Cellulose dip cord produced from highly homogeneous cellulose solution and tire using the same
    1.
    发明申请
    Cellulose dip cord produced from highly homogeneous cellulose solution and tire using the same 有权
    由高度均匀的纤维素溶液和使用其的轮胎生产的纤维素浸渍帘线

    公开(公告)号:US20050066646A1

    公开(公告)日:2005-03-31

    申请号:US10874308

    申请日:2004-06-24

    摘要: The present invention relates to a method for producing tire using high strength lyocell dip cord, and more particularity, to a lyocell dip cord and tire produced by a method comprising the steps of: (A) dissolving 0.01 to 3 wt % of cellulose powder in portions in concentrated liquid N-methylmorpholine N-oxide (NMMO) to prepare cellulose-containing NMMO solution; (B) feeding the NMMO solution and cellulose powder into an extruder having a screw to be subjected to dispersing, mixing, shearing, kneading, melting and measuring ability in the extruder to prepare a swollen and homogenized cellulose solution; (C) spinning the cellulose solution through a spinning nozzle, passing the spinning solution through an air gap to a coagulation bath and coagulating the spinning solution to obtain a multifilament; (D) subject the multifilament to water-wash, drying and oil-treatment, followed by winding; and (E) twisting the wound yarn with a twisting machine to prepare a greige cord, weaving the greige cord and dipping the woven cord in a dipping solution. According to the present invention, by lowering of solidification temperature of NMMO by dissolving a small amount of pulp in concentrated liquid NMMO, it is possible to prepare a homogeneous cellulose solution at a low temperature. Also, the lyocell dip cord prepared according to the present invention has excellent adhesion to rubber, tenacity and modulus. And, the tire in which the lyocell dip cord according to the present invention is applied to the carcass ply has excellent dimensional stability and handling stability.

    摘要翻译: 本发明涉及一种使用高强度莱赛尔浸渍帘线生产轮胎的方法,更具体地说,涉及通过包括以下步骤的方法生产的莱赛尔浸渍帘线和轮胎:(A)将0.01至3重量%的纤维素粉末溶解在 浓缩液体中的部分N-甲基吗啉N-氧化物(NMMO),以制备含纤维素的NMMO溶液; (B)将NMMO溶液和纤维素粉末加入到具有螺杆的挤出机中,以在挤出机中进行分散,混合,剪切,捏合,熔融和测量能力,以制备溶胀均匀的纤维素溶液; (C)通过纺丝喷嘴将纤维素溶液纺丝,使纺丝溶液通过气隙进入凝固浴并使纺丝溶液凝固得到复丝; (D)将复丝进行水洗,干燥和油处理,然后卷绕; 和(E)用捻线机缠绕纱线,以制备一条格子绳,编织细绳,将编织线浸入浸渍溶液中。 根据本发明,通过将少量纸浆溶解在浓缩液体NMMO中来降低NMMO的凝固温度,可以在低温下制备均匀的纤维素溶液。 此外,根据本发明制备的lyocell浸渍帘线对橡胶具有优异的粘合力,韧度和模量。 并且,将根据本发明的lyocell浸渍帘线应用于胎体帘布层的轮胎具有优异的尺寸稳定性和操作稳定性。

    Cellulose dip cord produced from highly homogeneous cellulose solution and tire using the same
    2.
    发明授权
    Cellulose dip cord produced from highly homogeneous cellulose solution and tire using the same 有权
    由高度均匀的纤维素溶液和使用其的轮胎生产的纤维素浸渍帘线

    公开(公告)号:US06983779B2

    公开(公告)日:2006-01-10

    申请号:US10874308

    申请日:2004-06-24

    IPC分类号: B60C9/00 D02G3/48

    摘要: The present invention relates to, and more particularily, to a lyocell dip cord and tire produced by a method comprising the steps of: (A) dissolving 0.01 to 3 wt % of cellulose powder in portions in concentrated liquid N-methylmorpholine N-oxide (NMMO) to prepare cellulose-containing NMMO solution; (B) feeding the NMMO solution and cellulose powder into an extruder having a screw to be subjected to dispersing, mixing, shearing, kneading, melting and measuring ability in the extruder to prepare a swollen and homogenized cellulose solution; (C) spinning the cellulose solution through a spinning nozzle, passing the spinning solution through an air gap to a coagulation bath and coagulating the spinning solution to obtain a multifilament; (D) subject the multifilament to water-wash, drying and oil-treatment, followed by winding; and (E) twisting the wound yarn with a twisting machine to prepare a greige cord, weaving the greige cord and dipping the woven cord in a dipping solution.

    摘要翻译: 更具体地说,本发明涉及通过包括以下步骤的方法生产的莱赛尔浸渍帘线和轮胎:(A)将0.01至3重量%的纤维素粉末部分地溶解在浓缩的N-甲基吗啉N-氧化物( NMMO)制备含纤维素的NMMO溶液; (B)将NMMO溶液和纤维素粉末加入到具有螺杆的挤出机中,以在挤出机中进行分散,混合,剪切,捏合,熔融和测量能力,以制备溶胀均匀的纤维素溶液; (C)通过纺丝喷嘴将纤维素溶液纺丝,使纺丝溶液通过气隙进入凝固浴并使纺丝溶液凝固得到复丝; (D)将复丝进行水洗,干燥和油处理,然后卷绕; 和(E)用捻线机缠绕纱线,以制备一条格子绳,编织细绳,将编织线浸入浸渍溶液中。

    Lyocell multifilament
    4.
    发明申请
    Lyocell multifilament 有权
    Lyocell复丝

    公开(公告)号:US20050019564A1

    公开(公告)日:2005-01-27

    申请号:US10874222

    申请日:2004-06-24

    摘要: The present invention relates to a high tenacity, high modulus and low shrinkage lyocell multifilament yarn suitable for use in tire cords and MRG (mechanical rubber goods). The lyocell multifilament yarn is a cellulose-based fiber for industrial applications, which is produced by dissolving pulp having a degree of polymerization (DPW) of 700-2,000 and preferably 800-1,400, and a α-cellulose content of more than 90% and preferably more than 92%, in N-methylmorpholine N-oxide (NMMO) hydrate, at a pulp concentration of 5-15% by weight and preferably 8-13% by weight. The lyocell monofilament according to the present invention is characterized by the following stress-strain profile: (1) the lyocell monofilament analyzed after drying is elongated by less than 3.0% and has an initial modulus of 150-400 g/d, when it was subjected to an initial stress of 3.0 g/d; (2) it is elongated by 3.0-7.0% when it was subjected to a stress greater than the initial stress but smaller than 6.0 g/d; and (3) it is elongated from a tensile tenacity of at least 6.0 g/d until the yarn is broken.

    摘要翻译: 本发明涉及适用于轮胎帘线和MRG(机械橡胶制品)的高韧性,高模量和低收缩率的莱赛尔复丝纱线。 莱赛尔复丝纱是用于工业应用的纤维素基纤维,其通过将具有700-2,000,优选800-1,400的聚合度(DPW)和大于90%的α-纤维素含量的纸浆溶解而制备,以及 优选大于92%的N-甲基吗啉N-氧化物(NMMO)水合物,纸浆浓度为5-15重量%,优选为8-13重量%。 根据本发明的裂解液单丝的特征在于以下应力 - 应变曲线:(1)干燥后分析的裂解细胞单丝伸长小于3.0%,初始模量为150-400g / d,当为 经受3.0g / d的初始应力; (2)当其施加大于初始应力但小于6.0g / d的应力时,其伸长3.0-7.0%; 和(3)从至少6.0g / d的拉伸强度拉伸至纱线断裂为止。

    Lyocell multifilament
    6.
    发明授权
    Lyocell multifilament 有权
    Lyocell复丝

    公开(公告)号:US06902804B2

    公开(公告)日:2005-06-07

    申请号:US10874222

    申请日:2004-06-24

    摘要: The present invention relates to a high tenacity, high modulus and low shrinkage lyocell multifilament yarn suitable for use in tire cords and MRG (mechanical rubber goods). The lyocell multifilament yarn is a cellulose-based fiber for industrial applications, which is produced by dissolving pulp having a degree of polymerization (DPW) of 700-2,000 and preferably 800-1,400, and a α-cellulose content of more than 90% and preferably more than 92%, in N-methylmorpholine N-oxide (NMMO) hydrate, at a pulp concentration of 5-15% by weight and preferably 8-13% by weight.The lyocell monofilament according to the present invention is characterized by the following stress-strain profile: (1) the lyocell monofilament analyzed after drying is elongated by less than 3.0% and has an initial modulus of 150-400 g/d, when it was subjected to an initial stress of 3.0 g/d; (2) it is elongated by 3.0-7.0% when it was subjected to a stress greater than the initial stress but smaller than 6.0 g/d; and (3) it is elongated from a tensile tenacity of at least 6.0 g/d until the yarn is broken.

    摘要翻译: 本发明涉及适用于轮胎帘线和MRG(机械橡胶制品)的高韧性,高模量和低收缩率的莱赛尔复丝纱线。 莱赛尔复丝纱是用于工业应用的纤维素基纤维,其通过将具有700-2,000,优选800-1,400的聚合度(DPNW)的纸浆溶解而制备, 纤维素含量在N-甲基吗啉N-氧化物(NMMO)水合物中大于90%,优选大于92%,纸浆浓度为5-15重量%,优选8-13重量%。 根据本发明的lyocell单丝的特征在于以下应力 - 应变曲线:(1)干燥后分析的裂解细胞单丝伸长小于3.0%,初始模量为150-400g / d,当为 经受3.0g / d的初始应力; (2)当其施加大于初始应力但小于6.0g / d的应力时,其伸长3.0-7.0%; 和(3)从至少6.0g / d的拉伸强度拉伸至纱线断裂为止。