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公开(公告)号：US10655069B2
公开(公告)日：2020-05-19
申请号：US15778101
申请日：2016-11-07
IPC分类号： C10G2/00 , B01J23/74 , B01J23/75 , B01J37/18 , B01J29/03 , B01J35/10 , B01J37/00 , B01J23/89 , B01J35/08 , B01J37/02 , B01J37/04 , B01J37/08 , B01J37/03
摘要： A process for the synthesis of linear paraffinic hydrocarbons from a feed of carbon monoxide and dihydrogen in the presence of a catalyst of a mesoporous oxide matrix and a content by weight of the element cobalt of 0.5% to 60%, wherein the catalyst is prepared by a) mixing, in an aqueous or hydro-organic solvent, a molecular precursor containing cobalt and a molecular precursor of the mesoporous oxide matrix containing element X of silicon, aluminium, titanium, zirconium and or cerium; b) aerosol spray drying the mixture to form spherical liquid droplets; c) drying to obtain solid particles at a temperature of 10° C. to 300° C.; d) activation by a reduction treatment to form nanoparticles of cobalt with an oxidation state of 0.
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公开(公告)号：US10563131B2
公开(公告)日：2020-02-18
申请号：US15778508
申请日：2016-11-07
摘要： A process for the synthesis of linear paraffinic hydrocarbons from a feed comprising carbon monoxide and dihydrogen in the presence of a mesoporous oxide matrix and cobalt prepared by mixing, at least one molecular precursor of cobalt and at least one colloidal precursor of mesoporous oxide matrix and by silicon, aluminium, titanium, zirconium, cerium or mixtures thereof, dissolved in aqueous or hydro-organic solvent; spray drying the mixture obtained to form spherical liquid droplets; drying the droplets to obtain solid particles activating the solid particles by reduction to form nanoparticles of cobalt with an oxidation state of 0.
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公开(公告)号：US10975000B2
公开(公告)日：2021-04-13
申请号：US15744266
申请日：2016-07-05
摘要： The invention relates to a catalyst that comprises at least the tantalum element, at least an aldolizing element and at least a mesoporous oxide matrix, with the tantalum mass being between 0.1 and 30% of the mesoporous oxide matrix mass, the mass of the at least one aldolizing element being between 0.02 and 4% of the mesoporous oxide matrix mass, and use thereof.
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公开(公告)号：US10737254B2
公开(公告)日：2020-08-11
申请号：US15749297
申请日：2016-07-26
发明人： Audrey Bonduelle , Alexandra Chaumonnot , Damien Delcroix , Christophe Vallee , Souad Rafik-Clement , Severine Forget
IPC分类号： C07C6/04 , B01J31/22 , B01J31/16 , B01J35/10 , B01J37/02 , B01J23/28 , B01J27/19 , B01J23/882 , B01J37/00 , B01J37/08 , C07C11/02
摘要： The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and silicon, said elements being incorporated into said matrix by means of at least one precursor comprising molybdenum and silicon and having at least one sequence of Si—O—Mo bonds.
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公开(公告)号：US10322983B2
公开(公告)日：2019-06-18
申请号：US15749344
申请日：2016-07-26
IPC分类号： C07C6/04 , B01J23/28 , B01J27/19 , B01J37/02 , B01J21/02 , B01J21/06 , B01J21/10 , B01J23/12 , B01J23/22 , B01J23/30 , B01J23/882 , B01J35/10 , C07C11/04 , C07C11/06 , C07C11/08
摘要： The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and aluminum, said elements being incorporated into said matrix by means of at least one precursor comprising molybdenum and aluminum.
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6.发明授权Process for dehydration and isomerization of alcohols using a catalyst based on a mesostructured material comprising silicon 有权使用基于包含硅的介孔结构材料的催化剂使醇脱水和异构化的方法公开(公告)号：US09512050B2
公开(公告)日：2016-12-06
申请号：US13853410
申请日：2013-03-29
CPC分类号： C07C5/2518 , B01J29/0308 , B01J29/041 , B01J35/1061 , B01J37/0045 , C07C1/24 , C07C5/2775 , C07C2521/12 , C07C2529/70 , C07C2529/80 , C07C2529/86 , C07C2529/87 , Y02P20/52 , C07C11/08 , C07C11/09
摘要： This invention has as its object a process for simultaneous dehydration and skeletal isomerization of a feedstock that comprises at least one C4 monoalcohol and that contains between 0.5 and 50% water, for the purpose of producing C4 alkenes, with said process operating at a temperature of between 250 and 550° C., under a pressure of between 0.1 and 1 MPa, with an hourly volumetric flow rate of between 0.1 and 10 h-1, characterized in that it uses a catalyst that comprises at least one mesostructured material that comprises silicon and at least one element X that is selected from among aluminum, boron, gallium, indium, and germanium.
摘要翻译： 本发明的目的是一种同时脱水和骨架异构化的方法，该方法包括至少一种C4一元醇，并且含有0.5％至50％的水，用于生产C4烯烃，所述方法在 介于250和550℃之间，在0.1至1MPa的压力下，小时体积流速在0.1至10小时-1之间，其特征在于其使用包含至少一种包含硅的介孔结构材料的催化剂 以及选自铝，硼，镓，铟和锗中的至少一种元素X。
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公开(公告)号：US11213802B2
公开(公告)日：2022-01-04
申请号：US15744106
申请日：2016-07-05
IPC分类号： B01J21/08 , B01J37/03 , B01J37/10 , B01J23/20 , B01J35/10 , B01J37/02 , C07C1/20 , B01J37/08 , B01J23/06 , B01J23/68 , B01J23/847
摘要： A mesoporous mixed oxide catalyst that comprises silicon and at least one metal M that is selected from the group that consists of the elements of groups 4 and 5 of the periodic table and mixtures thereof, with the mass of metal M being between 0.1 and 20% of the mixed oxide mass.
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公开(公告)号：US11091702B2
公开(公告)日：2021-08-17
申请号：US16769736
申请日：2018-11-26
IPC分类号： C10G45/04 , B01J37/02 , C10G45/50 , C10G45/54 , B01J27/188 , B01J37/20 , B01J37/08 , B01J23/883
摘要： The invention relates to a method for hydroprocessing a hydrocarbon feed, operated at a temperature of between 180° C. and 450° C., in the presence of a catalyst comprising i) a composite material comprising a compound based on at least one crystalline aluminium solid and carbon, the deposited carbon content being between 1 and 25 wt. % of the total mass of the composite material, and ii) at least one element of group VIB and at least one element of group VIII, in the sulfide form thereof, said catalyst being produced by a method comprising at least: a) a step of bringing a carbon precursor into contact with a compound based on at least one crystalline aluminium solid, b) a step of thermally treating the solid produced by step a), c) repeating steps a) and b) until the desired deposited carbon content is reached, d) depositing at least one element of group VIB and at least one element of group VIII on the surface of the solid produced by step c), and e) a step of sulfidisation of the solid produced in step d).
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公开(公告)号：US10322984B2
公开(公告)日：2019-06-18
申请号：US15749368
申请日：2016-07-26
IPC分类号： C07C6/04 , B01J23/28 , B01J27/19 , B01J35/10 , B01J37/08 , B01J37/02 , B01J23/00 , B01J23/882 , B01J37/00 , B01J21/02 , C07C11/04 , C07C11/06 , C07C11/08
摘要： The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and aluminum, said elements being incorporated into said matrix by means of at least two precursors of which at least one precursor contains molybdenum and at least one precursor contains aluminum.
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10.发明授权公开(公告)号：US09758442B2
公开(公告)日：2017-09-12
申请号：US14388859
申请日：2013-03-25
CPC分类号： C07C1/24 , B01J21/12 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J37/0009 , C07C5/2772 , C07C2529/03 , C07C11/09 , C07C11/08
摘要： Process for simultaneous dehydration and skeletal isomerization of a feedstock that comprises at least one C4 monoalcohol and that contains between 0.5 and 50% water, for the purpose of producing C4 alkenes, with said process operating at a temperature of between 250 and 550° C., under a pressure of between 0.1 and 1 MPa, with an hourly volumetric flow rate of between 0.1 and 10 h−1, characterized in that it uses a catalyst that comprises at least one non-zeolitic aluminosilicate-type solid.
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