Resin molded article and method for producing the same
    4.
    发明授权
    Resin molded article and method for producing the same 失效
    树脂成形体及其制造方法

    公开(公告)号:US06610236B1

    公开(公告)日:2003-08-26

    申请号:US09719137

    申请日:2000-12-08

    IPC分类号: B29C7102

    摘要: A resin molded article having a contact angle of water of 50 degrees or less on its surface is produced by molding a thermoplastic or thermosetting resin composition containing a polymer having a perfluoroalkyl group of a (meth)acrylate having a perfluoroalkyl group and a (meth)acrylate having a hydrophilic group, or a compound having a perfluoroalkyl group which is obtained by reacting an epoxy compound having a perfluoroalkyl group with a polyalkylene oxide having a terminal hydroxyl group, and heating the molded article. The molded article has a hydrophilic surface and improved stain-proofing properties.

    摘要翻译: 通过将含有具有全氟烷基的(甲基)丙烯酸酯的全氟烷基的聚合物的热塑性或热固性树脂组合物与(甲基)丙烯酸烷基酯共聚物的热塑性或热固性树脂组合物成型,制造其表面上的水接触角为50度以下的树脂成形品, 具有亲水基团的丙烯酸酯或具有全氟烷基的化合物,其通过使具有全氟烷基的环氧化合物与具有末端羟基的聚环氧烷反应获得,并加热该成型制品。 模制品具有亲水性表面和改善的防污性能。

    Water and oil-repellent resin composition
    5.
    发明授权
    Water and oil-repellent resin composition 有权
    防水防油树脂组合物

    公开(公告)号:US06225405B1

    公开(公告)日:2001-05-01

    申请号:US09284261

    申请日:1999-05-07

    IPC分类号: A62C502

    摘要: A resin composition comprising 100 parts by weight of a thermoplastic resin or thermosetting resin and 0.1 to 5 parts by weight of at least one perfluoroalkyl group-containing polymer selected from the group consisting of a copolymer of a (meth)acrylic ester having a perfluoroalkyl group of 5-18 carbon atoms and a (meth)acrylic ester having a hydrophilic group, a homopolymer of an epoxy compound having a perfluoroalkyl group of 5-18 carbon atoms, and a copolymer of said epoxy compound and a monomer copolymerizable therewith has excellent stain resistance, and is suitable for producing molded products undergoing severe adhesion of dirt such as kitchen wares, bathroom wares and the like.

    摘要翻译: 一种树脂组合物,其包含100重量份的热塑性树脂或热固性树脂和0.1至5重量份的至少一种含全氟烷基的聚合物,所述聚合物选自具有全氟烷基的(甲基)丙烯酸酯的共聚物 5-18个碳原子的(甲基)丙烯酸酯,具有亲水基团的(甲基)丙烯酸酯,具有5-18个碳原子的全氟烷基的环氧化合物的均聚物和所述环氧化合物与可共聚的单体的共聚物具有优异的着色性 并且适用于生产严重粘附诸如厨房用品,浴室用品等的污垢的成型产品。

    Fluoropolymer, process for preparing the same, and use thereof
    6.
    发明授权
    Fluoropolymer, process for preparing the same, and use thereof 有权
    含氟聚合物,其制备方法及其用途

    公开(公告)号:US06337135B1

    公开(公告)日:2002-01-08

    申请号:US09423010

    申请日:1999-10-29

    IPC分类号: B23B2706

    摘要: A fluorine-containing polymer, having a number-average molecular weight of 500 to 100,000 and represented by the following general formula Rf—(OC3F6)a—(OC2F4)b—(OCF2)c—X—Y—Z—MPnRm−n or PnRm−nM—Z—Y—X—(OC3F6)a—(OC2F4)b—(OCF2)c—X—Y—Z—MPnRm−n (wherein Rf is a perfluoroalkyl group; a, b and c independently represent 0 or a number equal to or greater than 1, with the proviso that the sum of a, b and c is at least 1; X is a group represented by the formula: —(O)d—(CF2)e—(CH2)f—; Y is a divalent polar group; Z is a group represented by the formula: —(CH2)g—; M is a metal atom; R is a hydrocarbon group; P is a hydrolyzable polar group; m is an integer equal to “(valency of M)−1”; and n is an integer of 1 to m), exhibits excellent stainproof property against oily dirt and can form on a substrate a stainproof layer having an excellent stainproof property against particularly fingerprints.

    摘要翻译: 数均分子量为500〜100000,由以下通式表示的含氟聚合物Rf-(OC3F6)a-(OC2F4)b-(OCF2)cXYZ-MPnRm-n或PnRm-nM-ZYX - (OC3F6)a-(OC2F4)b-(OCF2)cXYZ-MPnRm-n(其中Rf是全氟烷基; a,b和c独立地表示0或等于或大于1的数,条件是 a,b和c的和为至少1; X为下式所示的基团: - (O)d-(CF 2)e - (CH 2)f - ; Y为二价极性基; Z为 通式为:(CH 2)g-; M为金属原子; R为烃基; P为可水解的极性基团; m为等于“(M价)-1”的整数; n为 整数1〜m)表现出优异的防油污性,能够在基材上形成防污染特性优异的防污层。