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公开(公告)号：US11905471B2
公开(公告)日：2024-02-20
申请号：US17414882
申请日：2019-12-13
IPC分类号： C10G49/04 , B01J23/883 , B01J35/10 , B01J37/02 , B01J37/08
CPC分类号： C10G49/04 , B01J23/883 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J37/0205 , B01J37/088
摘要： The present invention relates to a hydrogenolysis process wherein a hydrocarbon-based feedstock comprising aromatic compounds having at least 8 carbon atoms is treated by means of a hydrogen feed and in the presence of a catalyst, in order to convert C2+ alkyl chains of said aromatic compounds into methyl groups and to produce a hydrogenolysis effluent enriched in methyl-substituted aromatic compounds, wherein the catalyst comprises a support, comprising at least one refractory oxide, and an active phase comprising nickel and molybdenum, wherein: the nickel content being between 0.1 and 25% by weight relative to the total weight of the catalyst; the molybdenum content being between 0.1 and 20% by weight relative to the total weight of the catalyst; and the catalyst comprising a molar ratio of molybdenum to nickel of between 0.2 and 0.9. The present invention also relates to said catalyst and to the process for preparing said catalyst.
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公开(公告)号：US11492311B2
公开(公告)日：2022-11-08
申请号：US17415040
申请日：2019-12-13
摘要： The present invention relates to a device and a process for converting aromatic compounds, wherein: methyl-substituted aromatic compounds are extracted from a hydrocarbon feedstock (2) comprising aromatic compounds having at least 8 carbon atoms in an extraction unit (1), to produce at least one effluent enriched in methyl-substituted aromatic compounds (3A, 3B) and an effluent depleted in methyl-substituted aromatic compounds (4); and C2+ alkyl chains of the aromatic compounds of the depleted effluent (4) are converted into methyl groups in a hydrogenolysis unit (5) placed downstream of the extraction unit (1), to produce a hydrogenolysis effluent enriched in methyl-substituted aromatic compounds (7).
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3.发明授权公开(公告)号：US11117844B2
公开(公告)日：2021-09-14
申请号：US16629620
申请日：2018-07-10
摘要： The invention relates to a process for dehydrating alcohols to olefins, comprising a reaction step and a catalyst selectivation step.
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4.发明授权公开(公告)号：US10829700B2
公开(公告)日：2020-11-10
申请号：US16320816
申请日：2017-06-22
发明人： Cyprien Charra , Vincent Coupard , Jeremy Gazarian , Adrien Mekki-Berrada , Jean-Marc Schweitzer
摘要： This invention has as its object a method for selective hydrogenation of a feedstock comprising a pyrolysis gasoline carried out in a three-phase reactor.
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公开(公告)号：US10773250B2
公开(公告)日：2020-09-15
申请号：US16680709
申请日：2019-11-12
发明人： Nikolai Nesterenko , Delphine Minoux , Nadiya Danilina , Jean-Pierre Dath , Vincent Coupard , Sylvie Maury
IPC分类号： B01J29/06 , B01J29/67 , B01J29/65 , B01J29/66 , B01J29/68 , B01J29/69 , B01J37/02 , C01B39/02 , C07C1/24 , B01J29/90 , B01J29/70 , C07C5/27 , B01J37/30 , C01B39/44 , B01J29/74
摘要： The present invention relates to a catalyst composition comprising a modified crystalline aluminosilicate of the Framework Type FER having Si/Al framework molar/ratio greater than 20 characterized in that in said modified crystalline aluminosilicate the ratio between the strong acid sites and the weak acid sites, S/W, is lower than 1.0 and having the extra framework aluminum (EFAL) content lowered to less than 10 wt % preferably 5 wt % even more preferably less than 2 wt % measured by 27Al MAS NMR. The present invention further relates to a process for producing olefins from alcohols in presence of said catalyst composition.
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公开(公告)号：US10604456B2
公开(公告)日：2020-03-31
申请号：US16134363
申请日：2018-09-18
发明人： Kirill Drobyshev , Vincent Coupard , Jean-Christophe Gabelle , Nikolai Nesterenko , Christophe Thille
摘要： This invention relates to a method for dehydration of alcohols into olefins comprising an improved step for recovery of unreacted alcohol.
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公开(公告)号：US10472300B2
公开(公告)日：2019-11-12
申请号：US15540327
申请日：2015-12-18
发明人： Delphine Minoux , Nikolai Nesterenko , Cindy Adam , Walter Vermeiren , Philip De Smedt , Jean-Pierre Dath , Vincent Coupard , Sylvie Maury , Nicolas Aribert
摘要： The present invention is a process for dehydrating an alcohol to prepare a corresponding olefin, comprising: (a) providing a composition (A) comprising at least an alcohol having at least 2 carbon atoms, optionally water, optionally an inert component, in a dehydration unit, (b) placing the composition (A) into contact with an acidic catalyst in a reaction zone of said dehydration unit at conditions effective to dehydrate at least a portion of the alcohol to make a corresponding olefin, (c) recovering from said dehydration unit an effluent (B) comprising: at least an olefin, water, undesired by-products including aldehydes and light products, optionally unconverted alcohol(s), optionally the inert component, wherein, said composition (A)—providing step (a) comprises adding an effective amount of one or more sulfur containing compound capable to reduce the undesired by-products by comparison with a non introduction of such sulfur containing compound. The component introduced at step (a) can be chosen from the group consisting of thiols, sulfides, disulfides.
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公开(公告)号：US10435338B2
公开(公告)日：2019-10-08
申请号：US16034572
申请日：2018-07-13
发明人： Beatrice Fischer , Vincent Coupard
IPC分类号： C07C2/76 , C07C7/11 , C07C7/00 , F25J3/02 , B01D53/04 , C10G50/00 , C10G53/04 , C10G53/06 , C10G55/06 , C10G57/02 , C10G70/04 , C10G70/06 , C10G11/18 , C10G21/00
摘要： A gaseous fraction leaving overhead from a fractionation column of a catalytic cracking unit (FCC) is fractionated using a unit for the conversion of ethylene into propylene, in order to upgrade the ethylene contained in the fuel gas.
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公开(公告)号：US10363494B2
公开(公告)日：2019-07-30
申请号：US15581237
申请日：2017-04-28
IPC分类号： B01D3/00
摘要： The present invention describes a device for supplying the catalytic zone of a reactive distillation column using a liquid stream as the reaction stream, the flow of liquid in the reactive zone being of the upflow type and gas not encountering the liquid in the reactive zone.
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10.发明授权Process for dehydration and isomerization of alcohols using a catalyst based on a mesostructured material comprising silicon 有权使用基于包含硅的介孔结构材料的催化剂使醇脱水和异构化的方法公开(公告)号：US09512050B2
公开(公告)日：2016-12-06
申请号：US13853410
申请日：2013-03-29
CPC分类号： C07C5/2518 , B01J29/0308 , B01J29/041 , B01J35/1061 , B01J37/0045 , C07C1/24 , C07C5/2775 , C07C2521/12 , C07C2529/70 , C07C2529/80 , C07C2529/86 , C07C2529/87 , Y02P20/52 , C07C11/08 , C07C11/09
摘要： This invention has as its object a process for simultaneous dehydration and skeletal isomerization of a feedstock that comprises at least one C4 monoalcohol and that contains between 0.5 and 50% water, for the purpose of producing C4 alkenes, with said process operating at a temperature of between 250 and 550° C., under a pressure of between 0.1 and 1 MPa, with an hourly volumetric flow rate of between 0.1 and 10 h-1, characterized in that it uses a catalyst that comprises at least one mesostructured material that comprises silicon and at least one element X that is selected from among aluminum, boron, gallium, indium, and germanium.
摘要翻译： 本发明的目的是一种同时脱水和骨架异构化的方法，该方法包括至少一种C4一元醇，并且含有0.5％至50％的水，用于生产C4烯烃，所述方法在 介于250和550℃之间，在0.1至1MPa的压力下，小时体积流速在0.1至10小时-1之间，其特征在于其使用包含至少一种包含硅的介孔结构材料的催化剂 以及选自铝，硼，镓，铟和锗中的至少一种元素X。
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