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公开(公告)号：US20050245777A1
公开(公告)日：2005-11-03
申请号：US11109551
申请日：2005-04-19
申请人： Howard Fong , Lizbeth Trevino , Brendan Murray , Manuel Cano
发明人： Howard Fong , Lizbeth Trevino , Brendan Murray , Manuel Cano
IPC分类号： C07C1/00 , C07C1/30 , C07C11/02 , C07C17/10 , C07C17/358 , C07C17/37 , C07C29/124
CPC分类号： C07C29/124 , C07C1/30 , C07C11/02 , C07C17/10 , C07C17/358 , C07C17/37 , C07C2521/10 , C07C2521/14 , C07C2523/14 , C07C2523/44 , C07C2523/745 , C07C2523/78 , C07C19/075 , C07C19/01 , C07C31/125
摘要： This invention provides for a process to convert branched or linear alkanes to branched or linear alpha olefins (AO) of the same carbon number. The process comprises the steps of: a) halogenating linear alkanes, branched alkanes, or a mixture of linear and branched alkane to produce a mixture containing primary mono-haloalkanes and hydrogen halide; b) separating the hydrogen halide from the mixture and optionally neutralizing it with a metal oxide to produce a partially halogenated metal oxide and/or metal halide which may be regenerated; c) separating the primary mono-haloalkanes from the mixture; d) reacting the separated primary mono-haloalkanes with a metal oxide to produce a mixture of products that contains alpha olefins, unconverted primary mono-haloalkanes, possibly other reaction products, and a partially halogenated metal oxide and/or metal halide which may be regenerated; e) regenerating the partially halogenated metal oxide and/or metal halide to halogen and/or acid and a metal oxide (such as Cl2) for recycle by reaction with air or oxygen ; and f) removing the unreacted primary mono-haloalkane from the reaction mixture and then purifying the alpha olefin.
摘要翻译： 本发明提供将支链或直链烷烃转化为相同碳数的支链或直链α-烯烃（AO）的方法。 该方法包括以下步骤：a）将直链烷烃，支链烷烃或直链和支链烷烃的混合物卤化以产生含有主要单卤代烷烃和卤化氢的混合物; b）从混合物中分离卤化氢并任选地用金属氧化物中和它以产生可再生的部分卤化的金属氧化物和/或金属卤化物; c）从混合物中分离初级单卤代烷烃; d）使分离的初级单卤代烷烃与金属氧化物反应以产生含有α-烯烃，未转化的初级单卤代烷烃，可能的其它反应产物和可再生的部分卤化的金属氧化物和/或金属卤化物的产物的混合物 ; e）将部分卤化的金属氧化物和/或金属卤化物再生成卤素和/或酸和金属氧化物（例如Cl 2 N 2），以通过与空气或氧气反应再循环; 和f）从反应混合物中除去未反应的主要单卤代烷烃，然后纯化α-烯烃。
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公开(公告)号：US20050245772A1
公开(公告)日：2005-11-03
申请号：US11116892
申请日：2005-04-28
申请人： Howard Fong , Lizbeth Trevino , Brendan Murray , Manuel Cano , Terry Thomason
发明人： Howard Fong , Lizbeth Trevino , Brendan Murray , Manuel Cano , Terry Thomason
IPC分类号： C07C1/30 , C07C17/10 , C07C27/00 , C07C29/124 , C07C41/01 , C07C43/11 , C07C45/27 , C07C305/06 , C11D1/04 , C11D3/37
CPC分类号： C07C1/30 , C07C29/124 , C07C31/20 , C07C11/02
摘要： Derivatives of branched or linear olefins and alcohols made by halogenation of branched or n-alkanes of the same carbon number, preferably to make primary mono-haloalkanes, which may then be oxidized with metal oxides. The derivatives of primary alcohols of this invention include alcohol ethoxylates, alcohol sulfates, alcohol sulfated ethoxylates, surfactants, including those made with these ethoxylates and/or sulfated ethoxylates, detergents made with these surfactants, oxyalkylated alcohols, oxyalkylated alcohol sulfates, polymethacrylate esters, alkyl amines and their derivatives, linear phthalates, linear adipates, alcohol ether amines, alkyl glycerol ether sulfonates, thioproprionate esters, alkyl polyglucosides, alcohol phosphates, alcohol ether phosphates, esters of fatty acids, alcohol phosphites, and benzophenones. Secondary alcohol derivatives include secondary alcohol ethoxylates, secondary alcohol sulfates, secondary alcohol sulfated ethoxylates, surfactants, including those made with these ethoxylates and/or sulfated ethoxylates, and detergents made with these surfactants. Internal olefins derivatives included within the scope of this invention include alkylbenzene, alkylxylene, detergent alcohols, plasticizer alcohols, alkenyl succinates, ether secondary alcohols, and diols and polyols produced by catalytic dihydroxylation of internal olefins with the use of hydrogen peroxide. Alpha olefin derivatives included within the scope of this invention include internal olefins, alkylbenzene, alkylxylene, alkylphenol, alkylnaphthalene, detergent alcohols, plasticizer alcohols, alkylates of phenylbenzo compounds, alkyl ammonium salts of unsaturated fatty acids, alkyl amines and their derivatives, alpha olefin sulfonates, alkenyl succinates, polyalphaolefins, linear mercaptans, synthetic acids such as based on 1-butene, 1-hexene, or 1-octene, chlorinated alpha olefins, aluminum alkyls, alkyl diphenylether disulfonates, fatty acids, lubricant additives, and ether primary alcohols.
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公开(公告)号：US20050245771A1
公开(公告)日：2005-11-03
申请号：US11109552
申请日：2005-04-19
IPC分类号： B01J23/42 , B01J23/56 , B01J23/62 , B01J23/644 , B01J23/745 , C01B7/01 , C01B7/09 , C07C17/10 , C07C17/23 , C07C17/358 , C07C29/124
CPC分类号： C07C17/358 , B01J23/42 , B01J23/56 , B01J23/626 , B01J23/6447 , B01J23/745 , C01B7/01 , C01B7/096 , C07C17/10 , C07C17/23 , C07C29/124 , C12C11/02 , C07C19/01 , C07C19/075 , C07C31/125
摘要： This invention provides a process to convert alkanes to primary alcohols of the same carbon number. Carbon numbers of particular interest are C8 to C18. The process comprises the steps of: a) halogenating a linear or branched (or mixture of linear and branched) alkane to produce a mixture of primary mono-haloalkanes, internal mono-haloalkanes, unreacted alkanes, hydrogen halide, and possibly multi-haloalkanes in the presence of a catalyst and/or by heating the reaction mixture; b) separating the hydrogen halide from the mixture and optionally neutralizing it with a metal oxide to produce a partially halogenated metal oxide and/or metal halide which may be regenerated; c) separating the primary mono-haloalkanes from the mixture; d) reacting the separated primary mono-haloalkanes in a reactor with a metal oxide or combination of metal oxides and water to convert the aforesaid primary mono-haloalkane to a mixture of products that contains primary alcohols, unconverted primary mono-haloalkanes, and possibly other reaction products, and a partially halogenated metal oxide and/or metal halide which may be regenerated; e) regenerating the partially halogenated metal oxide and/or metal halide to halogen (such as Cl2) and/or acid and a metal oxide for recycle by reaction with air or oxygen; and f) removing the unreacted primary mono-haloalkane from the reaction mixture and then purifying the primary alcohol.
摘要翻译： 本发明提供了将烷烃转化为相同碳数的伯醇的方法。 特别感兴趣的碳数为C 8至C 18。 该方法包括以下步骤：a）将直链或支链（或直链和支链的）混合物卤化以产生主要单卤代烷烃，内部单卤代烷烃，未反应的烷烃，卤化氢和可能的多卤代烷烃的混合物 催化剂的存在和/或通过加热反应混合物; b）从混合物中分离卤化氢并任选地用金属氧化物中和它以产生可再生的部分卤化的金属氧化物和/或金属卤化物; c）从混合物中分离初级单卤代烷烃; d）将反应器中分离的主要单卤代烷烃与金属氧化物或金属氧化物和水的组合反应，将上述初级单卤代链烷烃转化为含有伯醇，未转化的主要单卤代烷烃和可能的其它产物的混合物 反应产物和可再生的部分卤化的金属氧化物和/或金属卤化物; e）将部分卤化的金属氧化物和/或金属卤化物再生成卤素（例如Cl 2 H 2）和/或酸和金属氧化物，以通过与空气或氧气反应再循环; 和f）从反应混合物中除去未反应的主要单卤代链烷烃，然后纯化伯醇。
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公开(公告)号：US20070118007A1
公开(公告)日：2007-05-24
申请号：US11553365
申请日：2006-10-26
申请人： Howard Fong , Brendan Murray
发明人： Howard Fong , Brendan Murray
CPC分类号： C07C11/02 , C07C2/08 , C07C2/34 , C07C5/2506 , C07C29/16 , C07C303/24 , C07C2521/04 , C07C2523/04 , C07C2531/22 , C11D1/146 , C11D11/0082 , C07C31/125 , C07C305/06 , C07C11/08
摘要： This invention provides a process for making internal olefins which comprises isomerizing a feed comprising one or more internal olefin(s) in the presence of an isomerization catalyst to produce alpha olefins and reacting said alpha olefins in the presence of a dimerization catalyst to produce internal olefins.
摘要翻译： 本发明提供了一种制备内烯烃的方法，该方法包括在异构化催化剂存在下将包含一种或多种内烯烃的原料异构化以产生α-烯烃，并在二聚催化剂存在下使所述α-烯烃反应以产生内烯烃 。
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5.发明申请公开(公告)号：US20070016696A1
公开(公告)日：2007-01-18
申请号：US11306424
申请日：2005-12-28
IPC分类号： G06F15/16
CPC分类号： G06F17/3089
摘要： A method, system and software tool for emulating a portal application in a rich client application are provided. The rich client application is executable on a client platform capable of displaying views contributed by plug-in components registered with the client platform. The method comprises providing a user interface for eliciting user inputs for creating a new portal application on the client platform, detecting user selection of a portal page layout, and one or more views for each cell of the page layout, and generating a description of a client page representing the portal application. When the rich client application is run on the client platform it is directed to build a client page representing the portal application using the generated description.
摘要翻译： 提供了一种用于在富客户端应用程序中模拟门户应用程序的方法，系统和软件工具。 富客户端应用程序可在能够显示由客户端平台注册的插件组件贡献的视图的客户端平台上执行。 该方法包括提供用于引导用户输入的用户界面，用于在客户端平台上创建新的门户应用，检测门户页面布局的用户选择以及页面布局的每个单元的一个或多个视图，以及生成 客户端页面代表门户应用程序。 当富客户端应用程序在客户端平台上运行时，它被引导使用生成的描述构建表示门户应用程序的客户端页面。
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公开(公告)号：US20060183954A1
公开(公告)日：2006-08-17
申请号：US11398300
申请日：2006-04-05
申请人： Michael Doll , Brendan Murray
发明人： Michael Doll , Brendan Murray
IPC分类号： C07C5/25
CPC分类号： C07C5/2518 , C07C2529/08
摘要： A process for the double bond isomerization of an olefin, which process comprises contacting a feed comprising the olefin with an isomerization catalyst, wherein prior to contacting the feed with the isomerization catalyst one or more components of the feed are pretreated by contacting with a pretreating material which comprises a zeolite which has a pore size of at least 0.35 nm; a plant which is suitable for carrying out the isomerization process; and a process for treating an olefin mixture which comprises a linear α-olefin and a vinylidene olefin which is isomeric to the linear α-olefin and which is of the general formula CH2═C(R1)R2, wherein R1 represents an ethyl group and R2 represents a linear 1-alkyl group, which process comprises isomerising the vinylidene olefin to form a double bond isomer of the vinylidene olefin by contacting a feed comprising the olefin mixture with an isomerization catalyst, and separating the linear α-olefin from the double bond isomer of the vinylidene olefin, wherein prior to contacting the feed with the isomerization catalyst one or more components of the feed are pretreated by contacting with a pretreating material which comprises a zeolite which has a pore size of at least 0.35 nm.
摘要翻译： 一种烯烃双键异构化的方法，该方法包括将包含烯烃的进料与异构化催化剂接触，其中在将进料与异构化催化剂接触之前，将进料的一种或多种组分与预处理材料 其包含孔径至少为0.35nm的沸石; 适用于进行异构化处理的植物; 以及一种用于处理烯烃混合物的方法，所述烯烃混合物包含直链α-烯烃和与线性α-烯烃异构的亚乙烯基烯烃，其通式为CH 2 -C（R 0 其中R 1表示乙基，R 2表示直链的1-烷基，其中R 1表示直链的1-烷基，其中R 1表示乙基，R 2表示直链的1-烷基， 将亚乙烯基烯烃异构化以形成亚乙烯基烯烃的双键异构体，其通过使包含烯烃混合物的进料与异构化催化剂接触，并将线性α-烯烃与亚乙烯基烯烃的双键异构体分离，其中在接触之前 与异构化催化剂一起进料的进料通过与预处理材料接触来预处理，该预处理材料包含孔径至少为0.35nm的沸石。
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公开(公告)号：US20060178544A1
公开(公告)日：2006-08-10
申请号：US11053559
申请日：2005-02-08
申请人： Brendan Murray , Narayana Mysore , James Yaeger
发明人： Brendan Murray , Narayana Mysore , James Yaeger
IPC分类号： C07C2/68
CPC分类号： C07C2/66 , B01J29/7007 , B01J2229/42 , C10G29/205 , C10G61/02 , Y02P20/52 , C07C15/02 , C07C15/085
摘要： A method for increasing selectivity of alkylation to monoalkylation comprising: providing a feedstream consisting essentially of alkylating agent and a stoichiometric excess of benzene, the alkylating agent consisting essentially of a molar blend of propylene and one or more linear butene(s); and, contacting the feedstream with a catalytically effective amount of zeolite beta under alkylation reaction conditions which increase selectivity of the alkylation to monoalkylation compared to predicted selectivity to monoalkylation based on the concentration of the alkylating agent and on the molar blend of propylene and one or more linear butene(s).
摘要翻译： 提高烷基化至单烷基化选择性的方法，包括：提供基本上由烷基化剂和化学计量过量的苯组成的原料流，烷基化剂主要由丙烯与一种或多种直链丁烯的摩尔共混物组成; 并且在烷基化反应条件下使进料流与催化有效量的沸石β接触，其与基于烷基化试剂的浓度和丙烯与一种或多种摩尔共混物的预测的单烷基化选择性相比，增加了烷基化对单烷基化的选择性 线性丁烯。
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公开(公告)号：US08943424B2
公开(公告)日：2015-01-27
申请号：US13569577
申请日：2012-08-08
摘要： A system, computer program and method for developing a graphical user interface (GUI) in a computer program. The invention allows developers to control the properties of interface components according to the state of a program during execution. According to the invention, a GUI development environment may be configured to provide a GUI builder for creating the GUI, display an interface component with at least one interface component property to be instantiated in the GUI, display a property interface to input at least one value for the interface component property in response to an event detectable by the computer program during GUI program execution, and automatically generate GUI program code effectuating the value for the interface component property in response to the event detectable by the computer program during GUI program execution.
摘要翻译： 一种用于在计算机程序中开发图形用户界面（GUI）的系统，计算机程序和方法。 本发明允许开发人员在执行期间根据程序的状态来控制接口组件的属性。 根据本发明，GUI开发环境可以被配置为提供用于创建GUI的GUI构建器，在GUI中显示具有要被实例化的至少一个界面组件属性的接口组件，显示属性界面以输入至少一个值 响应于在GUI程序执行期间可由计算机程序检测到的事件的接口组件属性，并且响应于在GUI程序执行期间由计算机程序检测到的事件，自动生成GUI程序代码来实现界面组件属性的值。
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公开(公告)号：US20060189836A9
公开(公告)日：2006-08-24
申请号：US10880072
申请日：2004-06-29
申请人： Brendan Murray , Garo Vaporciyan
发明人： Brendan Murray , Garo Vaporciyan
CPC分类号： C07C15/085 , C07C1/22 , C07C2523/40 , C07C2523/44 , C07C2523/72 , C07C2523/74 , C07C2529/22 , Y02P20/127 , Y10S203/06
摘要： A process for producing an alkylbenzene from an alkylphenyl alcohol involving the steps of: (a) feeding a feed stream containing alkylphenyl a reactor having a catalytic distillation zone; and, (b) concurrently in the reactor (i) contacting the feed stream containing alkylphenyl alcohol with hydrogen in the catalytic distillation zone to convert alkylphenyl alcohol to alkylbenzene over a catalyst containing Group VIII or a Group IB metal; and, (ii) separating alkylbenzene from the reaction mixture by fractional distillation to produce an overhead stream containing alkylbenzene having a reduced concentration of alkylphenyl alcohol than the feed stream from the distillation column reactor. Examples of the alkylphenyl alcohol include cumyl alcohol, phenyl ethyl alcohol, or di(2-hydroxyl 2-propyl)benzene, and that for the alkylbenzene include cumene and di-ethyl benzene, or di(2-hydroxyl-2-propyl)benzene.
摘要翻译： 包括以下步骤生产烷基苯的方法：（a）将含有烷基苯基的进料流输送到具有催化蒸馏区的反应器; 和（b）在反应器中同时（i）在催化蒸馏区中使含有烷基苯基醇的进料流与氢气接触，以使烷基苯醇在含有VIII族或IB族金属的催化剂上转化为烷基苯; 和（ii）通过分馏从反应混合物中分离出烷基苯，以产生含有烷基苯醇浓度低于来自蒸馏塔反应器的进料流的烷基苯的塔顶液流。 烷基苯醇的实例包括枯基醇，苯基乙醇或二（2-羟基-2-丙基）苯，对于烷基苯包括枯烯和二乙基苯，或二（2-羟基-2-丙基）苯 。
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公开(公告)号：US20050101808A1
公开(公告)日：2005-05-12
申请号：US10965256
申请日：2004-10-14
申请人： Paul Ayoub , Hendrik Dirkzwager , Brendan Murray , Steve Sumrow
发明人： Paul Ayoub , Hendrik Dirkzwager , Brendan Murray , Steve Sumrow
CPC分类号： C07C29/16 , C07C31/125
摘要： Systems and methods to produced branched aliphatic alcohols are described. Systems may include a dehydrogenation-isomerization unit, an olefin dimerization unit, an olefin isomerization unit, a hydroformylation unit, a dehydrogenation unit, a hydrogenation unit and/or combinations thereof. Methods for producing branched aliphatic alcohols may include isomerization of olefins in a process stream. The isomerized olefins may be hydroformylated to produce aliphatic alcohols. After hydroformylation of the aliphatic alcohols, unreacted components from the hydroformylation process may be separated from the aliphatic alcohols products. The unreacted components from the hydroformylation process may be recycled back into the main process stream or sent to other processing units. Addition of multiple streams to the units may be performed to control reaction conditions in the units.
摘要翻译： 描述了制备支链脂族醇的体系和方法。 系统可以包括脱氢异构化单元，烯烃二聚单元，烯烃异构化单元，加氢甲酰化单元，脱氢单元，氢化单元和/或其组合。 制备支链脂族醇的方法可以包括在工艺流中烯烃的异构化。 异构化的烯烃可以加氢甲酰化以产生脂族醇。 在脂肪醇的加氢甲酰化之后，来自加氢甲酰化过程的未反应组分可以与脂族醇产物分离。 来自加氢甲酰化方法的未反应组分可以循环回到主工艺流中或送到其它处理单元。 可以向单元添加多个流以控制单元中的反应条件。
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