公开(公告)号：US4888268A

公开(公告)日：1989-12-19

申请号：US234008

申请日：1988-08-16

申请人： Isamu Itoh ,  Mitsunori Ono ,  Yoshio Inagaki

发明人： Isamu Itoh ,  Mitsunori Ono ,  Yoshio Inagaki

IPC分类号： G03C7/305

CPC分类号： G03C7/30511 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/159 ,  Y10S430/161

摘要： A silver halide photographic material, which contains at least one blocked photographic reagent having in the molecule thereof at least one group selected from ##STR1## group and capable of releasing a photographically useful reagent by cleavage of the --N--C--bond by a nucleophilic attack of a nucleophilic reagent on the carbonyl group and a subsequent intramolecular electron transfer reaction or intramolecular nucleophilic reaction and which has at least one photosensitive silver halide emulsion layer, is photographically processed in the presence of an amine. A photographic material which includes, in combination, a photographic reagent precursor capable of releasing a photographically useful reagent timely on photographic processing and a photosensitive silver halide emulsion layer is provided along with a method of processing the photographic material.

摘要翻译： 一种卤化银照相材料，其含有至少一种在其分子中具有至少一个选自“IMAGE”组的基团的封闭的照相试剂，并且能够通过亲核攻击来切割-NC键而释放照相用试剂 羰基上的亲核试剂和随后的分子内电子转移反应或分子内亲核反应并且具有至少一个光敏卤化银乳剂层，在胺的存在下进行照相处理。 提供了一种照相材料，其组合包括能够及时在照相处理和感光卤化银乳剂层上释放照相用试剂的照相试剂前体以及处理照相材料的方法。

公开(公告)号：US4743595A

公开(公告)日：1988-05-10

申请号：US743956

申请日：1985-06-12

申请人： Isamu Itoh ,  Mitsunori Ono ,  Hidetoshi Kobayashi ,  Kazuyoshi Yamakawa

发明人： Isamu Itoh ,  Mitsunori Ono ,  Hidetoshi Kobayashi ,  Kazuyoshi Yamakawa

IPC分类号： C07C213/00 ,  C07C215/76 ,  C07C233/75 ,  C07D233/60 ,  C07D263/56 ,  C07D263/57 ,  C07D295/08 ,  C07D307/68 ,  C07D413/04 ,  C07D413/12 ,  C09B29/00 ,  C07C149/42 ,  C07C87/60 ,  C07C91/40 ,  C07C103/87

CPC分类号： C07D263/56 ,  C07D263/57 ,  C07D307/68 ,  C07D413/04

摘要： A process for efficiently preparing 2-amino-5-nitrophenol derivatives in which benzoxazole derivatives are subjected to nucleophilic substitution reaction at the 5 position thereof to obtain corresponding benzoxazole derivatives, and the oxazole ring of the benzoxazole derivatives is then subjected to ring-opening to obtain 2-amino-5-nitrophenol derivatives. The 2-amino-5-nitrophenol derivatives are useful as industrial starting materials, reducing agents or antioxidants and intermediates for cyan-image-forming couplers.

摘要翻译： 一种有效制备其中苯并恶唑衍生物在其5位进行亲核取代反应以获得相应的苯并恶唑衍生物的2-氨基-5-硝基苯酚衍生物的方法，然后将苯并恶唑衍生物的恶唑环进行开环 得到2-氨基-5-硝基苯酚衍生物。 2-氨基-5-硝基苯酚衍生物可用作工业起始材料，还原剂或抗氧化剂以及用于青色成像成色剂的中间体。

公开(公告)号：US4734353A

公开(公告)日：1988-03-29

申请号：US857505

申请日：1986-04-21

申请人： Mitsunori Ono ,  Isamu Itoh ,  Keiji Mihayashi

发明人： Mitsunori Ono ,  Isamu Itoh ,  Keiji Mihayashi

IPC分类号： G03C7/26 ,  G03C1/10 ,  G03C1/43 ,  G03C5/305 ,  G03C7/305 ,  G03C5/54 ,  G03C5/26

CPC分类号： G03C7/305 ,  G03C1/10 ,  G03C1/43 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/16

摘要： A method for processing a silver halide photographic light-sensitive material comprising a support having thereon a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent capable of releasing a photographically useful agent, which method comprises processing the photographic light-sensitive material in the presence of an oxime.According to this method for processing a silver halide photographic light-sensitive material, both stability of the photographic light-sensitive material during storage and release of a photographically useful agent during processing are achieved without undersirable side-reactions, and a high sensitivity/fog ratio is obtained.

摘要翻译： 一种用于处理卤化银照相感光材料的方法，其包括其上具有感光卤化银乳剂层的载体，其具有能够释放照相用的试剂的封闭的照相剂，该方法包括处理照相感光材料 在肟的存在下。 根据这种用于处理卤化银照相感光材料的方法，在加工过程中摄影感光材料在照相感光材料的储存和释放期间的稳定性都达不到不需要的副反应，并且高灵敏度/雾度比 获得。

公开(公告)号：US4500636A

公开(公告)日：1985-02-19

申请号：US574432

申请日：1984-01-27

申请人： Mitsunori Ono ,  Isamu Itoh ,  Keiji Mihayashi ,  Yukio Karino

发明人： Mitsunori Ono ,  Isamu Itoh ,  Keiji Mihayashi ,  Yukio Karino

IPC分类号： G03C7/26 ,  C07D405/12 ,  G03C1/06 ,  G03C1/42 ,  G03C7/305 ,  G03C1/02

CPC分类号： C07D405/12 ,  G03C1/06 ,  G03C7/30511 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/159 ,  Y10S430/16 ,  Y10S430/161

摘要： A silver halide photographic light-sensitive material which comprises a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent, said blocked photographic agent being represented by the following general formula (I): ##STR1## wherein A represents a photographic agent moiety which is attached to a blocking moiety through a hetero atom; Z represents a divalent linkage group; p represents 0 or 1; X and Y each represents a substituent: m represents an integer of 0 to 4: and n represents an integer of 0 to 5.

摘要翻译： 一种卤化银照相感光材料，其包含与其相关联的感光卤化银乳剂层，其中封闭的照相剂，所述封闭的照相剂由以下通式（I）表示：其中A表示 通过杂原子连接到阻挡部分的照相剂部分; Z表示二价连接基团; p表示0或1; X和Y各自表示取代基：m表示0〜4的整数，n表示0〜5的整数。

公开(公告)号：US4842985A

公开(公告)日：1989-06-27

申请号：US130127

申请日：1987-12-08

申请人： Mitsunori Ono ,  Koji Tamoto ,  Keiji Mihayashi ,  Seiji Ichijima ,  Isamu Itoh ,  Yoshisada Nakamura

发明人： Mitsunori Ono ,  Koji Tamoto ,  Keiji Mihayashi ,  Seiji Ichijima ,  Isamu Itoh ,  Yoshisada Nakamura

IPC分类号： G03C7/26 ,  G03C7/305 ,  G03C7/32 ,  G03C7/392

CPC分类号： G03C7/30547 ,  G03C7/39224 ,  Y10S430/159

摘要： A conventional silver halide color photographic material is described, containing a coupler having a dye moiety having the maximum absorption wave length shifted to a short wave length by a linkage which is cleaved directly or through a timing group by a coupling reaction with the oxidation product of a developing agent and forming a compound or the precursor thereof (compound A) having a dye moiety having the maximum absorption wave length before shifting as the result of the above-described reaction and a compound capable of fixing the hue of the compound A at a long wave length and/or capable of immobilizing the compound A in the photographic layer.

摘要翻译： 描述了一种常规的卤化银彩色照相材料，其包含具有最大吸收波长长度移动到短波长的染料部分的成色剂，所述染料部分通过直接切割的连接或通过与氧化产物的偶联反应通过定时基团 显影剂，并形成化合物或其前体（化合物A），其具有作为上述反应的结果具有移位前最大吸收波长的染料部分的化合物或其前体（化合物A）和能够将化合物A的色调固定在 长波长和/或能够将化合物A固定在照相层中。

公开(公告)号：US4831152A

公开(公告)日：1989-05-16

申请号：US744571

申请日：1985-06-14

申请人： Isamu Itoh ,  Mitsunori Ono ,  Hidetoshi Kobayashi ,  Kazuyoshi Yamakawa

发明人： Isamu Itoh ,  Mitsunori Ono ,  Hidetoshi Kobayashi ,  Kazuyoshi Yamakawa

IPC分类号： C07C67/00 ,  C07C213/00 ,  C07C215/76 ,  C07C217/90 ,  C07C315/02 ,  C07C317/22 ,  C07D263/56 ,  C07D263/57 ,  C07D263/62 ,  C07D295/135 ,  C07D413/04 ,  C07D413/06

CPC分类号： C07D263/56 ,  C07D263/57 ,  C07D295/135 ,  C07D413/04

摘要： Novel benzoxazole compound having, at the 2 position, a group bonding through a carbon atom having no or one hydrogen atom and introduced with a chlorine or bromine atom at the 5 position. The compounds are key intermediates useful for preparing 2-amino-5-nitrophenol derivatives which are useful as intermediates for synthesis of industrial materials, reducing agents, antioxidants, cyan-image-forming couplers and the like.

摘要翻译： 新的苯并恶唑化合物在2位具有通过没有或一个氢原子的碳原子键合并在5位被氯或溴原子引入的基团。 这些化合物是可用于制备2-氨基-5-硝基苯酚衍生物的关键中间体，其可用作合成工业材料，还原剂，抗氧化剂，青色成像成色剂等的中间体。

公开(公告)号：US4554243A

公开(公告)日：1985-11-19

申请号：US613986

申请日：1984-05-25

申请人： Mitsunori Ono ,  Isamu Itoh

发明人： Mitsunori Ono ,  Isamu Itoh

IPC分类号： G03C7/26 ,  C07D231/08 ,  C07D231/20 ,  C07D231/56 ,  C07D249/18 ,  C07D257/04 ,  C07D285/12 ,  C07D401/12 ,  G03C1/06 ,  G03C7/305 ,  G03C8/08 ,  G03C1/40 ,  G03C1/10 ,  G03C1/34 ,  G03C1/42

CPC分类号： G03C7/305 ,  C07D231/08 ,  C07D231/56 ,  C07D249/18 ,  C07D257/04 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/16 ,  Y10S430/161

摘要： A silver halide photographic light-sensitive material is described which comprises a support having thereon a light-sensitive silver halide emulsion layer, wherein the photographic light-sensitive material therein contains a blocked photographic agent capable of releasing a photographically useful agent and the blocked photographic agent has a carbonyl group or thiocarbonyl group to which a hydrogen atom or a carbon atom is directly bonded and is substituted with a photographically useful group which is capable of being released upon an intramolecular nucleophilic attack by the oxygen atom in the carbonyl group or the sulfur atom in the thiocarbonyl group.The precursor of photographic agent is completely stable during storage prior to use of the photographic light-sensitive material, and releases a photographic agent at a desired time upon the processing of the photographic light-sensitive material. The precursor also exhibits its function to a substantial degree in a relatively low pH range. A method of forming an image using the silver halide photographic light-sensitive material is also described.

摘要翻译： 描述了一种卤化银照相感光材料，其包括其上具有感光卤化银乳剂层的载体，其中其中的照相感光材料含有能够释放照相用的试剂和封闭的感光剂的封闭的感光材料 具有与氢原子或碳原子直接键合的羰基或硫代羰基，并且被在羰基或硫原子中的氧原子分子内亲核攻击时能释放的照相用基团取代 在硫代羰基中。 在使用照相感光材料之前，照相剂的前体在储存期间是完全稳定的，并且在照相感光材料的加工过程中在期望的时间释放照相剂。 该前体还在相当低的pH范围内显着地发挥其功能。 还描述了使用卤化银照相感光材料形成图像的方法。

公开(公告)号：US4740453A

公开(公告)日：1988-04-26

申请号：US813308

申请日：1985-12-24

申请人： Koki Nakamura ,  Shigeo Hirano ,  Tadashi Ikeda ,  Keiji Mihayashi ,  Mitsunori Ono ,  Toshiro Takahashi ,  Ken-ichi Kuwabara ,  Morio Yagihara ,  Isamu Itoh

发明人： Koki Nakamura ,  Shigeo Hirano ,  Tadashi Ikeda ,  Keiji Mihayashi ,  Mitsunori Ono ,  Toshiro Takahashi ,  Ken-ichi Kuwabara ,  Morio Yagihara ,  Isamu Itoh

IPC分类号： G03C1/43 ,  G03C7/305 ,  G03C1/40 ,  G03C5/54

CPC分类号： G03C1/43 ,  G03C7/305 ,  G03C2005/168 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/16

摘要： A silver halide photosensitive material is described, comprising a support and at least one silver halide emulsion layer, wherein said emulsion layer or another layer contains a compound represented by formula (I) ##STR1## wherein X represents an atomic group forming a redox center of benzene type having substituents by linking with C.sub.A and C.sub.B, and which does not enable Time-PUG to be released until the redox center is oxidized during development processing; EWG represents an electron withdrawing group having a Hammet's .sigma. para value exceeding 0.3; C.sub.A and C.sub.B each represents a carbon atom; R.sub.1 and R.sub.2 each represents a hydrogen atom or a suitable substituent; Time represents a timing group connecting to C.sub.B through a sulfur, nitrogen, or selenium atom thereof, t is an integer of 0 or 1, and when t=0, Time is a chemical bond; PUG represents a photographically useful group and connects to C.sub.B through a sulfur, nitrogen, or selenium atom thereof when t=0; and n is an integer of 0 or 1.

摘要翻译： 描述了卤化银感光材料，其包括载体和至少一种卤化银乳剂层，其中所述乳剂层或另一层含有由式（I）表示的化合物（I），其中X表示形成 通过与CA和CB连接而具有取代基的苯类氧化还原中心，并且不能使Time-PUG释放直到氧化还原中心在显影处理期间被氧化; EWG代表Hammet sigma值超过0.3的吸电子基团; CA和CB各自表示碳原子; R1和R2各自表示氢原子或适当的取代基; 时间表示通过其硫，氮或硒原子与CB连接的定时基团，t为0或1的整数，当t = 0时，为化学键; PUG表示当t = 0时，通过其硫，氮或硒原子连接CB; n为0或1的整数。

公开(公告)号：US4618563A

公开(公告)日：1986-10-21

申请号：US641101

申请日：1984-08-15

申请人： Mitsunori Ono ,  Isamu Itoh ,  Keiji Mihayashi

发明人： Mitsunori Ono ,  Isamu Itoh ,  Keiji Mihayashi

IPC分类号： G03C7/26 ,  C07D401/12 ,  C07D403/12 ,  C07D403/14 ,  C07D413/12 ,  C07D417/12 ,  G03C1/06 ,  G03C7/00 ,  G03C7/305 ,  G03C8/08 ,  G03C8/10 ,  G03C1/40 ,  G03C1/08 ,  G03C1/34 ,  G03C5/54

CPC分类号： G03C7/30511 ,  G03C8/10 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/159 ,  Y10S430/16

摘要： A silver halide photographic light-sensitive material is described, comprising a support having thereon a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent represented by formula (I) ##STR1## wherein A represents a photographically useful agent moiety, which may have a timing group; X.sup.1 and X.sup.2 each represents a carbonyl group, a sulfonyl group, or a sulfinyl group; Z represents an atomic group forming a 5-membered, 6-membered, or 7-membered ring; R.sup.1 and R.sup.2, which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an acyl group, a sulfonyl group, or a heterocyclic group; R.sup.3 represents an alkyl group, an alkenyl group, a cycloalkyl group, a heterocyclic group, an aryl group, or an aralkyl group; m represents 0, 1, or 2; n represents 0 or 1; and the total of m+n is 1, 2, or 3. The precursor of photographic agent is completely stable during the preservation of the photographic light-sensitive material and releases a photographically useful agent at a desired time during processing of the photographic light-sensitive material. The precursor can exhibit its function to a substantial degree under mild conditions, such as in a pH range of from 9 to 12.

摘要翻译： 描述了一种卤化银照相感光材料，其包括其上具有感光卤化银乳剂层的载体，其具有与式（I）表示的封闭的感光剂相关联，其中A表示摄影有用的试剂部分，其中 可能有一个时间组; X1和X2各自表示羰基，磺酰基或亚磺酰基; Z表示形成5元，6元或7元环的原子团; R 1和R 2可以相同或不同，各自表示氢原子，卤素原子，烷基，烯基，环烷基，芳基，烷氧基，酰基，磺酰基， 或杂环基; R3表示烷基，烯基，环烷基，杂环基，芳基或芳烷基; m表示0,1或2; n表示0或1; 并且m + n的总和为1,2或3.照相剂的前体在照相感光材料的保存期间是完全稳定的，并且在照相感光材料的处理期间在期望的时间释放照相用的试剂， 敏感材料。 前体可以在温和条件下，例如在9至12的pH范围内显着地发挥其功能。

公开(公告)号：US4772537A

公开(公告)日：1988-09-20

申请号：US908689

申请日：1986-09-18

申请人： Isamu Itoh ,  Mitsunori Ono

发明人： Isamu Itoh ,  Mitsunori Ono

IPC分类号： C07D417/06 ,  C07D275/04 ,  C07D417/12 ,  C07D521/00 ,  G03C1/43 ,  G03C7/26 ,  G03C7/305 ,  G03C7/388 ,  G03C7/392 ,  G03C1/40 ,  G03C1/08 ,  G03C5/54

CPC分类号： G03C7/305 ,  G03C1/43 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/159 ,  Y10S430/16 ,  Y10S430/161

摘要： A silver halide photographic material which contains at least one blocked photographic reagent having in the molecule thereof at least one ##STR1## structure and capable of releasing a photogrpahically useful reagent by cleavage of the ##STR2## bond by a nucleophilic attack of a nucleophilic reagent on the structure and a subsequent intramolecular electron transfer reaction or an intramolecular nucleophilic reaction and which has at least one photosensitive silver halide emulsion layer. There is provided a photogrphic material which includes, in combination, a photographic reagent precursor capable of releasing a photographically useful reagent timely on photographic processing and a photosensitive silver halide emulsion layer.

摘要翻译： 一种卤化银照相材料，其含有至少一种在其分子中具有至少一个“结构”的封闭照相试剂，并且能够通过亲核试剂的亲核性攻击裂解“IMAGE”键，从而释放光致变色的试剂 该结构和随后的分子内电子转移反应或分子内亲核反应，并且具有至少一个光敏卤化银乳剂层。 提供了一种光雕材料，其组合包括能够及时在照相处理和光敏卤化银乳剂层上释放照相用试剂的照相试剂前体。