Ziegler-natta catalyst systems comprising a 1,2-phenylenedioate as internal donor and process for preparing the same
    4.
    发明授权
    Ziegler-natta catalyst systems comprising a 1,2-phenylenedioate as internal donor and process for preparing the same 有权
    齐格勒 - 纳塔催化剂体系,其包含1,2-亚苯基二酸盐作为内给体及其制备方法

    公开(公告)号:US09593172B2

    公开(公告)日:2017-03-14

    申请号:US14414401

    申请日:2013-07-12

    IPC分类号: C08F4/649 C08F10/00

    摘要: A catalyst composition for use as precursor for Ziegler-Natta catalyst system, said catalyst composition comprising a combination of magnesium moiety, titanium moiety and an internal donor containing at least one 1,2-phenylenedioate compound of structure (A). Also, the present invention provides a process for preparing the aforesaid catalyst composition. Further, the present invention provides a Ziegler-Natta catalyst system incorporating the aforesaid catalyst composition and a method for polymerizing and/or copolymerizing olefins using the Ziegler-Natta catalyst system.

    摘要翻译: 一种用作齐格勒 - 纳塔催化剂体系的前体的催化剂组合物,所述催化剂组合物包含镁部分,钛部分和含有至少一种结构(A)的1,2-亚苯基二酸酯化合物的内给体的组合。 另外,本发明提供了制备上述催化剂组合物的方法。 此外,本发明提供了使用齐格勒 - 纳塔催化剂体系结合上述催化剂组合物的齐格勒 - 纳塔催化剂体系和使烯烃聚合和/或共聚的方法。

    ORGANOMETALLIC COMPOUND IN SOLID FORM, PROCESS FOR PREPARING THE SAME AND USE THEREOF
    8.
    发明申请
    ORGANOMETALLIC COMPOUND IN SOLID FORM, PROCESS FOR PREPARING THE SAME AND USE THEREOF 有权
    固体形式的有机化合物,其制备方法和用途

    公开(公告)号:US20150191553A1

    公开(公告)日:2015-07-09

    申请号:US14416609

    申请日:2013-09-24

    IPC分类号: C08F4/52 C08F4/16

    摘要: The present invention provides a solid organomagnesium precursor having formula {Mg(OR′)X}.a{MgX2}.b{Mg(OR′)2}.c{R′OH}, wherein R′ is selected from a hydrocarbon group, X is selected from a halide group, and a:b:c is in range of 0.01-0.5:0.01-0.5:0.01-5 and process for preparing the same, said process comprising contacting a magnesium source with a solvating agent, an organohalide and an alcohol to obtain the solid organomagnesium precursor. The present invention also provides a process for preparing a catalyst system using the organomagnesium precursor and its use thereof for polymerization of olefins. The organomagnesium precursor is prepared as follows: At 0° C., magnesium in diethyl ether is reacted with the organohalide. After all magnesium has reacted, the calculated amount of alcohol was added and after the completion of addition, the ether was evaporated and a solid compound obtained.

    摘要翻译: 本发明提供具有式{Mg(OR')X} .a {MgX 2} .b {Mg(OR')2} .c {R'OH}的固体有机镁前体,其中R'选自烃基 X选自卤化物基团,a:b:c在0.01-0.5:0.01-0.5:0.01-5的范围内及其制备方法,所述方法包括使镁源与溶剂化剂接触, 有机卤化物和醇,得到固体有机镁前体。 本发明还提供了使用有机镁前体制备催化剂体系的方法及其在烯烃聚合中的应用。 有机镁前体如下制备:在0℃下,在乙醚中的镁与有机卤化物反应。 全部镁反应后,加入计算出的醇量,加完后,蒸发乙醚,得到固体化合物。

    Organometallic compound in solid form, process for preparing the same and use thereof
    10.
    发明授权
    Organometallic compound in solid form, process for preparing the same and use thereof 有权
    固体形式的有机金属化合物,其制备方法及其应用

    公开(公告)号:US09587041B2

    公开(公告)日:2017-03-07

    申请号:US14416609

    申请日:2013-09-24

    IPC分类号: C08F4/52 C08F4/16 C07F3/02

    摘要: The present invention provides a solid organomagnesium precursor having formula {Mg(OR′)X}.a{MgX2}.b{Mg(OR′)2}.c{R′OH}, wherein R′ is selected from a hydrocarbon group, X is selected from a halide group, and a:b:c is in range of 0.01-0.5:0.01-0.5:0.01-5 and process for preparing the same, said process comprising contacting a magnesium source with a solvating agent, an organohalide and an alcohol to obtain the solid organomagnesium precursor. The present invention also provides a process for preparing a catalyst system using the organomagnesium precursor and its use thereof for polymerization of olefins. The organomagnesium precursor is prepared as follows: At 0° C., magnesium in diethyl ether is reacted with the organohalide. After all magnesium has reacted, the calculated amount of alcohol was added and after the completion of addition, the ether was evaporated and a solid compound obtained.

    摘要翻译: 本发明提供具有式{Mg(OR')X} .a {MgX 2} .b {Mg(OR')2} .c {R'OH}的固体有机镁前体,其中R'选自烃基 X选自卤化物基团,a:b:c在0.01-0.5:0.01-0.5:0.01-5的范围内及其制备方法,所述方法包括使镁源与溶剂化剂接触, 有机卤化物和醇,得到固体有机镁前体。 本发明还提供了使用有机镁前体制备催化剂体系的方法及其在烯烃聚合中的应用。 有机镁前体如下制备:在0℃下,在乙醚中的镁与有机卤化物反应。 全部镁反应后,加入计算出的醇量,加完后,蒸发乙醚,得到固体化合物。