摘要:
Thermoreactive recording material contains, as developer, a mixture of an acidic-modified polymer of (meth)acrylonitrile and/or methacrylonitrile and a diphenol of the formula ##STR1## in which Y is, for example, a single bond, an alkylene or alkylidene radical, gives, on thermal printing, a dye which has a reduced tendency to sublime.
摘要:
A thermoreactive recording material contains a dyestuff precursor and an acid-modified polymer of acrylonitrile or methacrylonitrile and a 4-hydroxybenzoic acid ester as acceptor.
摘要:
The invention relates to a process for the continuous production of polyacrylonitrile hydrolyzates and to their use as dispersion and grinding aids for pigments and fillers, such as for example kaolin, CaCO.sub.3 or gypsum.
摘要:
It is possible to remove quantities of heat from exothermically running polymerization reactions of vinyl monomers in heterogeneous phase, in a sophisticated manner by adding liquids to the reaction medium for the removal of heat and to regulate the reaction temperature, which liquids do not dissolve the polymer under the reaction conditions and the boiling temperatures of which are lower than or are identical to the technically predetermined reaction temperatures under the polymerization conditions which are applied, and the heat which is released in the reaction system is removed by evaporating these liquids.
摘要:
Acrylonitrile polymers and copolymers with good affinity for basic dyes without sulfonic acid groups containing comonomers are obtained by polymerizing at a temperature of from 0.degree. to 60.degree. C. in an aliphatic hydrocarbon having a boiling point of from -10.degree. to 80.degree. C. or in a mixture of aliphatic hydrocarbons having boiling points in the range from -10.degree. to 80.degree. C. using an initiator system comprising from 0.1 to 8.0 mole percent of sulfur dioxide, from 0.1 to 2.0 mole percent of a hydroperoxide which is soluble in the reaction medium and from 0.01 to 1.0 mole percent of an acid which is soluble in the reaction system in that polymerization is carried out continuously and in that an average residence time of from 10 minutes to 2 hours is maintained.
摘要:
Vacuole-free films, filaments and fibers consisting of a polymer mixture which comprises a copolymer of acrylonitrile and a polymer which is obtained by a polymer-analogue reaction of a polyacrylic acid ester with dimethylamine, said polymer containing from 40-99 mol % of N,N-dimethyl acrylamide units.
摘要:
Described is a process for producing segmented polyurethanes having improved processing characteristics in the melt state and an efficient spinning process based thereon to form highly elastic, fine linear density elastane yarn and filament having improved mechanical and thermal properties by using hydroxyalkyl-terminated polysiloxanes in combination with specific crosslinking-capable polyisocyanates in the reaction of long-chain high molecular weight polyhydroxy compounds with organic diisocyanates and low molecular weight diols and also optionally further auxiliary and additive substances in the melt.
摘要:
A process for modifying superabsorbent polymers is disclosed. The surface of a polymer containing hydrolyzed polyacrylonitrile in the form of particulates, is modified by crosslinking in a water/alcohol reaction mixture and in the presence of silica. The resulting product features improved absorbency under load and lesser degree of gel blocking.
摘要:
Super-absorbent polymer in the form of pre-formed spherical particles obtainable by alkaline hydrolysis of aqueous emulsions of crosslinked and/or un-crosslinked homopolymers and/or copolymers of acrylonitrile in water/alcohol mixtures and the use of the polymer in hygiene products, as a water-storing material in agriculture and for the sheathing of electrical cables.
摘要:
Oil- and water-repellent papers are treated on the surface or in the pulp of the papers with fluorine-containing copolymers ofa) acrylates containing perfluoroalkyl groups, of the formulaCH.sub.2 .dbd.CR.sup.1 --COO--X--C.sub.n F.sub.2n+1 (I),b) monomers of the formulaCH.sub.2 .dbd.CR.sup.2 --COO--R.sup.3 (II),c) monomers of the formulaCH.sub.2 .dbd.CR.sup.4 --COO--(CH.sub.2 CH.sub.2 O).sub.m --R.sup.5 (III),d) monomers of the formulaCH.sub.2 .dbd.CR.sup.6 --COO--CH.sub.2 CH.sub.2 --N(R.sup.7,R.sup.8) (IVa)or, in salt-like form, of the formula[CH.sub.2 .dbd.CR.sup.6 --COO--CH.sub.2 CH.sub.2 --N(R.sup.7,R.sup.8,R.sup.9)].sup..sym. Y.sup..crclbar. (IVb)or, in N-oxidized form, of the formula ##STR1## and e) monomers of the formulaCH.sub.2 .dbd.CR.sup.10 CONHR.sup.11 (V)these substituents and indices in the formulae having the meaning given in the description and the copolymers comprising the monomers in amounts of a) =50 to 90% by weight, b) =1 to 35% by weight, c) =3 to 20% by weight, d) =1 to 20% by weight and e) =0 to 10% by weight. Such copolymers having a content of e) =0.5 to 10% by weight are new.