涂料组合物,其包含(a)水分散性可电沉积的粘合剂树脂和(b)具有0.01至2微米粒度的水不溶性内部交联的聚合物微粒,所述聚合物微粒在其表面上物理粘附或共价 其结合式为:其中R表示未取代或取代的C 1 -C 6亚烷基或亚苯基,A为-COOH或-SO 3 H。

    Continuous polymerization method and apparatus
    3.
    发明授权
    Continuous polymerization method and apparatus 失效
    连续聚合方法和装置

    公开(公告)号:US5340891A

    公开(公告)日:1994-08-23

    申请号:US158924

    申请日:1993-11-29

    摘要: Polymer particles having a small particle diameter and a narrow particle diameter distribution are obtained by a continuous polymerization method which does not accompany an increase of cohering products attaching to an inner face of a reaction vessel and an air-bubble invasion and, in which stirring of a material solution for polymerization is easy. An emulsion polymerization reaction or a suspension polymerization reaction is carried out by supplying a material solution for polymerization continuously to a clearance between coaxial double cylinders, which have stretched toward a direction crossing a horizontal plane, from the end side of the cylinders, by rotating at least one of the double cylinders round the axis and thereby, causing Taylor vortices. The polymer particles thus-formed are obtained by through the other end side of the double cylinders to the outside.

    摘要翻译: 通过连续聚合法获得具有小粒径和窄粒径分布的聚合物颗粒,其不伴随着连接到反应容器的内表面和气泡入侵的粘附产物的增加,并且其中搅拌 聚合的材料溶液容易。 乳液聚合反应或悬浮聚合反应是通过将连续聚合的材料溶液从气缸的端部侧朝向与水平面交叉的方向拉伸的同轴双筒之间的间隙,通过在 至少一个双圆筒绕轴线,从而引起泰勒涡流。 这样形成的聚合物颗粒通过双缸的另一端侧到外部获得。

    Continuous polymerization method and apparatus
    5.
    发明授权
    Continuous polymerization method and apparatus 失效
    连续聚合方法和装置

    公开(公告)号:US5470539A

    公开(公告)日:1995-11-28

    申请号:US221392

    申请日:1994-03-30

    摘要: Polymer particles having a small particle diameter and a narrow particle diameter distribution are obtained by a continuous polymerization method which does not accompany an increase of cohering products attaching to an inner face of a reaction vessel and an air-bubble invasion and, in which stirring of a material solution for polymerization is easy. An emulsion polymerization reaction or a suspension polymerization reaction is carried out by supplying a material solution for polymerization continuously to a clearance between coaxial double cylinders, which have stretched toward a direction crossing a horizontal plane, from the end side of the cylinders, by rotating at least one of the double cylinders round the axis and thereby, causing Taylor vortices. The polymer particles thus-formed are obtained by through from the other end side of the double cylinders to the outside.

    摘要翻译: 通过连续聚合法获得具有小粒径和窄粒径分布的聚合物颗粒,其不伴随着连接到反应容器的内表面和气泡入侵的粘附产物的增加,并且其中搅拌 聚合的材料溶液容易。 乳液聚合反应或悬浮聚合反应是通过将连续聚合的材料溶液从气缸的端部侧朝向与水平面交叉的方向拉伸的同轴双筒之间的间隙,通过在 至少一个双圆筒绕轴线,从而引起泰勒涡流。 这样形成的聚合物颗粒通过从双筒的另一端侧到外部的方式获得。

    URETHANE RESIN PARTICLES FOR SLUSH MOLDING
    10.
    发明申请
    URETHANE RESIN PARTICLES FOR SLUSH MOLDING 有权
    用于成型的URETHANE树脂颗粒

    公开(公告)号:US20120245281A1

    公开(公告)日:2012-09-27

    申请号:US13514190

    申请日:2010-12-10

    IPC分类号: C08L75/04 C08L75/12

    摘要: Provided are urethane resin particles for slush molding which make it possible that inconveniences based on the slip-down of a pigment, on the aggregation of particles of the pigment, and on other causes are removed although this coloring is coloring onto the resin particle surfaces. The present invention is urethane resin particles for slush mold which contain a urethane resin and an additive, wherein the particles have a shape factor SF1 of 101 to 200, a shape factor SF2 of 120 to 240, and a central particle diameter of 20 to 500 μm. It is preferred that the urethane resin has a concentration of urea groups of 0.5 to 10% by weight, a total of the concentration of urethane groups and that of the urea groups of 4 to 20% by weight, a melting point of 160 to 260° C. and a glass transition temperature of −65 to 0° C.

    摘要翻译: 提供了用于搪塑的聚氨酯树脂颗粒,这使得可能除去颜料着色到树脂颗粒表面上以来,基于颜料的滑落,颜料的颗粒聚集和其它原因的不便。 本发明是含有聚氨酯树脂和添加剂的用于糊模的聚氨酯树脂颗粒,其中颗粒的形状因子SF1为101〜200,形状因子SF2为120〜240,中心粒径为20〜500 μm。 优选的是,所述聚氨酯树脂的尿素基浓度为0.5〜10重量%,氨基甲酸酯基和尿素基的浓度的总和为4〜20重量%,熔点为160〜260 ℃,玻璃化转变温度为-65℃至0℃。