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公开(公告)号：US20110257350A1
公开(公告)日：2011-10-20
申请号：US13066077
申请日：2011-04-06
申请人： Isam Jaber , Charles Ashton Garret Carter , Eric Clavelle , Andrzej Krzywicki , Ian Ronald Jobe , P. Scott Chisholm , Kamal Elias Serhal , Russell Kirk Archer , Keith Wayne Besenski
发明人： Isam Jaber , Charles Ashton Garret Carter , Eric Clavelle , Andrzej Krzywicki , Ian Ronald Jobe , P. Scott Chisholm , Kamal Elias Serhal , Russell Kirk Archer , Keith Wayne Besenski
IPC分类号： C08F110/02 , C08F4/22 , C08F2/06
CPC分类号： C08F10/00 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/62 , B01J2540/22 , C07C2/36 , C07C2531/14 , C07C2531/24 , C08F110/02 , Y02P20/52 , C08F2500/02 , C08F4/69267 , C07C11/02 , C07C11/107
摘要： Ethylene is selectively oligomerized in a continuously stirred tank reactor (CSTR) that is preferably operated in an isothermal manner using a chromium catalyst. The undesired formation of by-product polyethylene is mitigated by contacting the ethylene with hydrogen prior to adding the ethylene to the reactor and feeding the ethylene and hydrogen via a common feed port.
摘要翻译： 乙烯在连续搅拌的罐式反应器（CSTR）中选择性低聚，优选使用铬催化剂以等温方式操作。 在将乙烯加入到反应器中并通过共同的进料口进料乙烯和氢气之前，通过使乙烯与氢接触来减轻副产物聚乙烯的不期望的形成。
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公开(公告)号：US20120142989A1
公开(公告)日：2012-06-07
申请号：US13293889
申请日：2011-11-10
申请人： Isam Jaber , Ian Ronald Jobe , P. Scott Chisholm , Andrzej Krzywicki , Charles Ashton Garret Carter , Vernon Lindsay Strom , Kamal l Elias Serhal , Eric Clavelle , Stephen John Brown , Yves Lacombe , Anita Sylvia Magis , Mackenzie Alexander Harris , Russell Kirk Archer , Keith Wayne Besenski , Michel Berghmans , Oleksiy Golovchenko , Dale Alexander Sieben
发明人： Isam Jaber , Ian Ronald Jobe , P. Scott Chisholm , Andrzej Krzywicki , Charles Ashton Garret Carter , Vernon Lindsay Strom , Kamal l Elias Serhal , Eric Clavelle , Stephen John Brown , Yves Lacombe , Anita Sylvia Magis , Mackenzie Alexander Harris , Russell Kirk Archer , Keith Wayne Besenski , Michel Berghmans , Oleksiy Golovchenko , Dale Alexander Sieben
IPC分类号： C07C2/02
CPC分类号： C07C2/36 , C07C2523/26 , C07C2531/14 , C07C2531/24 , Y02P20/52 , C07C11/107 , C07C11/02
摘要： The oligomerization of ethylene using a chromium catalyst having a heteroatomic ligand may be used to provide oligomerization products that are selective towards hexene and/or octene. However, such processes also typically produce some polymer as an undesirable by product. The present invention is directed towards improvements in the selective oligomerization of ethylene.
摘要翻译： 可以使用具有杂原子配位体的铬催化剂使乙烯低聚来提供对己烯和/或辛烯有选择性的低聚产物。 然而，这些方法也通常产生一些聚合物作为不期望的产物。 本发明涉及改进乙烯的选择性低聚。
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公开(公告)号：US20120271087A1
公开(公告)日：2012-10-25
申请号：US13431442
申请日：2012-03-27
申请人： Stephen John Brown , Charles Ashton Garret Carter , P. Scott Chisholm , Isam Jaber , Ian Ronald Jobe , Oleksiy Golovchenko
发明人： Stephen John Brown , Charles Ashton Garret Carter , P. Scott Chisholm , Isam Jaber , Ian Ronald Jobe , Oleksiy Golovchenko
IPC分类号： C07C2/30
CPC分类号： C07C2/36 , C07C2531/12 , C07C2531/24 , C07C11/107
摘要： The oligomerization of ethylene using a chromium catalyst and an aluminoxane activator is well known. The undesired formation of polyethylene as a by-product is also known to occur during prior oligomerization processes. We have discovered that the use of an aluminoxane that is prepared by non-hydrolytic means provides a highly productive activator (co-catalyst) for ethylene oligomerization and mitigates the undesired formation of by-product polyethylene.
摘要翻译： 使用铬催化剂和铝氧烷活化剂的乙烯的低聚是公知的。 作为副产物的聚乙烯的不期望的形成也已知在先前的低聚反应过程中发生。 我们已经发现，使用由非水解方法制备的铝氧烷提供了用于乙烯低聚的高效活性剂（助催化剂），并减轻了副产物聚乙烯的不期望的形成。
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公开(公告)号：US20120101321A1
公开(公告)日：2012-04-26
申请号：US13200287
申请日：2011-09-22
IPC分类号： C07C2/36
CPC分类号： C07C2/36 , B01J31/143 , B01J31/24 , B01J2231/20 , B01J2531/0238 , B01J2531/62 , C07C2531/14 , C07C2531/24 , C07C11/02
摘要： The oligomerization of ethylene using a chromium catalyst having a bridged diphosphine ligand can produce a selective product distribution (to predominantly hexene or predominantly octene/hexene) when activated with an aluminoxane. The oligomerization reaction also produces polymer by product—particularly when the aluminoxane is provided in a non-aromatic solvent. The present invention mitigates this problem.
摘要翻译： 当用铝氧烷活化时，使用具有桥连二膦配体的铬催化剂的乙烯的低聚可以产生选择性产物分布（主要是己烯或主要是辛烯/己烯）。 低聚反应还通过产物产生聚合物，特别是当在非芳族溶剂中提供铝氧烷时。 本发明减轻了这个问题。
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5.发明申请BULK ETHYLENE OLIGOMERIZATION USING A LOW CONCENTRATION OF CHROMIUM CATALYST AND THREE-PART ACTIVATOR 审中-公开使用低浓度的铬催化剂和三部分活化剂的大豆乙烯低聚公开(公告)号：US20140142360A1
公开(公告)日：2014-05-22
申请号：US14232038
申请日：2012-07-25
申请人： Stephen John Brown , Charles Ashton Garret Carter , P. Scott Chisholm , Peter Zoricak , Oleksiy Golovchenko
发明人： Stephen John Brown , Charles Ashton Garret Carter , P. Scott Chisholm , Peter Zoricak , Oleksiy Golovchenko
IPC分类号： C07C2/30
CPC分类号： C07C2/30 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/62 , B01J2540/22 , C07C2/36 , C07C2531/14 , C07C2531/24 , C07C11/02
摘要： This invention enables the “bulk” oligomerization of ethylene (i.e. the oligomerization of ethylene in the presence of the oligomer product) using a catalyst system comprising 1) a very low concentration of a chromium catalyst and 2) a three part activator. The chromium catalyst contains a diphosphine ligand, preferably a so called P—N—P ligand. The activator includes an aluminoxane, trimethyl aluminum, and triethyl aluminum.
摘要翻译： 本发明使得能够使用包含1）非常低浓度的铬催化剂和2）三部分活化剂的催化剂体系来实现乙烯的“本体”低聚（即在低聚物产物存在下乙烯的低聚）。 铬催化剂含有二膦配体，优选所谓的P-N-P配体。 活化剂包括铝氧烷，三甲基铝和三乙基铝。
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公开(公告)号：US20110282016A1
公开(公告)日：2011-11-17
申请号：US13068342
申请日：2011-05-09
IPC分类号： C08F4/78
CPC分类号： C07C2/36 , B01J31/122 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/62 , B01J2540/22 , C07C2531/12 , C07C2531/14 , C08F110/02 , C08F2410/01 , C08F2500/02 , C07C11/02
摘要： The oligomerization of ethylene using a chromium catalyst having a phosphorus-nitrogen-phosphorus (“P—N—P”) ligand is typically activated with an aluminoxane. The addition of an alkyl zinc, particularly diethyl zinc, has been fund to improve the productivity of certain oligomerization reactions. In particular, the addition of diethyl zinc to an oligomerization reaction that is activated by methylaluminoxane (MAO) improves the productivity of the reaction.
摘要翻译： 使用具有磷 - 氮 - 磷（“P-N-P”）配体的铬催化剂的乙烯的低聚通常用铝氧烷活化。 烷基锌，特别是二乙基锌的添加已被用于提高某些低聚反应的生产率。 特别地，将二乙基锌加入由甲基铝氧烷（MAO）活化的低聚反应提高了反应的生产率。
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公开(公告)号：US20130345377A1
公开(公告)日：2013-12-26
申请号：US13918506
申请日：2013-06-14
申请人： Victoria Ker , Patrick Lam , Yan Jiang , Peter Phung Minh Hoang , Darryl J. Morrison , Charles Ashton Garret Carter
发明人： Victoria Ker , Patrick Lam , Yan Jiang , Peter Phung Minh Hoang , Darryl J. Morrison , Charles Ashton Garret Carter
IPC分类号： C08F210/16
CPC分类号： C08J5/18 , B32B27/32 , C08F4/65916 , C08F4/6592 , C08F210/16 , C08F2410/01 , C08F2410/02 , C08F2420/04 , C08J2323/08 , C08F210/14 , C08F2500/10 , C08F2500/12 , C08F2500/06 , C08F2500/11
摘要： Ethylene copolymers having a relatively high melt flow ratio and a multimodal profile in a temperature rising elution fractionation (TREF) plot are disclosed. The copolymers can be made into film having good dart impact values and good stiffness properties under decreased extruder pressures.
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公开(公告)号：US08252956B2
公开(公告)日：2012-08-28
申请号：US13135100
申请日：2011-06-24
CPC分类号： C08F10/00 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/62 , B01J2540/22 , C07C2/36 , C07C2531/14 , C07C2531/24 , C07F9/46 , C08F110/02 , C08F4/22 , C08F2500/02 , C08F4/69267 , C07C11/02 , C07C11/107
摘要： A new P-N-P ligand in which each phosphorus atom is bonded to two ortho-fluorine substituted phenyl groups is useful in ethylene oligomerizations. In combination with i) a source of chromium and ii) an activator such as methalumoxane; the ligand of this invention may be used to prepare an oligomer product that contains a mixture of hexenes and octenes. The hexenes and octenes produced with this ligand contain very low levels of internal olefins when produced under preferred reaction conditions.
摘要翻译： 每个磷原子与两个邻氟取代的苯基键合的新的P-N-P配体可用于乙烯低聚。 与i）铬源，和ii）活化剂如甲基铝氧烷; 本发明的配体可用于制备含有己烯和辛烯的混合物的低聚物产物。 当在优选的反应条件下产生时，用该配体产生的己烯和辛烯含有非常低水平的内烯烃。
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公开(公告)号：US20110257352A1
公开(公告)日：2011-10-20
申请号：US13135100
申请日：2011-06-24
IPC分类号： C08F4/78
CPC分类号： C08F10/00 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/62 , B01J2540/22 , C07C2/36 , C07C2531/14 , C07C2531/24 , C07F9/46 , C08F110/02 , C08F4/22 , C08F2500/02 , C08F4/69267 , C07C11/02 , C07C11/107
摘要： A new P-N-P ligand in which each phosphorus atom is bonded to two ortho-fluorine substituted phenyl groups is useful in ethylene oligomerizations. In combination with i) a source of chromium and ii) an activator such as methalumoxane; the ligand of this invention may be used to prepare an oligomer product that contains a mixture of hexenes and octenes. The hexenes and octenes produced with this ligand contain very low levels of internal olefins when produced under preferred reaction conditions.
摘要翻译： 每个磷原子与两个邻氟取代的苯基键合的新的P-N-P配体可用于乙烯低聚。 与i）铬源，和ii）活化剂如甲基铝氧烷; 本发明的配体可用于制备含有己烯和辛烯的混合物的低聚物产物。 当在优选的反应条件下产生时，用该配体产生的己烯和辛烯含有非常低水平的内烯烃。
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公开(公告)号：US07994363B2
公开(公告)日：2011-08-09
申请号：US12077565
申请日：2008-03-20
IPC分类号： C07F9/02
CPC分类号： C08F10/00 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/62 , B01J2540/22 , C07C2/36 , C07C2531/14 , C07C2531/24 , C07F9/46 , C08F110/02 , C08F4/22 , C08F2500/02 , C08F4/69267 , C07C11/02 , C07C11/107
摘要： A new P-N-P ligand in which each phosphorus atom is bonded to two ortho-fluorine substituted phenyl groups is useful in ethylene oligomerizations. In combination with i) a source of chromium and ii) an activator such as methalumoxane; the ligand of this invention may be used to prepare an oligomer product that contains a mixture of hexenes and octenes. The hexenes and octenes produced with this ligand contain very low levels of internal olefins when produced under preferred reaction conditions.
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