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1.发明申请Phosphoric acid group-containing polymer electrolyte (composite) membrane and its production method 审中-公开含磷酸基聚合物电解质（复合）膜及其制备方法公开(公告)号：US20060293475A1
公开(公告)日：2006-12-28
申请号：US11511265
申请日：2006-08-29
申请人： Iko Ito , Masahiro Rikukawa
发明人： Iko Ito , Masahiro Rikukawa
IPC分类号： C08F30/02
CPC分类号： H01M2/1653 , C08F30/02 , C08F230/02 , H01B1/122 , H01M8/1027 , H01M8/1034 , H01M8/1039 , H01M8/106 , H01M8/1072 , H01M2300/0082 , H01M2300/0094 , Y02P70/56 , Y10T428/249962 , Y10T442/2418
摘要： The invention relates to solid polyelectrolyte membranes and processes for their production. As solid polyelectrolyte materials, there have been known fluoropolymers which have perfluoroskeletons and side chains bearing sulfonic acid groups and heat-resistant resins which have hydrocarbon skeletons and contain alkylsulfonic acid or alkylphosphoric acid groups introduced thereto. The fluoropolymers are excellent in heat resistance and chemical resistance but have the problem of being expensive, while the heat-resistant resins have the problem of being poor in chemical resistance. Further, solid polyelectrolyte materials having higher electric conductivities have been desired. With the purpose of providing solid polyelectrolyte membranes having satisfactorily high electric conductivities and being excellent in heat resistance and chemical resistance and processes for producing the membranes, solid polyelectrolyte membranes are made from resins bearing both phosphoric acid groups and sulfonic acid groups which resins are obtained by copolymerizing a monomer bearing in the molecule a phosphoric acid group and an ethylenically unsaturated bond with a monomer bearing in the molecule a sulfonic acid group and an ethylenically unsaturated bond.
摘要翻译： 本发明涉及固体聚电解质膜及其生产方法。 作为固体聚电解质材料，已知有具有全氟骨架和带有磺酸基团的侧链和具有烃骨架并含有引入其中的烷基磺酸或烷基磷酸基团的耐热树脂的含氟聚合物。 含氟聚合物的耐热性和耐化学性优异，但是具有昂贵的问题，而耐热树脂具有耐化学性差的问题。 此外，期望具有较高电导率的固体聚电解质材料。 为了提供具有令人满意的高电导率并且耐热性和耐化学性优异的固体聚电解质膜以及制造膜的方法，固体聚电解质膜由具有磷酸基和磺酸基的树脂制成，树脂通过 使分子中含有单体的磷酸基和烯键式不饱和键与分子中具有磺酸基和烯属不饱和键的单体共聚。
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2.发明授权Phosphoric acid group-containing polymer electrolyte (composite) membrane and its production method 有权含磷酸基聚合物电解质（复合）膜及其制备方法公开(公告)号：US07160968B2
公开(公告)日：2007-01-09
申请号：US10399628
申请日：2001-10-19
申请人： Iko Ito , Masahiro Rikukawa
发明人： Iko Ito , Masahiro Rikukawa
IPC分类号： C08F130/02
CPC分类号： H01M2/1653 , C08F30/02 , C08F230/02 , H01B1/122 , H01M8/1027 , H01M8/1034 , H01M8/1039 , H01M8/106 , H01M8/1072 , H01M2300/0082 , H01M2300/0094 , Y02P70/56 , Y10T428/249962 , Y10T442/2418
摘要： The invention relates to solid polyelectrolyte membranes and processes for their production. As solid polyelectrolyte materials, there have been known fluoropolymers which have perfluoroskeletons and side chains bearing sulfonic acid groups and heat-resistant resins which have hydrocarbon skeletons and contain alkylsulfonic acid or alkylphosphoric acid groups introduced thereto. The fluoropolymers are excellent in heat resistance and chemical resistance but have the problem of being expensive, while the heat-resistant resins have the problem of being poor in chemical resistance. Further, solid polyelectrolyte materials having higher electric conductivities have been desired. With the purpose of providing solid polyelectrolyte membranes having satisfactorily high electric conductivities and being excellent in heat resistance and chemical resistance and processes for producing the membranes, solid polyelectrolyte membranes are made from resins bearing both phosphoric acid groups and sulfonic acid groups which resins are obtained by copolymerizing a monomer bearing in the molecule a phosphoric acid group and an ethylenically unsaturated bond with a monomer bearing in the molecule a sulfonic acid group and an ethylenically unsaturated bond.
摘要翻译： 本发明涉及固体聚电解质膜及其生产方法。 作为固体聚电解质材料，已知有具有全氟骨架和带有磺酸基团的侧链和具有烃骨架并含有引入其中的烷基磺酸或烷基磷酸基团的耐热树脂的含氟聚合物。 含氟聚合物的耐热性和耐化学性优异，但是具有昂贵的问题，而耐热树脂具有耐化学性差的问题。 此外，期望具有较高电导率的固体聚电解质材料。 为了提供具有令人满意的高电导率并且耐热性和耐化学性优异的固体聚电解质膜以及制造膜的方法，固体聚电解质膜由具有磷酸基和磺酸基的树脂制成，树脂通过 使分子中含有单体的磷酸基和烯键式不饱和键与分子中具有磺酸基和烯属不饱和键的单体共聚。
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公开(公告)号：US08969430B2
公开(公告)日：2015-03-03
申请号：US12621274
申请日：2009-11-18
申请人： Mamoru Aizawa , Masahiro Rikukawa
发明人： Mamoru Aizawa , Masahiro Rikukawa
CPC分类号： A61L27/425 , A61L27/56
摘要： A hydroxyapatite ceramic hybrid material includes a hydroxyapatite ceramic structure having pores therein and a biodegradable polymer included in the pores in the hydroxyapatite ceramic structure. The biodegradable polymer can be a poly L-lactic acid polymer. A method for preparing a hydroxyapatite ceramic-biodegradable polymer hybrid material includes preparing a porous hydroxyapatite ceramic containing pores having an average pore diameter of 10 μm or larger; and forming a biodegradable polymer in the pores of the porous hydroxyapatite ceramic. The porous hydroxyapatite ceramic may be prepared by: preparing a slurry comprising hydroxyapatite fibers and heat-degradable particles in a selected solvent; filtering the slurry to obtain a paste; preparing a molded body using the paste; compacting the molded body to produce a green compact; and firing the green compact at a temperature at least 1000° C. to produce a porous hydroxyapatite ceramic structure.
摘要翻译： 羟基磷灰石陶瓷混合材料包括其中具有孔的羟基磷灰石陶瓷结构和包含在羟基磷灰石陶瓷结构的孔中的可生物降解的聚合物。 生物可降解聚合物可以是聚L-乳酸聚合物。 制备羟基磷灰石陶瓷可生物降解聚合物混合材料的方法包括制备含有平均孔径为10μm以上的孔的多孔羟基磷灰石陶瓷; 并在多孔羟基磷灰石陶瓷的孔中形成可生物降解的聚合物。 多孔羟基磷灰石陶瓷可以通过以下步骤制备：在选定的溶剂中制备包含羟基磷灰石纤维和可热降解颗粒的浆料; 过滤浆料得到糊状物; 使用糊料制备成型体; 压制成型体以产生生坯; 并在至少1000℃的温度下焙烧生坯，以产生多孔羟基磷灰石陶瓷结构。
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4.发明授权公开(公告)号：US08871167B2
公开(公告)日：2014-10-28
申请号：US13308459
申请日：2011-11-30
CPC分类号： A61L27/425 , A61L27/56
摘要： A hydroxyapatite ceramic hybrid material, which includes a biodegradable polymer included in the pores in a hydroxyapatite ceramic structure, and a method thereof, and a calcium phosphate porous body, which is formed by an intertwining of fibrous calcium phosphates and includes a plurality of first pores formed where the fibrous calcium phosphates interconnect and plurality of equal diameter substantially spherical second pores with a larger inside diameter than the first pores, and a method thereof are provided.
摘要翻译： 羟基磷灰石陶瓷混合材料，其包括羟基磷灰石陶瓷结构的孔中包含的生物可降解聚合物及其方法，以及磷酸钙多孔体，其通过纤维状磷酸钙的交织而形成，并且包括多个第一孔 其中纤维状磷酸钙互相连接，并且具有比第一孔更大的内径的多个等直径的大致球形的第二孔，以及其方法。
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公开(公告)号：US07740968B2
公开(公告)日：2010-06-22
申请号：US11722251
申请日：2005-12-20
CPC分类号： H01M4/8668 , C08F8/24 , C08F297/04 , H01B1/122 , H01M4/8605 , H01M4/8807 , H01M4/8896 , H01M8/1004 , H01M8/1023 , H01M8/1081 , Y02P70/56
摘要： This invention relates to an ion-conducting binder used for a membrane electrode assembly for polymer electrolyte fuel cells, the assembly consisting of a polymer electrolyte membrane and two gas diffusion electrodes stuck to the polymer electrolyte membrane with the membrane put between the electrodes, which binder comprises a block copolymer which comprises a polymer block (A) having as a main unit an aromatic vinyl compound unit whose α-carbon is quaternary carbon, and a flexible polymer block (B), and has ion-conducting groups on the polymer block (A), and a solution or suspension thereof, and a membrane electrode assembly and a polymer electrolyte fuel cell.The ion-conducting binder, membrane electrode assembly and polymer electrolyte fuel cell of this invention are economical, mild to the environment and excellent in moldability and oxidation stability.
摘要翻译： 本发明涉及一种用于聚合物电解质燃料电池的膜电极组件的离子传导性粘合剂，该组合物由聚合物电解质膜和粘附在聚合物电解质膜上的两个气体扩散电极组成，膜间置于电极之间，该粘合剂 包括嵌段共聚物，其包含以α-碳为季碳作为主要单元的聚合物嵌段（A）和柔性聚合物嵌段（B），并且在聚合物嵌段上具有离子传导性基团 A）及其溶液或悬浮液，以及膜电极组件和聚合物电解质燃料电池。 本发明的离子导电粘合剂，膜电极组件和聚合物电解质燃料电池是经济的，对环境温和，并且成型性和氧化稳定性优异。
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6.发明授权Phosphorus-containing polymer compound, synthesizing method thereof, antioxidant, high-durability polymer electrolyte composite, electrode, and fuel cell 失效含磷高分子化合物，其合成方法，抗氧化剂，高耐久性聚合物电解质复合材料，电极和燃料电池公开(公告)号：US07384996B2
公开(公告)日：2008-06-10
申请号：US10720469
申请日：2003-11-25
IPC分类号： C08K5/5317
CPC分类号： H01M4/8605 , C08F8/40 , C08G61/10 , C08G2261/312 , C08L65/02 , C09K15/322 , H01M8/1023 , H01M8/1051 , H01M2008/1095 , H01M2300/0082 , Y02P70/56
摘要： The invention provides phosphonated poly(4-phenoxybenzoyl-1,4-phenylene), and synthesizing method thereof, an antioxidant formed of phosphonated poly(4-phenoxybenzoyl-1,4-phenylene), a high-durability polymer electrolyte composite formed of a fluoropolymer electrolyte and phosphonated poly(4-phenoxybenzoyl-1,4-phenylene), and a fuel cell in which the high-durability polymer electrolyte composite is used in an electrode thereof.
摘要翻译： 本发明提供了膦酸化的聚（4-苯氧基苯甲酰基-1,4-亚苯基）及其合成方法，由磷酸化聚（4-苯氧基苯甲酰基-1,4-亚苯基）形成的抗氧化剂，由 含氟聚合物电解质和膦酸化聚（4-苯氧基苯甲酰基-1,4-亚苯基），以及在其电极中使用高耐久性聚合物电解质复合材料的燃料电池。
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7.发明申请公开(公告)号：US20120136088A1
公开(公告)日：2012-05-31
申请号：US13308459
申请日：2011-11-30
CPC分类号： A61L27/425 , A61L27/56
摘要： A hydroxyapatite ceramic hybrid material, which includes a biodegradable polymer included in the pores in a hydroxyapatite ceramic structure, and a method thereof, and a calcium phosphate porous body, which is formed by an intertwining of fibrous calcium phosphates and includes a plurality of first pores formed where the fibrous calcium phosphates interconnect and plurality of equal diameter substantially spherical second pores with a larger inside diameter than the first pores, and a method thereof are provided.
摘要翻译： 羟基磷灰石陶瓷混合材料，其包括羟基磷灰石陶瓷结构的孔中包含的生物可降解聚合物及其方法，以及磷酸钙多孔体，其通过纤维状磷酸钙的交织而形成，并且包括多个第一孔 其中纤维状磷酸钙互相连接，并且具有比第一孔更大的内径的多个等直径的大致球形的第二孔，以及其方法。
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公开(公告)号：US20100152317A1
公开(公告)日：2010-06-17
申请号：US12621274
申请日：2009-11-18
申请人： Mamoru Aizawa , Masahiro Rikukawa
发明人： Mamoru Aizawa , Masahiro Rikukawa
IPC分类号： A61L27/10
CPC分类号： A61L27/425 , A61L27/56
摘要： A hydroxyapatite ceramic hybrid material includes a hydroxyapatite ceramic structure having pores therein and a biodegradable polymer included in the pores in the hydroxyapatite ceramic structure. The biodegradable polymer can be a poly L-lactic acid polymer. A method for preparing a hydroxyapatite ceramic-biodegradable polymer hybrid material includes preparing a porous hydroxyapatite ceramic containing pores having an average pore diameter of 10 μm or larger; and forming a biodegradable polymer in the pores of the porous hydroxyapatite ceramic. The porous hydroxyapatite ceramic may be prepared by: preparing a slurry comprising hydroxyapatite fibers and heat-degradable particles in a selected solvent; filtering the slurry to obtain a paste; preparing a molded body using the paste; compacting the molded body to produce a green compact; and firing the green compact at a temperature at least 1000° C. to produce a porous hydroxyapatite ceramic structure.
摘要翻译： 羟基磷灰石陶瓷混合材料包括其中具有孔的羟基磷灰石陶瓷结构和包含在羟基磷灰石陶瓷结构的孔中的可生物降解的聚合物。 生物可降解聚合物可以是聚L-乳酸聚合物。 制备羟基磷灰石陶瓷可生物降解聚合物混合材料的方法包括制备含有平均孔径为10μm以上的孔的多孔羟基磷灰石陶瓷; 并在多孔羟基磷灰石陶瓷的孔中形成可生物降解的聚合物。 多孔羟基磷灰石陶瓷可以通过以下步骤制备：在选定的溶剂中制备包含羟基磷灰石纤维和可热降解颗粒的浆料; 过滤浆料得到糊状物; 使用糊料制备成型体; 压制成型体以产生生坯; 并在至少1000℃的温度下焙烧生坯，以产生多孔羟基磷灰石陶瓷结构。
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公开(公告)号：US20080113244A1
公开(公告)日：2008-05-15
申请号：US11722251
申请日：2005-12-20
CPC分类号： H01M4/8668 , C08F8/24 , C08F297/04 , H01B1/122 , H01M4/8605 , H01M4/8807 , H01M4/8896 , H01M8/1004 , H01M8/1023 , H01M8/1081 , Y02P70/56
摘要： This invention relates to an ion-conducting binder used for a membrane electrode assembly for polymer electrolyte fuel cells, the assembly consisting of a polymer electrolyte membrane and two gas diffusion electrodes stuck to the polymer electrolyte membrane with the membrane put between the electrodes, which binder comprises a block copolymer which comprises a polymer block (A) having as a main unit an aromatic vinyl compound unit whose α-carbon is quaternary carbon, and a flexible polymer block (B), and has ion-conducting groups on the polymer block (A), and a solution or suspension thereof, and a membrane electrode assembly and a polymer electrolyte fuel cell.The ion-conducting binder, membrane electrode assembly and polymer electrolyte fuel cell of this invention are economical, mild to the environment and excellent in moldability and oxidation stability.
摘要翻译： 本发明涉及一种用于聚合物电解质燃料电池的膜电极组件的离子传导性粘合剂，该组合物由聚合物电解质膜和粘附在聚合物电解质膜上的两个气体扩散电极组成，膜间置于电极之间，该粘合剂 包括嵌段共聚物，其包含以α-碳为季碳作为主要单元的聚合物嵌段（A）和柔性聚合物嵌段（B），并且在聚合物嵌段上具有离子传导性基团 A）及其溶液或悬浮液，以及膜电极组件和聚合物电解质燃料电池。 本发明的离子导电粘合剂，膜电极组件和聚合物电解质燃料电池是经济的，对环境温和，并且成型性和氧化稳定性优异。
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公开(公告)号：US5403675A
公开(公告)日：1995-04-04
申请号：US45968
申请日：1993-04-09
申请人： Naoya Ogata , Masahiro Rikukawa
发明人： Naoya Ogata , Masahiro Rikukawa
CPC分类号： G01N27/404 , C07C45/46 , C08J5/2256 , C25B9/10 , H01M2/1653 , H01M6/181 , H01M8/1023 , H01M8/1025 , H01M8/1034 , H01M8/1039 , C08J2365/00
摘要： Sulfonated polyphenylene solid polymer electrolytes having high proton conductivity are provided, which are stable and which maintain high conductivity at temperatures of 100.degree. C. and above. These membranes are useful as solid polymer electrolytes for fuel cells and can be operated above the boiling point of water.
摘要翻译： 提供了具有高质子传导性的磺化聚苯撑固体聚合物电解质，它们是稳定的，并且在100℃及以上的温度下保持高导电性。 这些膜可用作燃料电池的固体聚合物电解质，并且可以在水的沸点以上操作。
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