公开(公告)号：US20170183489A1

公开(公告)日：2017-06-29

申请号：US15300389

申请日：2015-04-01

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Jordan KOPPING ,  Philipp BOECKMANN ,  Norbert NIESSNER ,  Lydia BEHRING

IPC: C08L25/12 ,  C08F265/06

CPC classification number: C08L25/12 ,  C08F265/04 ,  C08F265/06 ,  C08L2203/12 ,  C08L2203/16 ,  C08L51/04 ,  C08F212/10

Abstract: The invention relates to a process for producing moulding compositions containing: a) from 55 to 85% by weight of copolymer A composed of vinylaromatic monomer A1 and a,B-unsaturated monomer A2; b) from 15 to 45% by weight of graft copolymer B with particle size from 50 to 550 nm composed of: B 1: from 60 to 80% by weight of rubbery graft base B 1 composed of: B11: from 80 to 99% by weight of at least one C2-C8-alkyl acrylate, B12: from 0.5 to 2.5% by weight of cyclic crosslinking agent, B13: from 0 to 2% by weight of non-cyclic crosslinking agent, B2: from 20 to 40% by weight of at least one graft shell B2 composed of: B21: from 60 to 75% by weight of a styrene, B22: from 25 to 40% by weight of acrylonitrile, c) from 0 to 10% by weight of additives C; where the reaction time of the polymerization for producing the graft base B 1 is in the range from 2 to 5 h, and the addition of the starting materials takes place over at least two chronological segments.

公开(公告)号：US20160340504A1

公开(公告)日：2016-11-24

申请号：US15114615

申请日：2015-01-27

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert NIESSNER ,  Philipp BOECKMANN ,  Roland WALKER ,  Marcus REINING

IPC: C08L25/12 ,  C08J3/20 ,  C08J3/00

CPC classification number: C08L25/12 ,  C08J3/005 ,  C08J3/203 ,  C08J2325/12 ,  C08J2409/00 ,  C08J2451/06 ,  C08L2205/025 ,  C08L55/02

Abstract: The invention relates to a thermoplastic composition containing the components A and B and optionally the additional components C and D, the sum of which equals 100 wt. %. The molding compound consists of: a) 60 to 75 wt. % of one or more styrene copolymers A, b) 25 to 40 wt. % of one or more graft copolymers B, c) 0 to 15 wt. % of a rubber C which is different from component B, and d) 0 to 5 wt.% of one or more additives D. The composition contains 0.2 to 3.0 wt. %, based on the total weight of the components A to D, of oligomers, can be readily processed, and leads to scratch-resistant molded parts.

Abstract translation: 本发明涉及含有组分A和B以及任选的另外的组分C和D的热塑性组合物，其总和等于100wt。 ％。 模塑料由以下组成：a）60至75wt。 ％的一种或多种苯乙烯共聚物A，b）25〜40wt。 ％的一种或多种接枝共聚物B，c）0-15wt。 ％的不同于组分B的橡胶C，以及d）0-5重量％的一种或多种添加剂D.组合物含有0.2-3.0重量％ 基于低聚物的组分A至D的总重量的％可以容易地加工，并且导致耐划伤的模制部件。

公开(公告)号：US20170145201A1

公开(公告)日：2017-05-25

申请号：US15300037

申请日：2015-03-26

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Philipp BOECKMANN ,  Wolfgang FISCHER ,  Hans-Juergen HAUSSER

IPC: C08L25/12 ,  C08F265/04

CPC classification number: C08L25/12 ,  C08F2/002 ,  C08F2/26 ,  C08F265/04 ,  C08L2205/03 ,  C08F2/005 ,  C08L51/04 ,  C08F212/10

Abstract: A process for producing a thermoplastic molding composition comprising: 10% to 40% by weight of a graft copolymer A comprising 50% to 70% by weight, based on A, of a graft base A1 formed from an elastomeric, crosslinked acrylic ester polymer and 30% to 50% by weight of a graft shell A2, 50% to 90% by weight of a hard matrix B formed from copolymers of styrene or α-methylstyrene and acrylonitrile, 0% to 50% by weight of a further graft copolymer C, 0% to 15% by weight of additives D, wherein the reaction for preparation of the acrylic ester polymer A and/or the reaction for preparation of C is conducted in the presence of 0.01 to 4 times the molar amount of sodium carbonate, based on the sum total of the molar amount of initiator used in the preparation of the graft base and graft shell, leads to lower coagulate formation.

公开(公告)号：US20160297957A1

公开(公告)日：2016-10-13

申请号：US15038510

申请日：2014-11-19

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Philipp BOECKMANN ,  Wolfgang FISCHER ,  Maarten STAAL

IPC: C08L25/12 ,  C08J5/18 ,  C09D125/12

CPC classification number: C08L25/12 ,  C08F285/00 ,  C08J5/18 ,  C08J2325/12 ,  C08J2451/00 ,  C08L25/14 ,  C08L2207/53 ,  C09D125/12 ,  C08L51/04 ,  C08F212/08 ,  C08F220/44

Abstract: Thermoplastic moulding compositions containing: from 55 to 85% by weight of a copolymer A composed of styrene and acrylonitrile, from 10 to 40% by weight of at least one graft copolymer B composed of B1: from 50 to 80% by weight, preferably from 60 to 70% by weight, of crosslinked acrylate polymer B1 with average particle diameter from 300 to 700 nm as graft base B1, B2: a first graft shell B2 made of from 5 to 30 of a vinylaromatic monomer B21, and B3: a second graft shell B3 made of from 15 to 40 of a mixture of vinylaromatic monomers B31 and nitrile monomers B32, where these are present in a ratio by weight of from 4:1 to 3:2, and from 0 to 5% by weight of additives and/or auxiliaries C, have particular mechanical properties when the content of acrylonitrile in the copolymer component A and the content of acrylonitrile in the graft shell B3 differ by at least 8% by weight.

Abstract translation: 含有55〜85重量％的由苯乙烯和丙烯腈组成的共聚物A，10〜40重量％的由B1组成的至少一种接枝共聚物B：50〜80重量％，优选为 60〜70重量％的平均粒径为300〜700nm的交联丙烯酸酯聚合物B1作为接枝基B1，B2：由5-30的乙烯基芳族单体B21制成的第一接枝壳B2，B3：第二 由15至40个乙烯基芳族单体B31和腈单体B32的混合物制成的接枝壳B3，其中它们以4:1至3:2的重量比和0至5重量％的添加剂 和/或助剂C在共聚物组分A中的丙烯腈含量和接枝壳B3中的丙烯腈含量相差至少为8重量％时具有特定的机械性能。