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公开(公告)号：US08487154B2
公开(公告)日：2013-07-16
申请号：US12726009
申请日：2010-03-17
IPC分类号： C10G57/00
CPC分类号： C10G29/205 , B01J31/0277 , B01J31/0284 , B01J31/26 , B01J31/40 , B01J2219/00006 , B01J2219/00047 , B01J2231/20 , C10L1/06
摘要： A process comprising adjusting a level of conjunct polymers in an ionic liquid catalyst between a low level that favors production of C5+ products boiling at 137.8° C. or below and a higher level that favors production of both C5+ products boiling at 137.8° C. or below and C5+ products boiling above 137.8° C.; wherein the adjusting is done in response to market demand. A process unit, comprising a reactor that operates with an ionic liquid catalyst comprising a low level or a higher level of conjunct polymers, and the alkylation reactor is switched between operating with the low and the higher levels in response to market demand. A process unit, comprising a reactor that operates in an alkylate mode and a distillate mode, and a catalyst regenerator that operates with varying severity to adjust the level of conjunct polymers in response to demand for gasoline or distillate.
摘要翻译： 一种方法包括调节离子液体催化剂中的结合聚合物的水平，其水平低于沸点为137.8℃或更低的C5 +产物的生成，以及有利于沸点为137.8℃的两种C5 +产物的生产的较高水平，或 C5 +产物沸点高于137.8℃。 其中所述调整是根据市场需求进行的。 一种处理单元，其包括用包含低水平或更高水平的结合聚合物的离子液体催化剂操作的反应器，并且烷基化反应器响应于市场需求在低和高水平操作之间切换。 一种处理单元，包括以烷基化模式和馏出物模式操作的反应器，以及催化剂再生器，其以不同的严重程度操作，以响应于对汽油或馏出物的需求来调节结合聚合物的水平。
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公开(公告)号：US20110226669A1
公开(公告)日：2011-09-22
申请号：US12726009
申请日：2010-03-17
CPC分类号： C10G29/205 , B01J31/0277 , B01J31/0284 , B01J31/26 , B01J31/40 , B01J2219/00006 , B01J2219/00047 , B01J2231/20 , C10L1/06
摘要： A process comprising adjusting a level of conjunct polymers in an ionic liquid catalyst between a low level that favors production of C5+ products boiling at 137.8° C. or below and a higher level that favors production of both C5+ products boiling at 137.8° C. or below and C5+ products boiling above 137.8° C.; wherein the adjusting is done in response to market demand. A process unit, comprising a reactor that operates with an ionic liquid catalyst comprising a low level or a higher level of conjunct polymers, and the alkylation reactor is switched between operating with the low and the higher levels in response to market demand. A process unit, comprising a reactor that operates in an alkylate mode and a distillate mode, and a catalyst regenerator that operates with varying severity to adjust the level of conjunct polymers in response to demand for gasoline or distillate.
摘要翻译： 一种方法包括调节离子液体催化剂中的结合聚合物的水平，其水平低于沸点为137.8℃或更低的C5 +产物的生成，以及有利于沸点为137.8℃的两种C5 +产物的生产的较高水平，或 C5 +产物沸点高于137.8℃。 其中所述调整是根据市场需求进行的。 一种处理单元，其包括用包含低水平或更高水平的结合聚合物的离子液体催化剂操作的反应器，并且烷基化反应器响应于市场需求在低和高水平操作之间切换。 一种处理单元，包括以烷基化模式和馏出物模式操作的反应器，以及催化剂再生器，其以不同的严重程度操作，以响应于对汽油或馏出物的需求来调节结合聚合物的水平。
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公开(公告)号：US08455708B2
公开(公告)日：2013-06-04
申请号：US12725969
申请日：2010-03-17
IPC分类号： C10G57/00
CPC分类号： B01J19/004 , B01D3/009 , B01J31/0284 , B01J31/143 , B01J31/40 , B01J2219/00006 , B01J2219/00047 , C10G29/205 , C10G45/58 , C10G50/00 , C10G2300/1051 , C10G2300/1092 , C10G2300/305 , C10G2400/02
摘要： A process for producing hydrocarbon products, comprising: a) operating a process unit in an alkylate mode wherein greater than 50 wt % of a C5+ hydrocarbon stream from the process unit boils at 137.8° C. or below, b) adjusting one or more process conditions in the process unit, and c) after the adjusting step, operating the process unit in a distillate mode wherein greater than 50 wt % of the C5+ hydrocarbon stream from the process unit boils above 137.8° C. Also, a process unit, comprising: a) an alkylation reactor; and b) a control system that enables the alkylation reactor to be operated in the alkylate mode and in the distillate mode; wherein the alkylation reactor can switch back and forth from operating in the alkylate mode to the distillate mode.
摘要翻译： 一种生产烃产物的方法，包括：a）以烷基化模式操作处理单元，其中大于50重量％的来自所述处理单元的C5 +烃流在137.8℃或更低温度沸腾，b）调节一个或多个过程 处理单元中的条件，以及c）在调整步骤之后，以馏出模式操作处理单元，其中大于50重量％的来自处理单元的C5 +烃流沸点高于137.8℃。另外，处理单元包括 ：a）烷基化反应器; 和b）使烷基化反应器能够以烷基化模式和馏出模式操作的控制系统; 其中烷基化反应器可以来回切换为在烷基化模式下进行至馏出物模式。
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4.发明申请公开(公告)号：US20110230692A1
公开(公告)日：2011-09-22
申请号：US12725987
申请日：2010-03-17
CPC分类号： C10G29/205 , C07C2/58 , C07C2527/125 , C07C2531/02 , C10G2300/20 , C10G2300/202 , C10G2300/305 , C10G2400/02 , C07C9/16
摘要： We provide a process for producing high quality gasoline blending components, comprising: a) operating an alkylation reactor in an alkylate mode wherein a gasoline blending component is made having a RON of 90 or higher; and b) operating the alkylation reactor in a distillate mode wherein a second gasoline blending component and a distillate product is made, and wherein the second gasoline blending component has a RON of 85 or higher. Also, we provide an alkylation process unit, comprising: a control system connected to an alkylation reactor, that enables the alkylation reactor to operate in both an alkylate mode that produces a gasoline blending component having a RON of 90 or higher and in a distillate mode that produces a second gasoline blending component having a RON of 85 or higher.
摘要翻译： 我们提供一种生产高质量汽油调和组分的方法，包括：a）以烷基化方式操作烷基化反应器，其中制得的RON为90或更高的汽油共混组分; 和b）以蒸馏模式操作所述烷基化反应器，其中制备第二汽油调和组分和馏出物产物，并且其中所述第二汽油调和组分具有85或更高的RON。 另外，我们提供烷基化处理单元，其包括：连接到烷基化反应器的控制系统，其使得烷基化反应器能够以产生RON为90或更高的汽油调和组分的烷基化模式和馏出模式 其产生RON为85以上的第二汽油调和组分。
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5.发明授权公开(公告)号：US08895794B2
公开(公告)日：2014-11-25
申请号：US12725987
申请日：2010-03-17
CPC分类号： C10G29/205 , C07C2/58 , C07C2527/125 , C07C2531/02 , C10G2300/20 , C10G2300/202 , C10G2300/305 , C10G2400/02 , C07C9/16
摘要： We provide a process for producing high quality gasoline blending components, comprising: a) operating an alkylation reactor in an alkylate mode wherein a gasoline blending component is made having a RON of 90 or higher; and b) operating the alkylation reactor in a distillate mode wherein a second gasoline blending component and a distillate product is made, and wherein the second gasoline blending component has a RON of 85 or higher. Also, we provide an alkylation process unit, comprising: a control system connected to an alkylation reactor, that enables the alkylation reactor to operate in both an alkylate mode that produces a gasoline blending component having a RON of 90 or higher and in a distillate mode that produces a second gasoline blending component having a RON of 85 or higher.
摘要翻译： 我们提供一种生产高质量汽油调和组分的方法，包括：a）以烷基化方式操作烷基化反应器，其中制得的RON为90或更高的汽油共混组分; 和b）以蒸馏模式操作所述烷基化反应器，其中制备第二汽油调和组分和馏出物产物，并且其中所述第二汽油调和组分具有85或更高的RON。 另外，我们提供烷基化处理单元，其包括：连接到烷基化反应器的控制系统，其使得烷基化反应器能够以产生RON为90或更高的汽油调和组分的烷基化模式和馏出模式 其产生RON为85以上的第二汽油调和组分。
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公开(公告)号：US20110226664A1
公开(公告)日：2011-09-22
申请号：US12725969
申请日：2010-03-17
CPC分类号： B01J19/004 , B01D3/009 , B01J31/0284 , B01J31/143 , B01J31/40 , B01J2219/00006 , B01J2219/00047 , C10G29/205 , C10G45/58 , C10G50/00 , C10G2300/1051 , C10G2300/1092 , C10G2300/305 , C10G2400/02
摘要： A process for producing hydrocarbon products, comprising: a) operating a process unit in an alkylate mode wherein greater than 50 wt % of a C5+ hydrocarbon stream from the process unit boils at 137.8° C. or below, b) adjusting one or more process conditions in the process unit, and c) after the adjusting step, operating the process unit in a distillate mode wherein greater than 50 wt % of the C5+ hydrocarbon stream from the process unit boils above 137.8° C. Also, a process unit, comprising: a) an alkylation reactor; and b) a control system that enables the alkylation reactor to be operated in the alkylate mode and in the distillate mode; wherein the alkylation reactor can switch back and forth from operating in the alkylate mode to the distillate mode.
摘要翻译： 一种生产烃产物的方法，包括：a）以烷基化模式操作处理单元，其中大于50重量％的来自所述处理单元的C5 +烃流在137.8℃或更低温度沸腾，b）调节一个或多个过程 处理单元中的条件，以及c）在调整步骤之后，以馏出模式操作处理单元，其中大于50重量％的来自处理单元的C5 +烃流沸点高于137.8℃。另外，处理单元包括 ：a）烷基化反应器; 和b）使烷基化反应器能够以烷基化模式和馏出模式操作的控制系统; 其中烷基化反应器可以来回切换为在烷基化模式下进行至馏出物模式。
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公开(公告)号：US20110105811A1
公开(公告)日：2011-05-05
申请号：US12610010
申请日：2009-10-30
CPC分类号： C10G2/32 , B01J27/125 , B01J31/0277
摘要： A process to produce an alkylate distillate blending component in one embodiment comprising: providing at least one olefinic C5+ product which was produced by conversion of synthesis gas in a Fischer Tropsch process; and alkylating the olefinic C5+ product in the presence of an acidic ionic liquid alkylation catalyst with hydrocarbons selected from the group consisting of isoparaffins, cycloparaffins, and their mixtures to form an alkylate distillate blending component is described.
摘要翻译： 一种在一个实施方案中生产烷基化馏分共混组分的方法，包括：提供至少一种烯烃C5 +产物，其通过在费托方法中转化合成气产生; 并在酸性离子液体烷基化催化剂存在下烷烃化烯烃C5 +产物，其中烃选自异链烷烃，环烷烃及其混合物，形成烷基化物馏分共混组分。
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公开(公告)号：US08323478B2
公开(公告)日：2012-12-04
申请号：US13187656
申请日：2011-07-21
IPC分类号： C07C2/58
CPC分类号： C10G29/205 , C10G45/32 , C10G2300/1081 , C10G2300/1088 , C10G2300/1096 , C10G2300/201 , C10G2300/305 , C10G2300/4025 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10
摘要： A process, comprising: a. taking a sample from a continuous alkylation reactor process; b. measuring a content of a halide in the sample; and c. within 45 minutes from the taking a sample, adjusting a flow of a halide containing additive comprising the halide to control a ratio of a yield of an alkylate gasoline and a yield of a middle distillate. Also a process, comprising: a. taking a sample from an effluent of an alkylation reactor in an alkylation reactor process; b. measuring a content of a halide in the sample; and c. in response to the measured content of the halide, adjusting a flow of a halide containing additive to a predetermined range that has been selected to obtain a ratio of a yield of an alkylate gasoline and a yield of a middle distillate from 0.31 to 4.0 in a product from the alkylation reactor.
摘要翻译： 一个过程，包括：a。 从连续烷基化反应器工艺中取样; b。 测量样品中卤化物的含量; 和c。 在取样后45分钟内，调节包含卤化物的含卤化物添加剂的流动，以控制烷基化汽油的产率和中间馏分的产率。 还有一个过程，包括：a。 在烷基化反应器工艺中从烷基化反应器的流出物中取出样品; b。 测量样品中卤化物的含量; 和c。 响应于测量的卤化物含量，将含卤化物的添加剂的流量调节到预定范围内，以获得烷基化汽油的产率与中间馏分的产率之比为0.31至4.0，在 产物从烷基化反应器。
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公开(公告)号：US20110275876A1
公开(公告)日：2011-11-10
申请号：US13187656
申请日：2011-07-21
IPC分类号： C07C2/58
CPC分类号： C10G29/205 , C10G45/32 , C10G2300/1081 , C10G2300/1088 , C10G2300/1096 , C10G2300/201 , C10G2300/305 , C10G2300/4025 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10
摘要： A process, comprising: a. taking a sample from a continuous alkylation reactor process; b. measuring a content of a halide in the sample; and c. within 45 minutes from the taking a sample, adjusting a flow of a halide containing additive comprising the halide to control a ratio of a yield of an alkylate gasoline and a yield of a middle distillate. Also a process, comprising: a. taking a sample from an effluent of an alkylation reactor in an alkylation reactor process; b. measuring a content of a halide in the sample; and c. in response to the measured content of the halide, adjusting a flow of a halide containing additive to a predetermined range that has been selected to obtain a ratio of a yield of an alkylate gasoline and a yield of a middle distillate from 0.31 to 4.0 in a product from the alkylation reactor.
摘要翻译： 一个过程，包括：a。 从连续烷基化反应器工艺中取样; b。 测量样品中卤化物的含量; 和c。 在取样后45分钟内，调节包含卤化物的含卤化物添加剂的流动，以控制烷基化汽油的产率和中间馏分的产率。 还有一个过程，包括：a。 在烷基化反应器工艺中从烷基化反应器的流出物中取出样品; b。 测量样品中卤化物的含量; 和c。 响应于测量的卤化物含量，将含卤化物的添加剂的流量调节到预定范围内，以获得烷基化汽油的产率与中间馏分的产率之比为0.31至4.0，在 产物从烷基化反应器。
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10.发明申请METHOD TO MAKE AN ACID CATALYST HAVING GREATER THAN 20 WT% CONJUNCT POLYMER 审中-公开制备具有超过20 WT％共轭聚合物的酸催化剂的方法公开(公告)号：US20110319258A1
公开(公告)日：2011-12-29
申请号：US13228143
申请日：2011-09-08
CPC分类号： B01J31/06 , B01J31/0284 , B01J31/0298 , B01J2231/32 , C07C2/58 , C07C2527/126 , C07C2531/02 , C07C2531/06
摘要： A method to make an acidic ionic liquid catalyst, by mixing aluminum chloride in the presence of a hydrocarbon solvent, an organic chloride, and optionally an ionic liquid; wherein the acidic ionic liquid catalyst does not precipitate out solids; and wherein the acidic ionic liquid catalyst has greater than 20 wt % conjunct polymer and a molar ratio of Al to a heteroatom selected from the group consisting of N, P, O, S, and combinations thereof greater than 2.0. Also a method to make the acidic ionic liquid catalyst comprising: a. mixing aluminum chloride in the presence of a hydrocarbon solvent, and an organic chloride, to make an acid catalyst phase comprising a conjunct polymer; b. adding hydrogen chloride to the acid catalyst phase.
摘要翻译： 一种通过在烃溶剂，有机氯化物和任选的离子液体的存在下混合氯化铝来制备酸性离子液体催化剂的方法; 其中所述酸性离子液体催化剂不会沉淀出固体; 并且其中所述酸性离子液体催化剂具有大于20重量％的结合聚合物，并且Al与选自N，P，O，S及其组合的杂原子的摩尔比大于2.0。 还有一种制备酸性离子液体催化剂的方法，包括：a。 在烃溶剂和有机氯化物的存在下混合氯化铝，以制备包含结合聚合物的酸催化剂相; b。 在酸催化剂相中加入氯化氢。
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