摘要:
A catalyst and process for purifying crude terephthalic acid wherein the catalyst is prepared by contacting a carbonaceous support with an aqueous solution of sodium tetranitropalladate.
摘要:
A catalyst and process for purifying crude terephthalic acid wherein the catalyst is prepared by contacting a carbonaceous support with an aqueous solution of sodium tetranitropalladate.
摘要:
A catalyst and process for purifying crude terephthalic acid wherein the catalyst comprises palladium metal crystallites deposited upon a carbon support wherein the catalyst is prepared by contacting a carbonaceous support with an aqueous solution of a palladium amine complex in the presence of acetic acid.
摘要:
A process for producing a purified terephthalic acid which comprises reacting in a liquid phase a mixture of hydrogen and crude terephthalic acid, a palladium/rhodium catalyst on a porous carbonaceous support wherein the catalyst compound is prepared by adsorbing palladium on the support from a complex salt formed in the presence of an amine and acetic acid, followed by deposition of rhodium from a solution of sodium hexanitritorhodate.
摘要:
A process for producing a purified terephthalic acid which comprises reacting in a liquid phase a mixture of hydrogen and crude terephthalic acid, a palladium/rhodium catalyst on a porous carbonaceous support wherein the catalyst compound is prepared by adsorbing palladium on the support from a complex salt formed in the presence of an amine and acetic acid, followed by deposition of rhodium from a solution of sodium hexanitritorhodate.
摘要:
A process for producing fiber grade terephthalic acid is disclosed. In this process impurities having high molecular weight are eliminated by hydrogenation comprising the following steps: (a) treating an aqueous solution containing at least about 1 percent of said impure terephthalic acid with hydrogen at a temperature in the range of about 300.degree. F. to about 450.degree. F. and at a pressure sufficient to maintain the solution in the liquid phase in the presence of a supported or unsupported metallic Group VIII noble metal catalyst wherein both the metal and support components are insoluble in the solution at the temperature and at a hydrogen partial pressure of from about 30 to about 300 pounds per square inch; (b) separating the treated solution from the catalyst; (c) crystallizing terephthalic acid from the separated solution while retaining impurities and the reduced aromatic compounds dissolved in the resulting mother liquor at a temperature in the range of about 100.degree. F. to about 450.degree. F.; and (d) separating the mother liquor as a liquid phase containing dissolved impurities and reduction products from said crystals while continuing to maintain a temperature in the range of about 100.degree. F. to about 450.degree. F. whereby purified crystals of fiber grade terephthalic acid are recovered. Purified terephthalic acid is useful as a starting material in the manufacture of polyethylene terephthalate which is the principal polymer for polyester fibers, films, and resins for bottles.
摘要:
A method is disclosed for separating and measuring the fluorescence of 4-carboxy-p-terphenyl in crude terephthalic acid formed by the liquid-phase oxidation of p-xylene in a solvent.
摘要:
Configurable animal housing (caging) is arranged from an assortment of modules consisting of interchangeable frame cores, interstages, walls and divider panels that address a broad spectrum of animal housing needs. Various configurations include both open living and enrichment areas as well as isolation housing and are easily achieved using a quick-disconnect approach to assembly. Animal resistant lock assemblies hold modules together and use a common key to permit rapid changes of configuration without tools. Systems can address configurations for wall mounting, mobile racking, individual, and group housing, and almost any other configuration animal caregivers would want.
摘要:
Processes for producing aromatic monomers useful for forming polyesters are disclosed. Cost effective steps employed in the processes permit small amounts of process-related materials typically removed from monomer to remain in an aromatic monomer product. In many cases, the presence of the process-related materials left in the monomer product by the cost effective process steps can enhance the performance of the monomer in certain applications. Aromatic monomer products and polymers produced therefrom having these advantages also are disclosed, as well as products such as pasteurizable bottles made from these polymers.
摘要:
An improved CFB reactor or combustor arrangement has at least a first and a second group of impact type particle separators or U-beams with cooling surfaces located adjacent and immediately upstream of the second group of U-beams which serve to cool flue gas/solids flowing through the CFB before it reaches the second group of U-beams. By reducing the gas temperature in the vicinity of and entering the second group of U-beams, the U-beams can be made of less expensive materials and are thus less expensive to produce and maintain. The heat absorbed by the local cooling surfaces can be applied to heat a working fluid supplied to a turbine or other process.