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    Process of preparing a solid catalytic titanium component and process for the polymerization of 1-alkenes using such a titanium component
    1.
    发明授权
    Process of preparing a solid catalytic titanium component and process for the polymerization of 1-alkenes using such a titanium component 失效
    制备固体催化钛组分的方法和使用这种钛组分聚合1-烯烃的方法

    公开(公告)号：US4546092A

    公开(公告)日：1985-10-08

    申请号：US525825

    申请日：1983-08-23

    申请人： Jacobus A. Loontjens ,  Bernardus J. Muskens

    发明人： Jacobus A. Loontjens ,  Bernardus J. Muskens

    IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00

    CPC分类号： C08F10/00

    摘要： A process is disclosed for preparing a titanium catalyst component useful for homopolymerizing 1-alkenes and for copolymerizing 1-alkenes with each other and/or with ethylene, consisting essentially in grinding a titanium halide compound/electron-donor complex with a magnesium aluminum halide obtained by precipitation from an organic solvent.In the process the ground product is first washed with a washing liquid containing a solvent for the aluminum halide/electron-donor complex which forms during the grinding process and by preference at least one alcohol, the molar ratio between alcohol and titanium in the ground product ranging between 50:1 and 1:20, and then the washed product is exposed to a liquid titanium halide compound.With this procedure, it is possible to obtain a titanium component which imparts to the polymerization catalyst an excellent stereospecificity along with a very high activity, and with which it is possible to obtain polymers, e.g. polypropylene, with a very low halogen content, a very low titanium content, and an excellent powder morphology and bulk density.

    摘要翻译： 公开了一种用于制备可用于均聚1-烯烃并用于使1-烯烃彼此和/或与乙烯共聚的钛催化剂组分的方法，其基本上在与卤化镁卤化铝的卤化铝化合物/电子给体络合物的研磨中得到 通过有机溶剂的沉淀。 在该方法中，研磨产物首先用包含在研磨过程中形成的卤化铝/电子给体络合物的溶剂的清洗液和优选至少一种醇洗涤，研磨产物中醇与钛的摩尔比 范围在50:1和1:20之间，然后将洗涤的产物暴露于液体卤化钛化合物。 通过该方法，可以获得赋予聚合催化剂的极好的立体定向性以及非常高的活性的钛成分，并且可以通过其获得聚合物。 聚丙烯，具有非常低的卤素含量，非常低的钛含量，以及优异的粉末形态和体积密度。

    Process for the preparation of a polymer composition
    3.
    发明授权
    Process for the preparation of a polymer composition 失效
    制备聚合物组合物的方法

    公开(公告)号：US07589136B2

    公开(公告)日：2009-09-15

    申请号：US10572371

    申请日：2004-09-17

    申请人： Jacobus A. Loontjens

    发明人： Jacobus A. Loontjens

    IPC分类号： C08K5/35 ,  C08K5/1545

    CPC分类号： C08G63/91

    摘要： The invention relates to a process for the preparation of a polymer composition, the process comprising a step of contacting a polymer that comprises carboxyl groups with a cyclic imino ether compound characterized in that the cyclic imino ether compound is a phenylene oxazine according to formula (I), in which formula R=an oxazine group according to formula (II) n=0, 1, 2, 3, 4 or 5 and that the polymer is contacted with said oxazine in an extruder at a temperature above 100° C.

    摘要翻译： 本发明涉及一种制备聚合物组合物的方法，该方法包括使包含羧基的聚合物与环状亚氨基醚化合物接触的步骤，其特征在于环状亚氨基醚化合物是式（I ），其中R =式（II）的恶嗪基n = 0,1,2,3,4或5，并且聚合物在挤出机中在高于100℃的温度下与所述恶嗪接触。

    Supramolecular compound
    5.
    发明授权
    Supramolecular compound 有权
    超分子化合物

    公开(公告)号：US06683151B1

    公开(公告)日：2004-01-27

    申请号：US09511984

    申请日：2000-02-24

    申请人： Jacobus A. Loontjens ,  Johan E. G. A. Jansen ,  Bartholomeus J. M. Plum

    发明人： Jacobus A. Loontjens ,  Johan E. G. A. Jansen ,  Bartholomeus J. M. Plum

    IPC分类号： C09D17500

    CPC分类号： C08G18/6674 ,  C08G18/3851 ,  C08G18/4854 ,  C08G83/008 ,  Y10T428/2929 ,  Y10T428/2933 ,  Y10T428/2938 ,  Y10T428/2964

    摘要： The invention relates to a compound comprising a reaction product of (A) an isocyanate functional compound of which at least 40 wt. %, relative to the total amount of (A), has a molecular weight of at least about 500, and (B) a nitrogen-containing compound capable of reacting with said isocyanate functional compound (A). The reaction product has a molecular weight of less then about 20,000 and comprises an effective amount of groups that are able to form reversible intermolecular physical interactions such that a resulting compound shows polymeric mechanical properties at a temperature below a transition temperature. The nitrogen-containing compound is, for instance, melamine, urea, acetoguanamine, benzoguanamine, cyanamide, dicyanamide, thiourea, isocytosine, pyrimidone or aminopyridine. The supramolecular compound comprising a suitable amount of the reaction products exhibits a relatively high elongation at break.

    摘要翻译： 本发明涉及包含（A）异氰酸酯官能化合物的反应产物的化合物，其中至少40重量％ 相对于（A）的总量的％具有至少约500的分子量，和（B）能够与所述异氰酸酯官能化合物（A）反应的含氮化合物。 反应产物的分子量小于约20,000，并且包含有效量的能够形成可逆分子间物理相互作用的基团，使得所得化合物在低于转变温度的温度下显示出聚合物的机械性能。 含氮化合物是例如三聚氰胺，脲，乙酰胍胺，苯并胍胺，氨腈，二氰胺，硫脲，异胞嘧啶，嘧啶酮或氨基吡啶。 包含适量的反应产物的超分子化合物表现出较高的断裂伸长率。

    Process for the production of a polyolefin-based composite material of high rigidity
    6.
    发明授权
    Process for the production of a polyolefin-based composite material of high rigidity 失效

    公开(公告)号：US06583200B2

    公开(公告)日：2003-06-24

    申请号：US10050040

    申请日：2002-01-17

    申请人： Jacobus A. Loontjens ,  Sander Langereis

    发明人： Jacobus A. Loontjens ,  Sander Langereis

    IPC分类号： C08K900

    CPC分类号： C08K9/04 ,  C08L23/02

    摘要： A process for production of a polyolefin-based composite material of high rigidity, containing a polyolefin and a layered clay, involves impregnating a layered, swellable clay which is interstratified with a tetraalkyl cation, with at least one polymerizable monomer and then mixing this impregnated clay with a polyolefin and a peroxide, at a temperature above the melting point of the polyolefin. A polyolefin-based composite material containing 98-50 wt. % of a polyolefin, 1-50 wt. % of another homo- or copolymer and 1-50 wt. % of a layered clay, wherein the ratio between the modulus of elasticity of the material and that of the initial polyolefin, at a temperature which is 30° C. below the melting temperature of the polyolefin, is higher than or equal to 1 has high rigidity.

    High-molecular polyamide
    7.
    发明授权
    High-molecular polyamide 失效
    高分子聚酰胺

    公开(公告)号：US06228980B1

    公开(公告)日：2001-05-08

    申请号：US09421525

    申请日：1999-10-20

    申请人： Jacobus A. Loontjens ,  Bartholomeus J. M. Plum

    发明人： Jacobus A. Loontjens ,  Bartholomeus J. M. Plum

    IPC分类号： C08G6914

    CPC分类号： C08G69/48 ,  C08G63/916 ,  C08G69/18 ,  C08G69/20

    摘要： The invention relates to a process for preparing a high-molecular polyamide or polyester by melt-mixing polyamide or polyester having a lower molecular weight with a carbonyl bislactam having formula 1, in which n=an integer of between 3 and 15. With the process according to the invention a permanent increase in the molecular weight of a polyamide is obtained within 2 minutes, whereas this takes at least 10 minutes under comparable conditions using a bislactam according to the state of the art.

    摘要翻译： 本发明涉及通过将具有较低分子量的聚酰胺或聚酯与具有式1的羰基双内酰胺熔融混合制备高分子量聚酰胺或聚酯的方法，其中n = 3至15的整数。通过该方法 根据本发明，在2分钟内获得聚酰胺的分子量的永久增加，而根据现有技术，使用双内酰胺在相当的条件下至少需要10分钟。

    Process for the preparation of an N-alkyl or N-aryl carbamoyl derivative
    9.
    发明授权
    Process for the preparation of an N-alkyl or N-aryl carbamoyl derivative 失效
    制备N-烷基或N-芳基氨基甲酰基衍生物的方法

    公开(公告)号：US06448394B1

    公开(公告)日：2002-09-10

    申请号：US09815268

    申请日：2001-03-23

    申请人： Jacobus A. Loontjens ,  Bartholomeus J. M. Plum

    发明人： Jacobus A. Loontjens ,  Bartholomeus J. M. Plum

    IPC分类号： C07D22310

    CPC分类号： C08G18/8074 ,  C07D223/10 ,  C08G2150/20 ,  C08G2390/40

    摘要： The invention relates to a process for the preparation of an N-alkyl or N-aryl carbamoyl derivative in which an amine is contacted with a carbonic acid derivative according to the general formula: where fragments X in the form of XH are a lactam, oxime, imide or triazole. In particular the invention relates to the preparation of a blocked isocyanate according to a process in which no isocyanate is used. The invention also relates to the use of the N-alkyl or N-aryl carbamoyl derivative prepared according to the process according to the invention in a coating.

    摘要翻译： 本发明涉及一种制备N-烷基或N-芳基氨基甲酰基衍生物的方法，其中胺与根据通式的碳酸衍生物接触：其中XH形式的片段X为内酰胺，肟 ，酰亚胺或三唑。 特别地，本发明涉及根据其中不使用异氰酸酯的方法制备封端异氰酸酯。 本发明还涉及根据本发明的方法制备的N-烷基或N-芳基氨基甲酰基衍生物在涂层中的用途。

    Thermoplastic propylene block copolymer containing 1-alkene-propylene-diene copolymer block
    10.
    发明授权
    Thermoplastic propylene block copolymer containing 1-alkene-propylene-diene copolymer block 失效
    含有1-烯烃 - 丙烯 - 二烯共聚物嵌段的热塑性丙烯嵌段共聚物

    公开(公告)号：US4499242A

    公开(公告)日：1985-02-12

    申请号：US456433

    申请日：1983-01-07

    申请人： Jacobus A. Loontjens

    发明人： Jacobus A. Loontjens

    IPC分类号： C08F297/00 ,  C08F297/06 ,  C08F293/00 ,  C08F297/08

    CPC分类号： C08F297/06

    摘要： The invention relates to a thermoplastic propylene block copolymer comprising one or more substantially crystalline polypropylene blocks and one or more 1-alkene-propylene copolymer blocks, in at least one of which 1-alkene-propylene copolymer blocks diene units are present, and to a process for preparing such a propylene block copolymer.According to the invention, as diene, a cyclic hydrocarbon compound is used wherein at least one double bond forms part of a strained structure, particularly a polycyclic compound with 7 to 20 carbon atoms containing at least one 4- and/or 5-ring, with one or more double bonds in or to the ring.The invention offers the advantage that it is possible to prepare block copolymers which can otherwise not or hardly be made, while at the same time only a small quantity is formed of byproducts which are soluble in the dispersant.

    摘要翻译： 本发明涉及一种包含一种或多种基本上结晶的聚丙烯嵌段和一种或多种1-烯烃 - 丙烯共聚物嵌段的热塑性丙烯嵌段共聚物，其中至少一种其中存在1-烯烃 - 丙烯共聚物嵌段二烯单元， 制备这种丙烯嵌段共聚物的方法。 根据本发明，作为二烯，使用环状烃化合物，其中至少一个双键形成应变结构的一部分，特别是含有至少一个4-和/或5-环的具有7至20个碳原子的多环化合物， 在环中或环中具有一个或多个双键。 本发明的优点在于可以制备其它不能或几乎不能制备的嵌段共聚物，同时只有少量可溶于分散剂的副产物形成。